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101.
T
ru Tagawa Hideo Amemiya Isao Shinohara Miyuki Hagiwara Tsutomu Kagiya 《Journal of polymer science. Part A, Polymer chemistry》1975,13(12):2843-2847
At 200°C, temperature-induced transformations of peroxide radicals from ? CF2CF(OO·)CF2? (radical I) to ? CF2CFCF2? (radical 1) and ? CF2CF2OO· (radical II) to ? CF2CF2 (radical 2) in vacuo, and from I to II in oxygen atmosphere were observed. In these thermal transformations, the evolution of CO2 with a small amount of CO and CF2O was observed. Further, measurements of the heat of crystallization of the treated polytetrafluoroethylene suggest that a reduction of polymer molecular weight occurs during the transformations from I to 1 and I to II. 相似文献
102.
Ono M Anzai H Tozuka Y Moribe K Oguchi T Yamamoto K 《Chemical & pharmaceutical bulletin》2005,53(2):180-183
Pseudopolymorphism of sodium deoxycholate (NaDC) was investigated. Intact NaDC (dihydrate) was dried at 60 degrees C under reduced pressure resulting an anhydrous amorphous phase. On the other hand, intact NaDC was altered to an anhydrous crystalline form by heating at 200 degrees C. The water vapor adsorption and desorption isotherms of dehydrated NaDCs were determined using an automatic gravimetric water vapor adsorption analyzer. In the case of NaDC dehydrated at 60 degrees C, the weight was increased in rising relative humidity and it was transformed into the NaDC tetrahydrate above 60% RH, which was identified by TG/DTA and powder X-ray diffraction. During the water vapor adsorption process of the sample dehydrated at 200 degrees C, the NaDC dihydrate was obtained in the range of 50 to 70% RH and then transformed into the NaDC octahydrate above 85% RH. The NaDC octahydrate was characterized by TG/DTA and powder X-ray diffraction for the first time. During the desorption process, the octahydrate was changed to the tetrahydrate between 80 and 40% RH. 相似文献
103.
Nobuhiro Anzai Hiroko Kurihara Masato Sone Hidemitsu Furukawa Toshiyuki Watanabe Kazuyuki Horie Sandeep Kumar 《Liquid crystals》2006,33(6):671-679
We have found that the discotic nematic liquid crystal, hexakis(4-nonylphenylethynyl)benzene (HNEB), doped with the racemic chromium complex Cr(Ocacac)3, shows a novel straight-needle texture with hexagonal columnar alignments, changing to a curved-needle texture under irradiation of circularly polarized light (CPL). This novel phenomenon is specific to the mixture of HNEB and Cr(Ocacac)3. The formation of curved needles means that chiroselective photoinversion of racemic Cr(Ocacac)3 by CPL irradiation induces a needle direction change in a discotic liquid crystal. The change in chirality of Cr(Ocacac)3 in HNEB induced by CPL irradiation, and the resulting nano-segregation of its enantiomers during cooling from the isotropic to mesophase of HNEB, are considered to influence changes in the alignment of columns and/or small domains of column aggregates in the discotic liquid crystal. 相似文献
104.
Two epimeric carotenoids, named dinochromes A (2) and B (3), were isolated from the fresh water red tide Peridinium bipes, as anti-carcinogenic compounds. The stereostructure of dinochrome A and B were characterized to be (3S,5R,6R,3'S,5'R,8'R)- and (3S,5R,6R,3'S,5'R,8'S)-5',8'-epoxy-6,7-didehydro-5,6,5',8'-tetrahydro-beta,beta-carotene-3,5,3'-triol 3-O-acetate, respectively by (1)H- and (13)C-NMR, and circular dichroism (CD) data. Dinochromes A (2) and B (3) inhibit 12-O-tetradecanoyl phorbol 13-acetate (TPA)-stimulated (32)P-incorporation into the phosholipids of HeLa cells. Furthermore, dinochrome A was found to inhibit the proliferation of human malignant tumor cells, such as GOTO, OST and HeLa cells. 相似文献
105.
Kasajima N Ito H Hatano T Yoshida T Kaneda M 《Chemical & pharmaceutical bulletin》2005,53(10):1345-1347
Three new acylated flavonol glycosides, cypellogins A (1), B (2) and C (3), along with eight known phenolic compounds, were isolated from the dried leaves of Eucalyptus cypellocarpa, and their structures were elucidated using spectroscopic methods, including 2D NMR experiments and chemical evidence. 相似文献
106.
Hiroshi Mitsui Fumio Hosoi Miyuki Hagiwara Tsutomu Kagiya 《Journal of polymer science. Part A, Polymer chemistry》1968,6(10):2881-2888
The effects of acetylene on the γ-radiation-induced polymerization of ethylene were studied from the viewpoint of the gaseous products and polymer structure. The experiments were carried out under a pressure of 400 kg/cm2; the temperature was 30°C; the does rate was 1.1 × 105 rad/hr; and the acetylene content was 0–20%. The solid polymer was obtained in the polymerization of ethylene containing 2.2% acetylene, while the monomer containing 19.7% acetylene gave a yellowish viscous oil. The polymer yield and molecular weight decreased remarkably with acetylene content. The main gaseous product was hydrogen, and trace amounts of butane, butene-1, butadiene-1,3, and benzene and its derivatives were also observed. The rate of formation of hydrogen was almost independent of acetylene content and there was no difference in acetylene contents before and after the irradiation was found. The infrared spectra of the polymers showed the presence of vinylidene, trans-vinylene, and terminal vinyl unsaturations, 1,4-disubstituted benzene, and carbonyl groups. The contents of trans-vinylene, terminal vinyl, and methyl groups increased with acetylene content, and that of vinylidene was independent of acetylene content. The monomer reactivity ratios of ethylene and acetylene were evaluated as 45.5 and 66.0, respectively. On the basis of the results, the effects of acetylene on the γ-radiation-induced polymerization of ethylene were discussed. 相似文献
107.
Hiroshi Mitsui Sueo Machi Miyuki Hagiwara Fumio Hosoi Tsutomu Kagiya 《Journal of polymer science. Part A, Polymer chemistry》1967,5(11):2731-2743
The effects of oxygen on the γ-radiation-induced polymerization of ethylene were studied at a temperature of 30°C.; the pressure was 400 kg./cm.2, the dose rate was 1.9 × 105 rad/hr.; and oxygen content was from 1–2000 ppm. The main product was solid polymer, and no liquid product was found. The gaseous products were hydrogen, acetylene, higher hydrocarbons, carbon dioxide, aldehydes, and acids. Several kinds of carbonyls similar to those formed in γ-ray oxidized polyethylene were observed in the polymer. The polymer yield and the degree of polymerization decreased markedly with increasing oxygen content, while the amount of carbonyls in the polymer increased. The number of moles of polymer chain and the amounts of hydrogen and acetylene were found to be almost independent of the oxygen content. The polymerization of pure ethylene was not affected by carbon dioxide and formic acid. On addition of acetaldehyde, the polymer yield and the degree of polymerization decreased markedly, while the number of moles of polymer chain increased. In the polymerization of ethylene containing oxygen, both the rate of oxygen consumption and the carbonyl content of the polymer increased, while the inhibition period decreased by the addition of acetaldehyde. It was found that the degree of polymerization after the inhibition period is almost independent of the reaction time in the presence of acetaldehyde, while it increases with the time in the absence of acetaldehyde. 相似文献
108.
Yanagi T Mizoguchi J Adachi T Sato S Kodama K Anzai K Takagishi Y Kamei C Fujiwara M Matsushita T Yamashoji Y Inoue Y 《Chemical & pharmaceutical bulletin》2000,48(3):366-369
For 4-amino-5-chloro-2-methoxy-N-[(2S,4S)-1-ethyl-2-hydroxymethyl-4-pyrrolid inyl]benzamide (TKS159), two polymorphs, forms alpha and beta, were prepared and characterized by means of X-ray powder diffractometry, thermal analysis, infrared spectroscopy and 13C-NMR spectroscopy, both in the solution and solid phases. The X-ray powder diffraction analysis gave different patterns for forms alpha and beta. In the thermogravimetry and differential thermal analysis profiles, form beta exhibited characteristic endo- and exothermic peaks at 112.7 degrees C and 116.2 degrees C, respectively, due to the partial melting-induced phase transition to form alpha without accompanying weight loss, and these were followed by an additional endothermic peak at 138.2 degrees C due to fusion. For form alpha, only an endothermic peak at 137.8 degrees C due to fusion was observed. The IR spectroscopic analyses of forms alpha and beta gave different absorption bands assigned to N-H and O-H stretching, N-H bending, and C=O stretching vibrations. From the data obtained by thermal analysis, form alpha was shown to be thermodynamically more stable than form beta. 相似文献
109.
Kazukiyo Nagai Miyuki Mori Tetsuya Watanabe Tsutomu Nakagawa 《Journal of Polymer Science.Polymer Physics》1997,35(1):119-131
The poly(1-trimethylsilyl-1-propyne) (PMSP) has the potential to be an important membrane gas separation material due to the fact that it has the highest gas permeability of all polymeric membranes. One problem with PMSP is a decrease in the gas permeability with age. In order to understand the aging processes, we studied the change in free volume and the molecular motions of the PMSP and its membranes modified with 1-phenyl-1-propyne (PP) structures; that is, a copolymer and a blend of PMSP and PPP. During aging, the unrelaxed volume of the PMSP membrane was relaxed, and the molecular motion of carbons dropped, suggesting that the decrease in the microvoids caused a tighter chain packing. The copolymer and blend membrane had stable permeability compared to the PMSP. In particular, the addition of a small amount of the PP structure provided excellent stability with high gas permeability. A decrease in the unrelaxed volume of modified membranes was hardly observed with age; however, the molecular motion of some carbons slightly changed. This change did not affect the gas permeability. In this case, a larger unrelaxed volume was probably a dominant factor in the gas permeation of the PMSP rich membranes relative to the molecular motion in the T1 measurement. © 1997 John Wiley & Sons, Inc. 相似文献
110.
J.-C. Lasjaunias K. Biljaković D. Starešinić P. Monceau S. Takasaki J. Yamada S.-I. Nakatsuji H. Anzai 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,7(4):541-550
We report on specific heat measurements of the quasi-one-dimensional organic salt (TMTSF)2AsF6 in its spin density wave state between 75 mK and 7 K. Similarly to (TMTSF)2PF6, we find discontinuities in the lattice contribution at 1.9 K an d 3.5 K ascribed to sub-spin density wave phases. Time-dependent
effects due to dynamics of low-energy excitations in metastable states occur only below 0.2 K which yields an activation energy
for the equilibrium energy relaxation process of 0.34 K, 4-5 times smaller than found for (TMTSF)2PF6. Finally the reduction of the low-energy excitations contribution to the specific heat in comparison to PF6 reveals an intermediate cubic-like regime between 0.25 and 0.5 K that we tentatively describe as the phason contribution
of the incommensurate spin density wave modulation.
Received: 17 March 1998 / Revised: 27 July 1998 / Accepted: 22 September 1998 相似文献