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81.
In a previous paper we reported a study of the electronic structures of inner valence states of O(2) (+) and the dissociation process, where there remained some questions as to the origins of the dissociation fragment formation of the O+((2)D)+O((3)P) limit in observed spectra. In this paper, we present the results of calculations of the nonadiabatic transition probabilities of the multichannel dissociation process from the inner valence states of O(2) (+) and reproduce the general features of observed spectra previously reported, including fragment formation, using the Zhu-Nakamura theory. 相似文献
82.
The maximum asymptotic bias of an S-estimate for regression in the linear model is evaluated over the neighborhoods (called (c,γ)-neighborhoods) defined by certain special capacities, and its lower and upper bounds are derived. As special cases, the (c,γ)-neighborhoods include those in terms of -contamination, total variation distance and Rieder's (,δ)-contamination. It is shown that when the model distribution is normal and the (,δ)-contamination neighborhood is adopted, the lower and upper bounds of an S-estimate (including the LMS-estimate) based on a jump function coincide with the maximum asymptotic bias. The tables of the maximum asymptotic bias of the LMS-estimate are given. These results are an extension of the corresponding ones due to Martin et al. (Ann. Statist. 17 (1989) 1608), who used -contamination neighborhoods. 相似文献
83.
K Umetsu M Tanaka I Yuasa N Saitou I Takeyasu N Fuku E Naito K Ago N Nakayashiki A Miyoshi S Kashimura G Watanabe M Osawa 《Electrophoresis》2001,22(16):3533-3538
A number of mutations in coding and noncoding regions of mitochondrial DNA (mtDNA) have previously been studied. In the present study, we simultaneously typed six mutation sites in the coding region by use of amplified product-length polymorphism (APLP) analysis. The mtDNA variations of 2471 individuals from 20 populations of Japanese, Korean, Chinese, and German were examined and classified into 18 haplotypes. Two of these haplotypes, B1 (estimated ancestral haplotype) and C1, were distributed among all populations tested. However, the haplotypes A1, A2, B2, B3, and C2 were mostly restricted to the Mongoloid populations, whereas haplotypes B5 and C5 appeared almost exclusively in the German population. Phylogenetic analysis by the neighbor-joining method revealed that the Japanese populations were more closely related to each other than to the other East Asian populations surveyed. The multiplex APLP method is suitable for large-scale screening studies of mtDNA variability because it is both rapid and economical. 相似文献
84.
Dr. Hiroshi Hinou Risho Miyoshi Yasuaki Takasu Hirokazu Kai Dr. Masaki Kurogochi Dr. Shingo Arioka Dr. Xiao‐Dong Gao Dr. Nobuaki Miura Dr. Naoki Fujitani Dr. Shinya Omoto Dr. Tomokazu Yoshinaga Dr. Tamio Fujiwara Dr. Takeshi Noshi Dr. Hiroko Togame Prof. Hiroshi Takemoto Prof. Shin‐Ichiro Nishimura 《化学:亚洲杂志》2011,6(4):1048-1056
A potent inhibitor for Vibrio cholerae neuraminidase (VCNA) was developed by using a novel two‐step strategy, a target amino acid validation using mechanism‐based labeling information, and a potent inhibitor search using a focused library. The labeling information suggested the hidden dynamics of a loop structure of VCNA, which can be a potential target of the novel inhibitor. A focused library composed of 187 compounds was prepared from a 9‐azide derivative of 2,3‐dehydro‐N‐acetylneuraminic acid (DANA) to interrupt the function of the loop of the labeled residues. Inhibitor 3c showed potent inhibition properties and was the strongest inhibitor with FANA, a N‐trifluoroacetyl derivative of DANA. Validation studies of the inhibitor with a detergent and a Lineweaver–Burk plot suggested that the 9‐substitution group would interact hydrophobically with the target loop moiety, adding a noncompetitive inhibition property to the DANA skeleton. This information enabled us to design compound 4 having the combined structure of 3c and FANA. Compound 4 showed the most potent inhibition (Ki=73 nM , mixed inhibition) of VCNA with high selectivity among the tested viral, bacterial, and mammal neuraminidases. 相似文献
85.
Speckle is a random distribution of a radiant power density or an irradiance on the observation plane (retina of observers in the laser display) due to the interference of randomly phase-modulated wavefronts. Since a color is synthesized by the superposition of red-green-blue (RGB) primary-color lasers in laser displays, if the speckle patterns of RGB lasers are uncorrelated with each other, then the fluctuation in radiant power density results in a change in color received by the observer. We name this random distribution of color “color speckle”. The distribution of color on the xy chromaticity diagram is investigated for speckle patterns of various speckle contrasts. We demonstrate a numerical simulation of color speckle. Then, we derive the theoretical expressions of the variance and covariance of the distribution of xy chromaticity under the assumption of low speckle contrast. 相似文献
86.
87.
Y Kobayashi M. K. Kubo Y. Yamada T. Saito H. Ueno H. Ogawa W. Sato K. Yoneda H. Watanabe N. Imai H. Miyoshi K. Asahi 《Journal of Radioanalytical and Nuclear Chemistry》2003,255(3):403-406
In-beam Mössbauer spectra of 57Fe, decayed from short-lived 57Mn (T1/2 = 1.45 min) implanted into potassium permanganate, KMnO4, were measured at temperatures between 11 K and 130 K. This is the first application of a secondary RI beam to the study of valence states after nuclear transformation. The in-beam Mössbauer spectra obtained below 90 K could be analyzed with two components, a doublet and a singlet. From the calculations of the molecular orbital wave functions, the singlet is suggested to be substitutional 57Fe atoms for Mn-sites in tetrahedral [MnO4]– with an unusually high valence state of Fe8+. 相似文献
88.
Y. Kobayashi H. Nonaka J. Miyazaki M. K. Kubo H. Ueno A. Yoshimi H. Miyoshi D. Kameda K. Shimada D. Nagae K. Asahi Y. Yamada 《Hyperfine Interactions》2005,166(1-4):357-361
The in-beam Mössbauer spectroscopy using a short-lived 57Mn (T 1/2=1.5 min) beam was carried out to study the production of the exotic chemical species of 57Fe atoms arising from 57Mn implanted into solid oxygen. The obtained spectra can be analyzed by four components of doublets at least, which are assigned to be novel Fe species of FeO, Fe(O2), (O2)FeO2, and Fe(O2)2, on the basis of ab initio molecular orbital calculations. 相似文献
89.
90.