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Prem Pandey Supriya Chaturvedi Rutuja Gumathannavar Dr. Mandar M. Shirolkar Dr. Vijay Kanuru Prof. Dr. Atul Kulkarni Dr. Sang Hyun Moh 《ChemistryOpen》2023,12(1):e202200200
We report a facile room temperature telescoping synthesis of a nanocurcumin complex with 17.5-fold permeation enhancement as determined by comparative in vitro permeation study with raw curcumin. The permeation results were further validated with in silico drug absorption prediction using ADMET predictors. 相似文献
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Let f, g: (Rn, 0) (Rp, 0) be two C map-germs. Then f and gare C0-equivalent if there exist homeomorphism-germs h and lof (Rn, 0) and (Rp, 0) respectively such that g = l f h1.Let k be a positive integer. A germ f is k-C0-determined ifevery germ g with jk g(0) = jk f(0) is C0-equivalent to f. Moreover,we say that f is finitely topologically determined if f is k-C0-determinedfor some finite k. We prove a theorem giving a sufficient conditionfor a germ to be finitely topologically determined. We explainthis condition below. Let N and P be two C manifolds. Consider the jet bundle Jk(N,P) with fiber Jk(n, p). Let z in Jk(n, p) and let f be suchthat z = jkf(0). Define
Whether (f) < k depends only on z, not on f. We can thereforedefine the set
Let Wk(N, P) be the subbundle of Jk(N, P) with fiber Wk(n, p).Mather has constructed a finite Whitney (b)-regular stratificationSk(n, p) of Jk(n, p) Wk(n, p) such that all strata aresemialgebraic and K-invariant, having the property that if Sk(N,P) denotes the corresponding stratification of Jk(N, P) Wk(N, P) and f C(N, P) is a C map such that jkf is multitransverseto Sk(N, P), jkf(N) Wk(N, P) = and N is compact (or f is proper),then f is topologically stable. For a map-germ f: (Rn, 0) (Rp, 0), we define a certain ojasiewiczinequality. The inequality implies that there exists a representativef: U Rp such that jkf(U 0) Wk (Rn, Rp = and suchthat jkf is multitransverse to Sk (Rn, Rp) at any finite setof points S U 0. Moreover, the inequality controlsthe rate jkf becomes non-transverse as we approach 0. We showthat if f satisfies this inequality, then f is finitely topologicallydetermined. 1991 Mathematics Subject Classification: 58C27. 相似文献
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Sahib M. A. A. B. Zulkipli Nur Farhanah Rosol Ahmad Haziq Aiman Yasin Moh Harun Sulaiman Wadi 《Journal of Russian Laser Research》2022,43(3):328-333
Journal of Russian Laser Research - We propose a MXene Ti3C2Tx thin-film and demonstrate as saturable absorber (SA) to generate mode-locked laser pulses. In constructing the SA, titanium carbide... 相似文献
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Moh PY Cubillas P Anderson MW Attfield MP 《Journal of the American Chemical Society》2011,133(34):13304-13307
Crystalline nanoporous materials are one of the most important families of complex functional material. Many questions pertaining to the molecular assembly mechanism of the framework of these materials remain unanswered. Only recently has it become possible to answer definitively some of these questions by observation of growing nanoscopic surface features on metal organic frameworks (MOFs) through use of in situ atomic force microscopy (AFM). Here we reveal that a growth process of a MOF, zeolitic imidazolate framework ZIF-8, occurs through the nucleation and spreading of successive metastable unenclosed substeps to eventually form stable surface steps of the enclosed framework structure and that this process is reliant on the presence of nonframework species to bridge the developing pores during growth. The experiments also enable identification of some of the fundamental units in the growth process and the stable crystal surface plane. The former findings will be applicable to numerous nanoporous materials and support efforts to synthesize and design new frameworks and to control the crystal properties of these materials. 相似文献
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Zakaria Umi Namirah Paul Mukul Chandra Das Shyamal Dhar Anirban Zulkipli Nur Farhanah Rosol Ahmad Haziq Aiman Yasin Moh Harun Sulaiman Wadi 《Journal of Russian Laser Research》2022,43(3):339-345
Journal of Russian Laser Research - We successfully demonstrate Q-switched fiber laser with a 20 cm long Hafnium-Bismuth-Erbium codoped fiber (HBEDF) as an active medium in conjunction with... 相似文献
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Chunyin Law Yan Meng Seung Moh Koo James P. Morken 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(20):6726-6730
β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates. 相似文献
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Herein, we give a detailed experimental analysis for scaling law behavior in the "moderately dense" and "high-density" brush regimes for poly(methyl methacrylate) brushes swollen in a range of solvent conditions. This expansive experimental analysis aims to validate decades of mean field theory predictions on power law scaling behavior of grafted polymer chains. Brushes with grafting densities (σ) ranging from 0.1 to 0.8 nm(-2) are prepared by atom-transfer radical polymerization. The swollen thickness (h) is characterized using liquid cell ellipsometry, and the solvent quality is varied using mixtures of acetone and methanol. In a good solvent, the exponential scaling behavior (h ∝ σ(n)) has the typical n = 1/3 dependency for grafting densities of σ ≤ 0.4 nm(-2). For grafting densities of >0.4 nm(-2), n increases, indicating the transition from the moderately dense to the high-density brush regime. However, in a poor solvent, the scaling behavior is independent of σ and scales as h ∝ σ(0.80), approaching the theoretical expectations of h ∝ σ(1). An abrupt transition between these scaling law behaviors occurs at the Θ-solvent condition of ~45% (v/v) methanol in acetone. While our experimental results parallel trends predicted by mean field theory, differences are observed and appear to be attributed to self-solvation of the polymer, polydispersity in the molecular weight, and chain termination. 相似文献
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A simple and sensitive high-performance liquid chromatographic method for the determination of Therminol 66 thermal heating fluid in glycerin and fatty acids is developed. Sample solutions dissolved in methanol-tetrahydrofuran (50:50, v/v) are injected directly into a reversed-phase C18 column and eluted with a methanol and water mixture (88:12, v/v). The concentration of the thermal heating fluid is monitored by fluorescence detection at 257 nm (excitation) and 320 nm (emission). The calibration graph obtained from various concentrations of the thermal heating fluid in the methanol and tetrahydrofuran mixture is linear (correlation coefficient = 0.999), and the limit of detection is 0.01 microg/mL. Spiked glycerin containing 0.1 to 1.0 microg/g of the thermal heating fluid also gives good linearity with a mean recovery of 95.3%. The mean intra- and interassay precision are 1.80-6.51% and 5.71-9.03%, respectively, at the 0.1-microg/g level. The method is simple and does not require any pretreatment step, thus it is ideal for quality assurance purposes. 相似文献