全文获取类型
收费全文 | 351411篇 |
免费 | 5641篇 |
国内免费 | 1103篇 |
专业分类
化学 | 193636篇 |
晶体学 | 4682篇 |
力学 | 13625篇 |
综合类 | 8篇 |
数学 | 44224篇 |
物理学 | 101980篇 |
出版年
2021年 | 2134篇 |
2020年 | 2608篇 |
2019年 | 2543篇 |
2018年 | 2868篇 |
2017年 | 2704篇 |
2016年 | 5328篇 |
2015年 | 4485篇 |
2014年 | 5644篇 |
2013年 | 16577篇 |
2012年 | 13137篇 |
2011年 | 15633篇 |
2010年 | 9796篇 |
2009年 | 9521篇 |
2008年 | 14268篇 |
2007年 | 14292篇 |
2006年 | 13745篇 |
2005年 | 12720篇 |
2004年 | 11362篇 |
2003年 | 9924篇 |
2002年 | 9659篇 |
2001年 | 10697篇 |
2000年 | 8373篇 |
1999年 | 6586篇 |
1998年 | 5269篇 |
1997年 | 5071篇 |
1996年 | 5226篇 |
1995年 | 4687篇 |
1994年 | 4508篇 |
1993年 | 4306篇 |
1992年 | 4826篇 |
1991年 | 4595篇 |
1990年 | 4329篇 |
1989年 | 4079篇 |
1988年 | 4362篇 |
1987年 | 4025篇 |
1986年 | 3925篇 |
1985年 | 5637篇 |
1984年 | 5679篇 |
1983年 | 4613篇 |
1982年 | 4994篇 |
1981年 | 5044篇 |
1980年 | 4754篇 |
1979年 | 4843篇 |
1978年 | 4857篇 |
1977年 | 4838篇 |
1976年 | 4776篇 |
1975年 | 4687篇 |
1974年 | 4534篇 |
1973年 | 4691篇 |
1972年 | 2686篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Laguel Yassine Pillutla Krishna Malick Jérôme Harchaoui Zaid 《Set-Valued and Variational Analysis》2021,29(4):967-996
Set-Valued and Variational Analysis - R. Tyrell Rockafellar and his collaborators introduced, in a series of works, new regression modeling methods based on the notion of superquantile (or... 相似文献
12.
13.
Li Y. Shi W. H. Dong L. M. Xu S. X. Huang H. J. Yin J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,... 相似文献
14.
15.
Restricted testing conditions were considered recently. For the maximal operator, Hytönen, Li and Sawyer [8] first obtained parental testing condition. Later, they [9] showed that it suffices to restrict testing to doubling cubes. Chen and Lacey [3] gave a similar restricted testing condition. In our paper, we discuss a version of the latter in the multilinear setting.
相似文献16.
S. Venkatesan S. Suresh P. Ramu M. Kandasamy J. Arumugam S. Thambidurai K.M. Prabu N. Pugazhenthiran 《印度化学会志》2022,99(5):100436
A facile biosynthesis route was followed to prepare zinc oxide nanoparticles (ZnO NPs) using Euphorbia milii (E. milii) leaf constituents. The SEM images exhibited presence of spherical ZnO NPs and the corresponding TEM images disclosed monodisperse nature of the ZnO NPs with diameter ranges between 12 and 20 nm. The Brunauer–Emmett–Teller (BET) analysis revealed that the ZnO NPs have specific surface area of 20.46 m2/g with pore diameter of 2 nm–10 nm and pore volume of 0.908 cm3/g. The EDAX spectrum exemplified the existence of Zn and O elements and non-appearance of impurities that confirmed pristine nature of the ZnO NPs. The XRD pattern indicated crystalline peaks corresponding to hexagonal wurtzite structured ZnO with an average crystallite size of 16.11 nm. The FTIR spectrum displayed strong absorption bands at 512 and 534 cm?1 related to ZnO. The photocatalytic action of ZnO NPs exhibited noteworthy degradation of methylene blue dye under natural sunlight illumination. The maximum degradation efficiency achieved was 98.17% at an illumination period of 50 min. The reusability study proved considerable photostability of the ZnO NPs during photocatalytic experiments. These findings suggest that the E. milii leaf constituents can be utilized as suitable biological source to synthesis ZnO NPs for photocatalytic applications. 相似文献
17.
Tomáš Hložek Martin Štícha Miroslava Bursová Ivan Jelínek Petr Tůma Radomír Čabala 《Electrophoresis》2020,41(18-19):1564-1567
Riociguat is novel antihypertensive drug for treatment of pulmonary hypertension. As such, it is still being tested in many clinical and pharmacokinetic trials. Existing methods that determine serum riociguat and desmethylriociguat (DMR) are based solely on liquid chromatography with mass spectrometry. Therefore, we present a novel capillary electrophoresis with mass spectrometry method (CE-MS) for their determination in human serum as alternative method for ongoing trials. Complete resolution of both analytes was achieved by means of pH optimization of ammonium formate background electrolytes that are fully compatible with ESI/MS detection. Simple liquid-liquid extraction was used as sample pretreatment. The calibration dependence of the method was linear (in the range of 10–1000 ng/mL), with adequate accuracy (90.1–114.9%) and precision (13.4%). LOD and LOQ were arbitrarily set at 10 ng/mL for both analytes. Clinical applicability was validated using serum samples from patients treated with riociguat in pharmacokinetic study and the results corresponded with reference HPLC-MS/MS values. Capillary electrophoresis proved to be sensitive and selective tool for the analysis of riociguat and DMR. 相似文献
18.
19.
Haixing Guan Qianwen Zhang Prof. Dr. Patrick J. Walsh Prof. Dr. Jianyou Mao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(13):5210-5215
A unique nickel/organic photoredox co-catalyzed asymmetric reductive cross-coupling between α-chloro esters and aryl iodides is developed. This cross-electrophile coupling reaction employs an organic reductant (Hantzsch ester), whereas most reductive cross-coupling reactions use stoichiometric metals. A diverse array of valuable α-aryl esters is formed under these conditions with high enantioselectivities (up to 94 %) and good yields (up to 88 %). α-Aryl esters represent an important family of nonsteroidal anti-inflammatory drugs. This novel synergistic strategy expands the scope of Ni-catalyzed reductive asymmetric cross-coupling reactions. 相似文献
20.
Attila Kovács 《International journal of quantum chemistry》2020,120(1):e26051
Lanthanide dinitrogen complexes, Ln(N2) x (x = 1-8), were investigated by Density Functional Theory computations using the B3LYP exchange-correlation functional in conjunction with quasirelativistic pseudopotentials for Ln. After a recent study on the lanthanum complexes (A. Kovács, Structural Chemistry 2018 , 29, 1825), the present study aimed to probe the changes upon variously filled 4f subshells of Ln on the structures, stabilities, and bonding properties in related complexes of Nd, Ho, and Lu. The bonding properties were assessed on the basis of natural atomic charges, Ln valence orbital populations, and analysis of bonding molecular orbitals. 相似文献