On the temperature dependence of the surface energy of actinide crystal faces

The temperature coefficient of the surface energy has been calculated and the influence of the temperature on the anisotropy of the surface energy has been demonstrated for crystal faces of the polymorphic phases of actinides.     

Intracellular injection of phospholipids directly alters exocytosis and the fraction of chemical release in chromaffin cells as measured by nano-electrochemistry

Using a nano-injection method, we introduced phospholipids having different intrinsic geometries into single secretory cells and used single cell amperometry (SCA) and intracellular vesicle impact electrochemical cytometry (IVIEC) with nanotip electrodes to monitor the effects of intracellular incubation on the exocytosis process and vesicular storage. Combining tools, this work provides new information to understand the impact of intracellular membrane lipid engineering on exocytotic release, vesicular content and fraction of chemical release. We also assessed the effect of membrane lipid alteration on catecholamine storage of isolated vesicles by implementing another amperometric technique, vesicle impact electrochemical cytometry (VIEC), outside the cell. Exocytosis analysis reveals that the intracellular nano-injection of phosphatidylcholine and lysophosphatidylcholine decreases the number of released catecholamines, whereas phosphatidylethanolamine shows the opposite effect. These observations support the emerging hypothesis that lipid curvature results in membrane remodeling through secretory pathways, and also provide new evidence for a critical role of the lipid localization in modulating the release process. Interestingly, the IVIEC data imply that total vesicular content is also affected by in situ supplementation of the cells with some lipids, while, the corresponding VIEC results show that the neurotransmitter content in isolated vesicles is not affected by altering the vesicle membrane lipids. This suggests that the intervention of phospholipids inside the cell has its effect on the cellular machinery for vesicle release rather than vesicle structure, and leads to the somewhat surprising conclusion that modulating release has a direct effect on vesicle structure, which is likely due to the vesicles opening and closing again during exocytosis. These findings could lead to a novel regulatory mechanism for the exocytotic or synaptic strength based on lipid heterogeneity across the cell membrane.

Amperometry and intracellular vesicle impact electrochemical cytometry with nanotip electrodes were used to monitor the effects on exocytosis and vesicular storage after nano-injection of phospholipids with different geometries into secretory cells.     

Fiber optic Fabry-Perot pressure sensor with low sensitivity to temperature changes for downhole application

Pressure and temperature are two important parameters in reservoir engineering. The fiber optic sensors can be used for permanent downhole monitoring. In this paper, we propose an extrinsic fiber Fabry-Perot interferometer (EFPI) sensor for pressure measurement with low sensitivity variation. The pressure sensitivity of EFPI sensor and of the fiber Bragg grating (FBG) sensors have been measured. The experimental pressure sensitivity for EFPI and FBG sensors are measured to be 2.75 × 10⁻⁸ 1/kPa and 1.52 × 10⁻⁸ 1/kPa, respectively. The temperature cross-sensitivity problem of the EFPI sensor has been solved by a new technique. The temperature sensitivity of EFPI sensor has been decreased to 1.2 × 10⁻⁶/°C, while the temperature sensitivity of non-compensated EFPI sensor has been measured to be 16.4 × 10⁻⁶/°C. The results show that the EFPI sensor has a higher pressure sensitivity and good capability to decrease temperature sensitivity in comparison to FBG sensor.     

Synthesis,structural and complex impedance spectroscopy studies of Ni0.4Co0.4Mg0.2Fe2O4 spinel ferrite

Spinel ferrite having composition Ni_0.4Co_0.4Mg_0.2Fe₂O₄ was prepared by sol-gel method. X-ray diffraction result indicates that the ferrite sample has a cubic spinel type structure. FT-IR showed two absorption bands (ν₁ and ν₂) that are attributed to the stretching vibration of tetrahedral and octahedral sites. Complex impedance properties have been investigated in 200–420 K temperature range with varying frequency between 40 and 10⁷ Hz. Frequency and temperature dependency of imaginary part of permittivity (?″) and dielectric loss (tanδ) has been discussed in terms of hopping of charge carriers between Fe²⁺ and Fe³⁺ ions. Activation energy has been estimated from both temperature dependency of dc conductivity and relaxation time data, which indicates that the relaxation process and conductivity have the same origin. Nyquist plots of impedance show semicircle arcs for sample and an electrical equivalent circuit has been proposed to explain the impedance results.     

Electrochemical reactions of chalcogenbiscyclanones and the products of their S-, O-, and N-heterocyclization

In this work, the routes of the redox reactions of chalcogenbiscyclanones and the products of their S-, O-, N-heterocyclization in organic solvents were analyzed and validated. The influence of the nature of the heteroatoms and substituents on the redox activity of S- and Se-containing biscyclanones, benzannelated thianthrenes, oxathianthrenes, and diazepine was established based on electrochemical studies, ESR spectroscopy data, and the results of quantum chemical calculations