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51.
Mohamad Sh. Ramadan Nabila M. El-Mallah Sherif M. Abd-Elmenem 《Journal of Dispersion Science and Technology》2013,34(8):1110-1120
AbstractThe interaction between anionic dyes [Reactive Orange 122 (R.O 122), Reactive Blue 19 (R.B 19), Reactive Violet 5 (R.V 5) and Acid Green 20 (A.G 20)] with cationic surfactant cetyltrimethylammoniun bromide (CTAB) has been investigated by spectrophotometry and conductance technique. The used dyes are characterized by tautomeric behavior which affects the mechanism of the interaction. Various parameters such as dye structure, surfactant composition, solvent composition, temperature and pH of the medium were studied. The spectral data were applied for calculating the binding constant between dye and surfactant (Kb), fraction of micellization (?mic), and standard free energy change of binding (ΔG°b) in 0,10,20 and 30 v/v % acetonitile (AN). Conductance technique was constructed to estimate the ion pairing constant (Ka) at different temperatures and v/v % AN. Thermodynamic parameters (ΔG°, ΔH° and ΔS°) for ion pair formation were evaluated. The role of hydrophobic and electrostatic effect on dye-surfactant interaction was discussed. 相似文献
52.
S. Hosseini M. HomaieeA.B. Mohamad M.R. MalekbalaA.A.H. Khadum 《Physica B: Condensed Matter》2011,406(9):1689-1694
Cesium dihydrogen phosphate (CDP) nanoparticles were synthesized using the surfactants cetyltrimethyl ammonium bromide (CTAB), polyoxyethylene-polyoxypropylene (F-68) and (F-68:CTAB) with molar ratio 0.06. The samples conductivity such as CDPCTAB, CDPF-68 and CDP(F-68:CTAB)0.06 was studied by impedance spectroscopy in the frequency range 0.01 Hz to 1 MHz. The Nyquist plots were drawn at different temperatures of 210, 230 and 260 °C, which are defined below transition, phase transition and above transition, respectively. The measured conductivities obey the Arrhenius relation. The influence of surfactants on conductivity are more significant at higher temperature due to grain boundary. The conductivity of CDPCTAB increased slightly with increasing temperature to 260 °C, whereas the conductivity of other samples decreased with increasing temperature over 230 °C. The results indicated that the conductivities increase in the order of CDPCTAB>CDP(F-68:CTAB)0.06>CDPF-68. These are in accordance to the ion exchange capacities of the samples that the surfactant shows a direct influence on the samples proton mobility. It is found that the conductivity of CsH2PO4 is influenced by surfactant type. 相似文献
53.
Hossein Tavanai Rouholah Jalili Mohamad Morshed 《Surface and interface analysis : SIA》2009,41(10):814-819
The effects of fiber diameter and activation temperature on the pore characteristics of polyacrylonitrile based activated carbon nanofibers are investigated. It was found that lower fiber diameters as well as higher activation temperatures lead to a higher weight loss, specific surface area and total pore volume. The nitrogen adsorption capacity of activated carbon nanofibers is almost three times that of activated carbon fiber with a diameter of 10 µm. As far as the size of pores in activated carbon nanofibers is concerned, it is basically the micropores that dominate the scene. Moreover, tailoring the pore characteristics by adjusting the activation temperature and fiber diameter is plausible. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
54.
55.
S. Hosseini A. B. Mohamad A. H. Kadhum W. R. Wan Daud 《Journal of Thermal Analysis and Calorimetry》2010,99(1):197-202
A study concerned to thermogravimetric analysis is performed in cesium dihydrogen phosphate (CsH2PO4) that was synthesized, using cetyltrimethylammonium-bromide (CTAB), polyoxyethylene-polyoxypropylene (F-68) and mixture of
(F-68:CTAB) with two mole ratio 0.06 and 0.12 as surfactant. The dehydration behavior of particles was studied using thermal
gravimetric analysis and differential scanning calorimetric. Subsequently, the experimental results indicated that the first
dehydration temperature in the range of 237–239 °C upon heating, the second peaks occur at temperature range 290–295 °C and
overlapping in the thermogravimetric events is observed. The mass loss values are obtained in the range of 6.62–6.97 wt% that
is less than reported theoretical value 7.8 wt%. These values show well compatibility of reaction CsH2PO4 to Cs2H2P2O7 with 3.92 wt% whereas mass loss value of CsH2PO4 to CsPO3 is less than theoretical value 7.8 wt%. The activation energy of two steps dehydration are calculated using Kissinger equation
for the samples synthesized via CTAB and (F-68) with minimum value mass loss 6.62% and maximum value mass loss 6.97%, respectively.
The calculation results reveal that the reaction rate in the first step (CsH2PO4 → Cs2H2P2O7) is faster than the second step (CsH2PO4 → CsPO3). The weight loss values of the samples demonstrate that existence of CTAB can be considered as effective factor which prevents
more weight loss during the dehydration process. 相似文献
56.
Behnam Bahrami Abasali KhodadadiYadollah Mortazavi Mohamad Esmaieli 《Applied Surface Science》2011,257(23):9710-9716
We report the variation of yield and quality of carbon nanotubes (CNTs) grown by chemical vapor deposition (CVD) of methane on iron oxide-MgO at 900-1000 °C for 1-60 min. The catalyst was prepared by impregnation of MgO powder with iron nitrate, dried, and calcined at 300 °C. As calcined and unreduced catalyst in quartz reactor was brought to the synthesis temperature in helium flow in a few minutes, and then the flow was switched to methane. The iron oxide was reduced to iron nanoparticles in methane, while the CNTs were growing.TEM micrographs, in accordance with Raman RBM peaks, indicate the formation of mostly single wall carbon nanotubes of about 1.0 nm size. High quality CNTs with IG/ID Raman peak ratio of 14.5 are formed in the first minute of CNTs synthesis with the highest rate. Both the rate and quality of CNTs degrades with increasing CNTs synthesis time. Also CNTs quality sharply declines with temperature in the range of 900-1000 °C, while the CNTs yield passes through a maximum at 950 °C. About the same CNTs lengths are formed for the whole range of the synthesis times. A model of continuous emergence of iron nanoparticle seeds for CNTs synthesis may explain the data. The data can also provide information for continuous production of CNTs in a fluidized bed reactor. 相似文献
57.
Mohamad Kamarol Mohd Jamil Shinya Ohtsuka Masayuki Hikita Hitoshi Saitoh Masayuki Sakaki 《Journal of Electrostatics》2011,69(6):611-617
This paper presents the decomposition by-products of trifluro-iodo-methane and their relative proportions in the gas phase under the occurrence of partial discharge. The experiment was performed in the presence of water vapor from 250 to 400 ppm under a non-uniform electric field configuration. The experimental results reveal that the by-products of C2F6, C2F4, C2F5I with the amount of 1300, 200, and 55 (CH3I) ppm, respectively, were produced for a cumulative charge of 161 mC. Other by-products, such as C3F8, CHF3, C3F6 CH3I were obtained at less than 30 ppm C2F6 was the dominant gas by-product of trifluro-iodo-methane suffering partial discharge. 相似文献
58.
Arif D. SheikhAbdulsamee Fawzi V.L. Mathe 《Journal of magnetism and magnetic materials》2011,323(6):740-747
We present systematic studies that comprise phase connectivity and dielectric, multiferroic (MF) and magnetoelectric (ME) properties of (x) Ni0.8Co0.2Fe2O4+(1−x) Pb(Mg1/3Nb2/3)0.67Ti0.33O3 [where x=0.15, 0.30 and 0.45] ME composites prepared by conventional solid-state reaction method. Scanning electron microscopic images of the composites predict different types of connectivity schemes viz 3-0, 3-1 and 3-3. The phase transition temperature of PMN-PT is independent of Ni0.8Co0.2Fe2O4 content. Room temperature P-E and M-H loops indicate the simultaneous existence of ferroelectric/magnetic ordering. In order to study the possibility of monitoring electrical ordering by means of a magnetic field, ME measurements were carried out. The composition-dependent phase connectivity was well co-related to formation of percolation path and inturn magnetoelectric output. 相似文献
59.
Hadey K. Mohamad 《Journal of magnetism and magnetic materials》2011,323(1):61-66
I studied the ferrimagnetic Ising model with nearest neighbour interactions for a square lattice and simple cubic one, using mean field theory. The free energy of a mixed spin Ising ferrimagnetic model was calculated from a mean field approximation of the Hamiltonian. By minimizing the free energy, I obtained the equilibrium magnetizations and the compensation temperatures. Clear indications of the single-ion anisotropies on the compensation points of the mixed spin-3/2 and spin-5/2 ferrimagnetic lattices are found. Some interesting behaviors of these systems are obtained depending not only on the values of magnetic anisotropies for both sublattice sites but also on the lattice structure. The longitudinal magnetic fields dependence of the spin compensation temperature is the main focus of research. The possibility of many compensation temperatures is indicated. 相似文献
60.