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Molecular Diversity - This study describes the use of 3-aminotriazole, different aldehydes and N-methyl-1-(methylthio)-2-nitroethenamine as a ketene N,S-acetal in a three-component condensation for... 相似文献
84.
The Bridgman anvil technique offers a simple and versatile means of generating very high pressures required in solid state
studies. The opposed anvil technique is based on the principle of massive support. The practical case of a gasketted anvil
is considered, and an expression for the maximum pressure generated under massive support is derived in terms of the geometric
parameters, the strength of the anvil material and the gasket properties. In particular, for a given maximum pressure, it
is possible to calculate the taper angle, the taper height and the gasket thickness from this expression. The anvil is assumed
to be in the elastic region under load. Good agreement is obtained between the calculated and the experimental values for
the massive support factor (msf) for various taper angles. By choosing the proper geometry, it is possible to achieve a pressure as high as 130 kbar in an
alloy steel anvil. It has been clearly found that the straight portion, where the taper ends, does not really take any part
in changing the stress pattern. Thus the minimum straight portion can serve the purpose, and will result in material saving.
Anvils exhibit yielding at very high pressure. It is also pointed out that a further strengthening of the anvil can extend
the ultimate pressure. Several methods of further strengthening the anvils are discussed. 相似文献
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A necessary condition for generation of bright soliton Kerr frequency combs in microresonators is to achieve anomalous group velocity dispersion (GVD) for the resonator modes. This condition is hard to implement in the visible as well as ultraviolet since the majority of optical materials are characterized with large normal GVD in these wavelength regions. We overcome this challenge by borrowing ideas from strongly dispersive coupled systems in solid state physics and optics. We show that photonic compound ring resonators can possess large anomalous GVD at any desirable wavelength, even if each individual resonator is characterized with normal GVD. Based on this concept, we design a mode‐locked frequency comb with thin‐film silicon nitride compound ring resonators in the vicinity of the rubidium D1 line (794.6 nm) and propose to use this optical comb as a flywheel for chip‐scale optical clocks.
88.
Mohammad Kemal Agusta Melanie David Hiroshi Nakanishi Hideaki Kasai 《Surface science》2010,604(3-4):245-251
A theoretical study on the structure and adsorption mechanism of hydrazine (N2H4) on Ni(1 0 0) are presented. The hydrazine molecule was found to adsorb on the surface through one of its nitrogen atom in its anti-conformation. The charge transfer from hydrazine lone pair orbitals played a key role in the formation of the bonding. The mechanism involved in the bonding was found to reduce the necessity of hyper-conjugation interaction, that reduces the gauche effect found in hydrazine at the gas-phase. Upon adsorption to the surface, the reduced interaction resulted in the promotion of a more favored conformation through its anti-conformation. 相似文献
89.
Davood Nematollahi Mohammad Alimoradi Mohammad Rafiee 《Journal of Physical Organic Chemistry》2007,20(1):49-54
The reaction of electrochemically generated o‐benzoquinones ( 2a‐f ) as Michael acceptors with 2‐acetylcyclohexanone (ACH) and 2‐acetylcyclopentanone (ACP), as nucleophiles has been studied in various pHs using cyclic voltammetry. The results indicate that the participation of o‐benzoquinones ( 2a‐f ) in the Michael reaction with acetylcyclohexanone (ACH) to form the corresponding catechol derivatives ( 4a‐f ). Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
90.
Neeraj Pant N. Pradhan Mohammad Hassan Murad 《International Journal of Theoretical Physics》2014,53(11):3958-3969
We present a spherically symmetric solution of the general relativistic field equations in isotropic coordinates for perfect charged fluid, compatible with a super dense star modeling. The solution is well behaved for all the values of Schwarzschild parameter u lying in the range 0 < u < 0.1727 for the maximum value of charge parameter K = 0.08163. The maximum mass of the fluid distribution is calculated by using stellar surface density as ρ b = 4.6888×1014g cm?3. Corresponding to K = 0.08 and u max = 0.1732, the resulting well behaved solution has a maximum mass M = 0.9324M ⊙ and radius R = 8.00 and by assuming ρ b = 2×1014g cm?3 the solution results a stellar configuration with maximum mass M = 1.43M ⊙ and radius R b = 12.25 km. The maximum mass is found increasing with increasing K up to 0.08. The well behaved class of relativistic stellar models obtained in this work might has astrophysical significance in the study of internal structure of compact star such as neutron star or self-bound strange quark star like Her X-1. 相似文献