Initial anticrossing between Stark manifold <Emphasis Type="Italic">n</Emphasis> and <Emphasis Type="Italic">n</Emphasis>+1 in Na

We present the theoretical results for the positions and widths of the initial anticrossing between Stark manifold n and n + 1 in sodium, obtained by using the method of diagonalization in which zero-field wave functions are chosen from a kind of atomic potential model. These results can provide the quantitative information for understanding the microwave ionization process, whose rate-limiting step is probably the n to n + 1 transition performed at the first crossing between the outermost states of these two manifolds.     

Symmetry numbers and chemical reaction rates

This article shows how to evaluate rotational symmetry numbers for different molecular configurations and how to apply them to transition state theory. In general, the symmetry number is given by the ratio of the reactant and transition state rotational symmetry numbers. However, special care is advised in the evaluation of symmetry numbers in the following situations: (i) if the reaction is symmetric, (ii) if reactants and/or transition states are chiral, (iii) if the reaction has multiple conformers for reactants and/or transition states and, (iv) if there is an internal rotation of part of the molecular system. All these four situations are treated systematically and analyzed in detail in the present article. We also include a large number of examples to clarify some complicated situations, and in the last section we discuss an example involving an achiral diasteroisomer.     

Calorimetry in the studies of cement–Pb compounds interaction

The effect of PbO on cement hydration kinetics by calorimetric method was evaluated as a first step in this project. Substantial retardation of reaction with water at early stages with subsequent intensification of the process was found. As the next step, the model systems covering pure cement minerals and their mixtures of various composition as well as soluble Pb salts were taken into account to elucidate the mechanism of delayed, by quite good formation of products in the so-called post-induction period. The precipitation of sulphate, forming very thin impermeable layer seems to be responsible for this delaying effect in case of cement, however the other reactions of Pb compounds in alkaline environment of hydrating calcium silicate are not out of importance. In order to prove this, the studies of chemical composition in small areas were also carried out.     

Conversion of 3-benzoyl-1-methyl-4-phenyl-γ-piperidol by arylamines and arylhydrazines. Synthesis of 3-arylamino-1-oxo-1-phenylpropanes and 1,3-diarylpyrazoles and their fragmentation under electron impact

It has been established that on heating, 3-benzoyl-4-hydroxy-1-methyl-4-phenylpiperidine is ring-opened in the presence of arylamines by a type of retroaldol reaction, with subsequent transamination of the intermediate Mannich base and the formation of 3-arylamino-1-oxo-1-phenylpropanes. When using arylhydrazines this γ-piperidol is recyclized with the formation of 1,3-diarylpyrazoles and their 4,5-dihydro derivatives. The mass spectral behavior of a series of 3-arylamino-substituted 1-phenylpropanones has been studied. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1486–1495, October, 2007.     

The Effect of Alkane Chain Length on the Liquid–Liquid Critical Temperatures of Oligostyrene/Linear-Alkane Mixtures

Summary. Upper critical solution temperatures (UCSTs) for liquid–liquid demixing in a set of mixtures of linear alkanes (pentane (N ₁=5) to pentacontane (N ₁=50)) with an oligostyrene (1241amu, N ₂=12) are reported. We find strong correlation between the Hildebrand solubility parameters of the alkanes and the UCST. Correlations are developed which enable predictions concerning the miscibility of mixtures of compounds with longer chains.     

Sorption equilibrium of methanol on new composite sorbents “CaCl<Subscript>2</Subscript>/silica gel”

This paper presents experimental data on methanol sorption on new composite sorbents which consist of mesoporous silica gels and calcium chloride confined to their pores. Sorption isobars and XRD analysis showed the formation of a solid crystalline solvate CaCl₂⋅2MeOH at low methanol uptake, while at higher uptake the formation of the CaCl₂–methanol solution occurred. The solution confined to the silica pores showed the sorption properties similar to those of the CaCl₂–methanol bulk solution. Calorimetric and isosteric analyses showed that the heat of methanol sorption depends on the methanol uptake, ranging from 38±2 kJ/mol for the solution to 81±4 kJ/mol for the solid crystalline phase CaCl₂⋅2MeOH. The above mentioned characterizations allowed the evaluation of the methanol sorption and the energy storage capacities, clearly showing that the optimal applications of these new composite sorbents are the methanol removal from gaseous mixtures, heat storage and sorption cooling driven by low temperature heat.     

Analysis of the effects of catalytic bleaching on cotton

Hydrogen peroxide can be catalyzed to bleach cotton fibers at temperatures as low as 30°C by incorporating dinuclear tri-μ-oxo bridged manganese(IV) complex of the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (MnTACN) as the catalyst in the bleaching solution. The catalytic system was found to be more selective under the conditions applied than the non-catalytic H₂O₂ system, showing better bleaching performance while causing slightly lower decrease in degree of polymerization (DP) of cellulose. In order to gain fundamental knowledge of the bleach effect on cotton fibers and cellulose as its main component, especially after catalytic bleaching, X-ray Photoelectron Spectroscopy (XPS) was used to study surface chemical effects. The Washburn method was applied to investigate wetting properties, and liquid porosity was used to obtain pore volume distribution (PVD) plots. Parallel analyzes performed on model cotton fabric, i.e. “clean” cotton fabric stained with morin - a pigment regularly found in native cotton fiber, helped to differentiate between pigment oxidation and other bleaching effects produced on the (regular) industrially scoured cotton fabric. Bleaching was not limited to the chemical action but also affected cotton fiber capillary parameters most likely due to the removal of non-cellulosic materials as well as chain-shortened cellulose.     

Adsorption of dyes on activated carbon and graphitic thermal carbon black

The adsorption of a basic dye (Methylene Blue; MB) and an acidic dye (Acid Orange; AO) has been studied on three activated carbons (ACs; FAS, SKD, and BAU) significantly differing in their porous structures and surface concentrations of ion-exchange groups and on graphitic thermal carbon black (GTCB). The effective specific surface area of FAS, SKD, and BAU determined by dye adsorption is, respectively, 60, 50, and 40% of the BET nitrogen adsorption surface area. The MB uptake on ACs and GTCB increases with rising pH, while the AO uptake decreases. Addition of an electrolyte (0.3 M NaCl) virtually does not effect the adsorption of dyes on ACs and GTCB. It is suggested that hydrophobic interactions, and not ionic ones, are the major contributors to the adsorption of dyes on ACs.     

One-pot Three-component Condensation Reactions in Water. An Efficient and Improved Procedure for the Synthesis of Furan Annulated Heterocycles

Summary. The environment-friendly one-pot three-component condensation reactions of 4-hydroxycoumarin or 4-hydroxy-6-methylpyrone, p-substituted benzaldehyde, and alkyl or aryl isocyanides to afford furocoumarines or furopyranones in water in good yields after about one hour at 75°C are reported.     

New computer program to calculate the symmetry of molecules

In this paper we, present some MATLAB and GAP programs and use them to find the automorphism group of the Euclidean graph of the C₈₀ fullerence with connectivity and geometry of I _h symmetry point group. It is proved that this group has order 120 and is isomorphic to I _h ≊Z₂×A₅, where Z₂ is, a cyclic group of order 2 and A₅ is the alternating group on five symbols.