全文获取类型
收费全文 | 142篇 |
免费 | 8篇 |
专业分类
化学 | 114篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 6篇 |
物理学 | 26篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 9篇 |
2012年 | 8篇 |
2011年 | 11篇 |
2010年 | 3篇 |
2009年 | 6篇 |
2008年 | 12篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 7篇 |
2004年 | 14篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有150条查询结果,搜索用时 46 毫秒
51.
52.
Abstract Depth profiles of nitrogen implanted into Zr with an energy of 50 keV were calculated by dynamic SASAMAL code with three different assumptions for the diffusion of excess atoms over stoichiometry, i.e., ‘no diffusion', ‘both-sides-diffusion’ and ‘upward-diffusion'. To distinguish nitrogens implanted certain stage of implantations, alternate implantations of 15N and 14N were used. The results were compared with the experimental results by the resonance nuclear reaction analysis, NRA. For 15N implantation with fluences from 1 × 1017 to 1 × 1018 ions/cm2, the calculated results with ‘upward-diffusion’ agreed very well with the NRA results for all fluences. For the depth profile of pre-implanted 15N (1 × 1017 ions/cm2), which was changed by the subsequent 14N implantation with fluences of 1 ~ 10 × 1017 ions/cm2, the agreement with the NRA results was satisfactory until the 14N fluence did not exceed 5 × 1017 ions/cm2, but for higher fluences, the retained probabilities of 15N obtained by the ‘upward-diffusion’ code were too low compared with the experimental value obtained by NRA. For the depth profiles of 15N (1 × 1017 ions/cm2) implanted following after implantations of 14N with fluences of 1 ~ 10 × 1017 ions/cm2, the agreement with the NRA results was quite good for all 14N fluences. It is concluded that the approximation of ‘upward-diffution’ is proper satisfactorily for the treatment of atoms implanted at the final stage of implantations, but a problem is left for the treatment of atoms implanted at the early stage of implantations. 相似文献
53.
The mechanism of nonmagnetic Mott transitions in the Hubbard model on the square lattice is studied, using a variational Monte Carlo method. A simple doublon (D)–holon (H) binding mechanism a previous study proposed [J. Phys. Soc. Jpn. 75 (2006) 114706] has to be modified, because even a wave function with completely bound D–H pairs brings about a Mott transition at a finite correlation strength. By introducing two characteristic lengths, D–H pair binding length, ξDH, and minimum inter-doublon distance, ξDD, we can properly describe the physics of Mott transitions, and determine the critical point by ξDD ~ ξDH. This concept seems universal, because it is valid not only for newly introduced wave functions with long-range D–H and D–D (H–H) correlation factors discussed here, but for a wide range of wave functions with D–H binding factors. 相似文献
54.
H. Yokoyama T. Miyagawa M. Ogata 《Physica C: Superconductivity and its Applications》2011,471(21-22):730-734
To understand the mechanism of Mott transitions in case of no magnetic influence, superfluid-insulator (Mott) transitions are studied for the S = 0 Bose Hubbard model on the square lattice, using a variational Monte Carlo approach. In trial many-body wave functions, we introduce various types of attractive correlation factors between a doubly-occupied site (doublon, D) and an empty site (holon, H), which play a central role for the transition. We propose an improved picture of D–H binding; a Mott transition occurs when the D–H pair length becomes equivalent to the minimum D–D distance, which lengths are appropriately estimated. We confirm this picture is valid for all the wave functions with attractive D–H factors we consider, and point out it can be universal for nonmagnetic Mott transitions. 相似文献
55.
Furusho Y Goto H Itomi K Katagiri H Miyagawa T Yashima E 《Chemical communications (Cambridge, England)》2011,47(35):9795-9797
A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF(6) without racemization. 相似文献
56.
Wataru IchinoseMasamichi Miyagawa Jun ItoMasanori Shigeno Ryo AmemiyaMasahiko Yamaguchi 《Tetrahedron》2011,67(30):5477-5486
The reverse amidohelicene (P)-tetramer containing (P)-helicenediamine and m-phenylenedicarboxylate was synthesized. The circular dichroism (CD) and vapor pressure osmometry (VPO) analysis revealed the dimeric aggregate formation in THF. It is notable that the reverse amide tetramer formed a duplex, as well as the original amidohelicene oligomers. In various solutions, mixtures of the reverse (P)-tetramer and amidohelicene (P)/(M)-tetramer formed homoaggregates instead of heteroaggregates. 相似文献
57.
Shimanouchi T Sasaki M Hiroiwa A Yoshimoto N Miyagawa K Umakoshi H Kuboi R 《Colloids and surfaces. B, Biointerfaces》2011,88(1):221-230
In this study, we investigated the dynamics of a membrane interface of liposomes prepared by eight zwitterionic phosphatidylcholines in terms of their headgroup mobility, with spectroscopic methods such as dielectric dispersion analysis (DDA), fluorescence spectroscopy. The DDA measurement is based on the response of the permanent dipole moment to a driving electric field and could give the information on the axial rotational Brownian motion of a headgroup with the permanent dipole moment. This motion depended on kinds of phospholipids, the diameter of the liposomes, and the temperature. The activation energy required to overcome the intermolecular force between headgroups of phospholipids depended on the strength of the interaction between headgroups such as hydrogen bonds and/or dipole-dipole interaction. Hydration at the phosphorous group of phospholipid and the molecular order of lipid membrane impaired the interaction between headgroups. Furthermore, the hydrophobicity of membrane surface increased parallel to the increase in headgroup mobility. It is, therefore, concluded that hydration of headgroup promoted its mobility to make the membrane surface hydrophobic. The lipid membrane in liquid crystalline phase or the lipid membrane with the larger curvature was more hydrophobic. 相似文献
58.
Prof. Takahide Fukuyama Yuko Ohta Dr. Célia Brancour Kazusa Miyagawa Prof. Ilhyong Ryu Dr. Anne‐Lise Dhimane Prof. Louis Fensterbank Prof. Max Malacria 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(23):7243-7247
We have developed novel Rh‐catalyzed [n+1]‐type cycloadditions of 1,4‐enyne esters, which involve an acyloxy migration as a key step. The efficient preparation of functionalized resorcinols, including biaryl derivatives, from readily available 1,4‐enyne esters and CO was achieved by Rh‐catalyzed [5+1] cycloaddition accompanied by 1,2‐acyloxy migration. When enyne esters had an internal alkyne moiety, the reaction proceeded by a [4+1]‐type cycloaddition involving 1,3‐acyloxy migration, leading to cyclopentenones. 相似文献
59.
Shogo Nobukawa Seiki Hasunuma Takumi Sako Azusa Miyagawa Masayuki Yamaguchi 《Journal of Polymer Science.Polymer Physics》2017,55(24):1837-1842
We have investigated the effect of antiplasticization on the stress‐optical behavior of polycarbonate (PC) containing terphenyls (tPh) and di(2‐ethylhexyl)adipate (DEHA). Addition of the three tPhs (p‐, o‐, and m‐tPh) and DEHA at contents of 5–10 wt % increases the tensile storage modulus (E' ) of PC owing to the antiplasticization effect. In particular, p‐tPh increases E' more than the other additives, suggesting that the rod‐like shape matches the free volume of PC in the glassy state. The three tPh isomers improve the glassy birefringence of PC while DEHA does not change the glassy birefringence, which corresponds to the polarizability anisotropy. The stress‐optical coefficient, a ratio of stress and birefringence, of PC decreases with increasing additive content in order of p‐tPh ? o‐tPh > m‐tPh = DEHA. This result is agreement with a restricted rotational motion of additive molecule in PC, which is observed in dynamic mechanical and birefringence data. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 1837–1842 相似文献
60.
Junichi Higo Shigeru Endo Kuniaki Nagayama Tomoyoshi Ito Toshiyuki Fukushige Toshikazu Ebisuzaki Daiichiro Sugimoto Hiroo Miyagawa Kunihiro Kitamura Junichiro Makino 《Journal of computational chemistry》1994,15(12):1372-1376
The special-purpose computer GRAPE-2A accelerates the calculation of pairwise interactions in many-body systems. This computer is a back-end processor connected to a host computer through a Versa Module Europe (VME) bus. GRAPE-2A receives coordinates and other physical data for particles from the host and then calculates the pairwise interactions. The host then integrates an equation of motion by using these interactions. We did molecular dynamics simulations for two systems of liquid water: System 1 (1000 molecules), and System 2 (1728 molecules). The time spent for one step of molecular dynamics was 3.9 s (System l), and 10.2 s (System 2). The larger the molecular system, the higher the performance. The speed of GRAPE-2A did not depend on the formula describing the pairwise interaction. The cost performance was about 20 times better than that of the fastest workstations available today, and GRAPE-2A cost only $22,000. © 1994 by John Wiley & Sons, Inc. 相似文献