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991.
Mohamed Haouari Safa Bhar Layeb Hanif D. Sherali 《Computational Optimization and Applications》2008,40(1):13-39
We propose a generalized version of the Prize Collecting Steiner Tree Problem (PCSTP), which offers a fundamental unifying
model for several well-known
-hard tree optimization problems. The PCSTP also arises naturally in a variety of network design applications including cable
television and local access networks. We reformulate the PCSTP as a minimum spanning tree problem with additional packing
and knapsack constraints and we explore various nondifferentiable optimization algorithms for solving its Lagrangian dual.
We report computational results for nine variants of deflected subgradient strategies, the volume algorithm (VA), and the
variable target value method used in conjunction with the VA and with a generalized Polyak–Kelley cutting plane technique.
The performance of these approaches is also compared with an exact stabilized constraint generation procedure. 相似文献
992.
A new parallel extended GCD algorithm is proposed. It matches the best existing parallel integer GCD algorithms of Sorenson and Chor and Goldreich, since it can be achieved in O(n/logn) time using at most n1+ processors on CRCW PRAM. Sorenson and Chor and Goldreich both use a modular approach which consider the least significant bits. By contrast, our algorithm only deals with the leading bits of the integers u and v, with uv. This approach is more suitable for extended GCD algorithms since the coefficients of the extended version a and b, such that au+bv=gcd(u,v), are deeply linked with the order of magnitude of the rational v/u and its continuants. Consequently, the computation of such coefficients is much easier. 相似文献
993.
Abdellah El Kinani Amine Mohammed Nejjari Mohamed Oudadess 《Mediterranean Journal of Mathematics》2008,5(1):33-42
We use positive elements of Hermitian algebras to give results on automatic continuity of algebra morphisms. Consequences
and applications are also given.
相似文献
994.
Basem Moosa Lukman O. Alimi Weibin Lin Aliyah Fakim Prashant M. Bhatt Mohamed Eddaoudi Niveen M. Khashab 《Angewandte Chemie (International ed. in English)》2023,62(46):e202311555
Porous molecular sorbents have excellent selectivity towards hydrocarbon separation with energy saving techniques. However, to realize commercialization, molecular sieving processes should be faster and more efficient compared to extended frameworks. In this work, we show that utilizing fluorine to improve the hydrophobic profile of leaning pillararenes affords a substantial kinetic selective adsorption of benzene over cyclohexane (20 : 1 for benzene). The crystal structure shows a porous macrocycle that acts as a perfect match for benzene in both the intrinsic and extrinsic cavities with strong interactions in the solid state. The fluorinated leaning pillararene surpasses all reported organic molecular sieves and is comparable to the extended metal–organic frameworks that were previously employed for this separation such as UIO-66. Most importantly, this sieving system outperformed the well-known zeolitic imidazolate frameworks under low pressure, which opens the door to new generations of molecular sieves that can compete with extended frameworks for more sustainable hydrocarbon separation. 相似文献
995.
Gabrielle Mpacko Priso Dr. Mohamed Haouas Dr. Nathalie Leclerc Dr. Clément Falaise Prof. Dr. Emmanuel Cadot 《Angewandte Chemie (International ed. in English)》2023,62(49):e202312457
Super-reduction of polyoxometalates (POMs) in solution is of fundamental interest for designing innovative energy storage systems. In this article, we show that the “Dawson-like” POM can undergo a disproportionation process during its massive electron uptake, leading to species containing three metal-metal bonds as evidenced by X-ray diffraction, multi-nuclear magnetic resonance spectroscopy (1H and 183W NMR), extended X-ray absorption fine structure (EXAFS), UV/Vis, and voltammetry techniques. This result indicates that electron storing within metal-metal bonds is not a unique property of Keggin-type POM as postulated since the 70s. Besides, we demonstrate that the presence of an electron-rich triad in the “Dawson-like” POM allows its post-functionalization with additional tungstate ions, generating a chiral molecule that is also the largest WIV-containing POMs known to date. 相似文献
996.
Ahmed S. Hammam Mohamed S. K. Youssef Ferial M. Atta Thana A. Mohamed 《Chemical Papers》2008,62(2):194-206
The reaction of two equivalents of sodium azide with diarylaminodibromo-p-benzoquinone (I) in DMF for 15–24 h produced quinoxalinophenazinediones together with a byproduct identified as diarylaminodiaminobenzoquinone.
On the other hand, the reaction of bromanil with active methylenes, such as diethyl malonate and ethyl acetoacetate, resulted
in disubstitution products which, on treatment with primary amines, cyclized into benzodipyrroletetrones. Comparative antifungal
and antibacterial studies were made. 相似文献
997.
Four new nickel(II) complexes, [{Ni(L)}2], [NiL · HPyr], [NiL · HIm] and [Ni(HL)2] · H2O, derived from diacetylmonoxime-S-benzyldithiocarbazonate (H2L) have been synthesized and characterized by elemental analyses, field desorption and electrospray ionization mass spectra, UV–Vis, infrared absorption spectra, as well as 1H NMR spectra. X-ray molecular structures showed that the Ni(II) in both [NiL · HPyr] and [NiL · HIm] are in a distorted square planar environment and is coordinated to the dianionic NNS tridentate hydrazoneoxime ligand via deprotonated oximate nitrogen, hydrazone imine nitrogen, and thiolate sulphur. The fourth coordination sites are occupied, respectively, by the pyrazole and imidazole nitrogens. The oximate O1 of [NiL · HPyr] is involved in intramolecular hydrogen bond with the pyrazole NH proton as well as intermolecular hydrogen bond pyrazole C6H proton, forming a helical chain propagating along the b-axis. The structure is stabilized by a set of π?π and CH?π interactions. The molecular units in [NiL · HIm] are linked together by hydrogen bond formation between the oximate oxygen and imidazole NH proton, giving rise to an infinite zigzag chain extended along the a-axis. The chains are interconnected by π?π and CH?O interactions. In [Ni(HL)2] · H2O, the Ni(II) is in a distorted octahedral environment. The two mononegative hydrazoneoxime ligands are coordinated in the meridional configuration where the two thiol sulphur atoms and the two oxime nitrogen atoms are cis to each other, while the imine nitrogen atoms are trans. The oxime proton O2H is involved in a reciprocal bifurcated hydrogen bond formation with both N2 and S3 of the adjacent molecule giving rise to hydrogen bonded dimer. This dimeric structure is further stabilized by a pair of reciprocal CH?O interactions. A one dimensional chain of alternating dimeric unit and water molecule propagating along the c-axis is formed via hydrogen bond formation between the oxime O1 oxygen and the bridged water molecule proton. 相似文献
998.
Basinska T Slomkowski S Kazmierski S Chehimi MM 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8465-8472
Hydrodynamic and electrophoretic properties of core-shell poly(styrene/alpha- tert-butoxy-omega-vinylbenzyl-polyglycidol) (P(S/PGL)) microspheres suspended in water are described. The microspheres were obtained by surfactant-free emulsion copolymerization of styrene and alpha- tert-butoxy-omega-vinylbenzyl-polyglycidol macromonomer ( M n = 2800, M w/ M n = 1.05). The process yielded microspheres with number average diameter D n = 270 nm and with low diameter dispersity index D w/ D n = 1.01. Shells of P(S/PGL) microspheres were enriched in polyglycidol. Molar fraction of polyglycidol monomeric units in the shells (determined by X-ray photoelectron spectroscopy) was equal to 0.34, which is much higher than the average molar fraction of polyglycidol monomeric units in whole particles of 0.048. Influences of NaCl concentration and temperature on P(S/PGL) microsphere diameters and on their electrophoretic mobility were investigated. It was found that hydrodynamic diameter of P(S/PGL) microspheres, determined by photon correlation spectroscopy, decreased significantly when temperature did exceed a certain value (transition temperature, T t). It has been found that the decrease is more pronounced for higher concentrations of NaCl in the medium. For microspheres suspended in 10 (-1) M NaCl, the hydrodynamic diameter decreased by 8% whereas for the same particles in pure water the diameter decreased by 5.2%. The process of shrinkage was fully reversible. Values of T t for P(S/PGL) microspheres were lower for higher concentrations of NaCl. Adjustment of salt concentration allowed controlling T t in a range from 44.4 to 49.9 degrees C. 13C NMR relaxation time measurements (T 1) for carbon atoms in polyglycidol macromonomer revealed that T 1 did increase with increasing temperature (in temperature range from 25 to 75 degrees C) indicating higher motion of chains at higher temperature. Addition of NaCl did not induce a substantial change of T 1 in the mentioned temperature range. The swelling-deswelling properties of P(S/PGL) microspheres' interfacial layer affected adsorption of P(S/PGL) particles on modified with (3-aminopropyl)triethoxysilane mica. It was shown that the deposition of P(S/PGL) microspheres at 25 degrees C on mica led to formation of two-dimensional crystal-shape assemblies, whereas at 60 degrees C (far above T t = 49.8 degrees C in H2O) the microspheres were randomly adsorbed without formation of colloidal crystal assemblies. 相似文献
999.
1000.