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排序方式: 共有85条查询结果,搜索用时 46 毫秒
31.
Novel 2-iminiomethylvinamidinium trihalides were isolated as stable crystals and found to be useful triformylmethane synthons with non-deliquescent nature in air. They were easier to manufacture, handle, and store than the known 2-iminiomethylvinamidinium dichloride. By virtue of in situ aminal protection, a combination of the vinamidinium salt with a secondary amine achieved an efficient and scalable synthesis of 7-acylamino-3-formylquinoline, a versatile synthetic intermediate for potent anti-obesity drugs 7-acylamino-3-aminomethyl-8-methylquinolines. 相似文献
32.
Atsuyoshi Nakayama Naoko Yamano Norioki Kawasaki Yasuhide Nakayama 《Polymer Degradation and Stability》2013
Copolyesteramides of 2-pyrrolidone with ε-caprolactone were synthesized by ring-opening copolymerization. The copolymers were random-like and their melting temperature and heat of fusion were dependent on the polymer composition. Biodegradation by a polyamide 4 (PA4) degrading microorganism showed rapid degradation in the region of amide-rich polymer composition. On the contrary, enzymatic hydrolysis using a lipase resulted in a different tendency, that is, ester-rich copolymers hydrolyzed rapidly. Activated sludge makes copolymers degrade to CO2 in wide polymer composition ratio. Copolyesteramides are expected to be applied as an environmentally-friendly plastics or bioabsorbable polymers in medical fields. 相似文献
33.
Tsuchiya Y Shiraki T Matsumoto T Sugikawa K Sada K Yamano A Shinkai S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(2):456-465
In Nature, chromophoric groups play various roles, such as oxygen carriers, electron donors, light sensitizers, which are achieved in many cases by control of their aggregation modes in proteins. Host-guest chemistry between cyclodextrins and porphyrins has attracted great interest from supramolecular chemists because of their unique structures and functions that mimic those of proteins with chromophoric prosthetic groups. To mimic Nature's contrivances, the host-guest systems between cyclodextrins and porphyrins have frequently been studied. It is really surprising, however, that to date no detailed structural information of these complexes has been obtained from single-crystal analysis. In 2011, we reported the first successful isolation of a dye inclusion single crystal (DISC) between 2,3,6-trimethyl-β-cyclodextrin (TMβCD) and 5,10,15,20-tetrapyridylporphyrin (TPyP), and analyzed its X-ray crystal structure. The crystal structure revealed not only the real complex mode but also the attractive orientation of TPyP in the DISC. Herein, we present new strategies to prepare DISCs of TMβCD for several porphyrins and provide crystal structures, details of the complex modes, and optical properties. We believe that the present study has various important implications not only for the basic crystal analysis of inclusion complexes but also for potential applications that use these single crystals. 相似文献
34.
Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond Cleavage
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35.
Inside Cover: Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond CleavageZ308071 (Angew. Chem. Int. Ed. 2/2014)
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36.
Ichiro Takahashi Mikio Tsuzuki Hidehiko Kitajima Minoru Hatanaka Shiro Maeda Akihito Yamano Tomihisa Ohta Shinzo Hosoi 《Analytical sciences》2003,19(6):973-974
The structure of the Diels-Alder cycloadduct formed from 2-(1,2,3-1H-benzotriazol-1-yl)-2-(p-tolyl)-2H-isoindole and dimethyl acetylenedicarboxylate was proved as 11-aza-1-(1,2,3-1H-benzotriazol-1-yl)-11-(4-methylphenyl)-tricyclo-[5.2.1.0(2.7)]undeca-2,4,6.9-tetraene-9,10-dioic acid dimethyl ester. The benzotriazole moiety was located as its 1-yl form, analogous to previous reports. The benzotriazole and the benzene (of tricyclo framework) planes were twisted with an angle of 115.83 degrees. Intramolecular close contacts between benzotriazole and ester are characteristic [N(3)...C(26), 2.754(3)A; N(3)...H(22), 3.26(4)A]. The shortest contact of N(3)...H(22) accounting for the rotation of the methyl group is estimated to be 3.10 A, which might be reasonable as C-H...N-type hydrogen bonding. 相似文献
37.
Okubo T Kuwamoto H Kim KH Hayami S Yamano A Shiro M Maekawa M Kuroda-Sowa T 《Inorganic chemistry》2011,50(7):2708-2710
The reaction of Cu(Hm-dtc)(2), Br(2), and CuBr(2) yielded a new mixed-valence octanuclear Cu(I)/Cu(II)/Cu(III) cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from Cu(II) ions to Cu(III) ions between the clusters. 相似文献
38.
Takuya Yamano 《Central European Journal of Physics》2013,11(7):910-914
We clarify a strong link between general nonlinear Fokker-Planck equations with gauge fields associated with nonequilibrium dynamics and the Fisher information of the system. The notion of Abelian gauge theory for the non-equilibrium Fokker-Planck equation has proposed in the literature, in which the associated curvature represents internal geometry. We present the fluctuation of the gauge field can be decomposed into three parts. We further show that if we define the Fisher information matrix by using a covariant derivative then it gives correlation of the flux components but it is not gauge invariant. 相似文献
39.
Dabing Li Bei Ma Reina Miyagawa Weiguo Hu Mitsuhisa Narukawa Hideto Miyake Kazumasa Hiramatsu 《Journal of Crystal Growth》2009,311(10):2906-2909
Si-doped a-plane GaN films with different doping concentrations were grown by metal-organic vapor phase epitaxy. A mirrorlike surface without pits or anisotropic stripes was observed by optical microscopy. Detailed optical properties of the samples were characterized by temperature- and excitation-intensity-dependent PL measurements. A series of emission peaks at 3.487, 3.440, 3.375–3.350, 3.290 and 3.197 eV were observed in the low-temperature PL spectra of all samples. The origin of these emissions is discussed in detail. 相似文献
40.