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排序方式: 共有221条查询结果,搜索用时 15 毫秒
31.
Geng F Xin H Matsushita Y Ma R Tanaka M Izumi F Iyi N Sasaki T 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(30):9255-9260
We report the synthesis of a new series of layered hydroxides based on rare-earth elements with a composition of RE(OH)2.5Cl(0.5).0.8 H2O (RE: Eu, Tb, etc.) through the homogeneous precipitation of RECl3.x H2O with hexamethylenetetramine (HMT). Rietveld analysis combined with direct methods revealed an orthorhombic layered structure comprising a positively charged layer of [RE(OH)2.5-(H2O)0.8]0.5+ and interlayer Cl- ions. The Cl- ions were readily exchangeable for various anions (NO3-, SO4(2-), dodecylsulfonate, etc.) at ambient temperature. Photoluminescence studies showed that the compounds display typical RE3+ emission. With rare-earth-based host layers and tunable interlayer guests, the new compounds may be of interest for optoelectronic, magnetic, catalytic, and biomedical materials. 相似文献
32.
The enantiomeric resolution of N-t-butyloxycarbonyl (N-t-Boc) amino acids D/L isomers by reversed-phase HPLC was investigated using cyclodextrins (CD's) as chiral selectors for the mobile phase. The use of a low pH (pH<4) for the mobile phase enabled the enantioseparation of N-t-Boc amino acids. The opposite elution order of D/L isomers was observed when hydroxypropyl-derivatized beta-CD was used instead of native beta-CD. A computer simulation of the enantioseparation showed that the ratio of the retention factors of the chiral selector and the sample determined the elution order and the resolution. When the retention factor of the chiral selector is smaller than that of the sample, an isomer having larger complex formation constant eluted faster. However, when the chiral selector had a larger retention factor than the sample, an opposite elution order of the isomers was obtained. The large difference in the retention factors between the chiral selector and the sample led to good enantiomeric separation. 相似文献
33.
Yoshio Iwakura Fujio Toda Kenjiro Hattori 《Journal of polymer science. Part A, Polymer chemistry》1968,6(6):1633-1642
New vinylsilanes (M2), i. e. phenylvinylsilane (I), allylmethylsilane (II), allylphenylsilane (III), and p-vinylphenylmethylsilane (IV), were prepared and copolymerized with styrene (M1). The monomer reactivity ratios were r1 = 5.7 and r2 = 0, r1 = 36 and r2 = 0, r1 = 29 and r2 = 01, and r1 = 0.91 and r2 = 1.1, respectively. From the results of infrared and NMR spectra it was indicated that the vinylsilanes participated in copolymerization in the form of a vinyl type of polymerization and not in the form of a hydrogen-transfer type of polymerization. The reaction of copolymer with alcohols and methyl methacrylate and appropriate catalysts was investigated. 相似文献
34.
Hideo Inaba Fujio Komatsu Akihiko Horibe Naoto Haruki Akito Machida 《Heat and Mass Transfer》2008,44(11):1305-1313
This paper describes heat and mass transfer characteristics of organic sorbent coated on heat transfer surface of a fin-tube
heat exchanger. The experiments in which the moist air was passed into the heat exchanger coated with sorption material were
conducted under various conditions of air flow rate (0.5–1.0 m/s) and the temperature of brine (14–20°C) that was the heat
transfer fluid to cool the air flow in the dehumidifying process. It is found that the sorption rate of vapor is affected
by the air flow rate and the brine temperature. Meanwhile, the attempt of clarifying the sorption mechanism is also conducted.
Finally the average mass transfer coefficient of the organic sorbent coated on heat transfer surface of a fin-tube heat exchanger
is non-dimensionalzed as a function of Reynolds number and non-dimensional temperature, and it is found that the effect of
non-dimensional temperature on them is larger than Reynolds number . 相似文献
35.
In the present paper, the algorithm of Binary Image Cross-Correlation (BICC) was developed to measure the unsteady flow field.
A vortex flow field was used to test the algorithm by numerical simulation. The results show that BICC is an effective algorithm
for particle identification from consecutive images, the accurate velocity vector field can be obtained. The real velocity
field in a valve chamber was measured by BICC in this study. From the full-field velocity information, the pressure and vorticity
fields were also extracted by post-processing.
The project supported by the National Natural Science Foundation of China 相似文献
36.
Mechanical Characterization Measurement of Polymer Material under Stress by Birefringence Microscope
Some polymer materials under tensile stress provide us interesting information. Internal structure changes of polymer materials
must be observed by external stress. Birefringence shows the orientation characteristic in molecular orientation. A microscopic
measurement system for birefringence distribution is proposed to analyze the relation between applied stress and birefringence
distribution of an internal structure. Birefringence distributions of gelatin such as phase difference and azimuthal angle
are shown in cases of loading and unloading stress as a demonstration. The phase difference increased nonlinearly with each
process, and change of birefringence in the elastic domain was different from that in the plastic domain. 相似文献
37.
Urita K Shiga Y Fujimori T Iiyama T Hattori Y Kanoh H Ohba T Tanaka H Yudasaka M Iijima S Moriguchi I Okino F Endo M Kaneko K 《Journal of the American Chemical Society》2011,133(27):10344-10347
An outstanding compression function for materials preparation exhibited by nanospaces of single-walled carbon nanohorns (SWCNHs) was studied using the B1-to-B2 solid phase transition of KI crystals at 1.9 GPa. High-resolution transmission electron microscopy and synchrotron X-ray diffraction examinations provided evidence that KI nanocrystals doped in the nanotube spaces of SWCNHs at pressures below 0.1 MPa had the super-high-pressure B2 phase structure, which is induced at pressures above 1.9 GPa in bulk KI crystals. This finding of the supercompression function of the carbon nanotubular spaces can lead to the development of a new compression-free route to precious materials whose syntheses require the application of high pressure. 相似文献
38.
Image analysis applied to study on frictional-drag reduction by electrolytic microbubbles in a turbulent channel flow 总被引:1,自引:0,他引:1
We investigate frictional-drag reduction with electrolytic microbubbles based on image measurement of a turbulent flow in
a water channel at Re = 4800 (based on the half channel height). Microbubbles with a diameter ranging 30–200 μm can reduce frictional drag by as
much as 30% relative to single-phase flow even at low void fractions (α ≈ 3 × 10−4); however, drag reduction is only effective within a limited downstream distance from an electrode array. Arrangement of
the optical system allows us to measure the bubble-production rate by water electrolysis from images near the wall and to
trace the motion of bubbles. We also measure velocity fields using particle-tracking velocimetry based on a shallow depth-of-field
approach by segregating tracer particles from microbubbles. Vertically oscillating microbubbles likely represent interaction
with vortical structures near the wall, and bubbles approaching the wall appear to induce negative streamwise velocity relative
to the surrounding fluid. We relate the wall friction with the double integral of the Reynolds-stress profile and show that
its variation due to microbubbles decreases the drag on the wall. Microbubbles tend to coalesce downstream resulting in a
fewer bubbles but with greater size; accordingly, the oscillatory motion diminishes, and the frictional drag rather increases. 相似文献
39.
40.
Yoshio Iwakura Fujio Toda Yoshinori Torii Katsuaki Murata 《Journal of polymer science. Part A, Polymer chemistry》1968,6(4):785-791
Polyamideamines with a sequence of two amide and one amine linkage in a main chain were synthesized from the polyaddition of 2-isopropylidene-4-alkyl-3-oxazolin-5-ones and primary diamines. The polyaddition reaction proceeded through 1,4-conjugate addition of an amine group to 3-oxazolin-5-one and subsequent ring opening of the intermediate addition product with another amine. Although aliphatic diamines gave oily polymers, xylylenediamines afforded amorphous solid polymers. The reduced viscosities and polymer melt temperature of the polymers were 0.05–0.12 and 90–130°C., respectively. 相似文献