Total synthesis of tylosin

Tylosin has been synthesized byregio- and stereoselective introduction of the amino disaccharide moiety and D-mycinose onto the previously synthesized 16-membered-ring aglycone.     

A direct independence proof of Buchholz's Hydra Game on finite labeled trees

We shall give a direct proof of the independence result of a Buchholz style-Hydra Game on labeled finite trees. We shall show that Takeuti-Arai's cut-elimination procedure of and of the iterated inductive definition systems can be directly expressed by the reduction rules of Buchholz's Hydra Game. As a direct corollary the independence result of the Hydra Game follows. Received: August 23, 1994 / Revised: July 24, 1995 and May 9, 1996     

The modified Yamabe problem and geometry of modified scalar curvatures

Study of modified scalar curvatures and the modified Yamabe problem is given. An existence theorem of type of Trudinger and Aubin is obtained. Interpreting Isotropic curvature as a certain modified scalar curvature we can extend the four-dimensional sphere theorem of [23]. Another modified scalar curvature is used in solving open problems concerning the conjecture of self-dual Einstein 4-manifold and the Goldberg conjecture, both being under negative Ricci condition.     

Rank of 3-tensors with 2 slices and Kronecker canonical forms

Tensor type data are becoming important recently in various application fields. We determine the rank of a 3-tensor with 2 slices in comparison with its Kronecker canonical form over the complex and real number field.     

Global existence to the initial–boundary value problem for a system of nonlinear diffusion and wave equations

We prove the global existence of weak solution pair to the initial boundary value problem for a system of m-Laplacian type diffusion equation and nonlinear wave equation. The interaction of two equations is given through nonlinear source terms $f(u,v)$ and $g(u,v)$.     

Hodge algebra structures on certain rings of invariants and applications

Let B be a commutative ring with identity, m, n, and r be positive integers such that r ≤ min{m, n}, a ₁, …, a _r (resp. b ₁, … b _r ) be integers such that 1 ≤ a ₁< … < a _r ≤ m (resp. 1 ≤ b ₁ < … < b _r < n) and U (resp. V) be the most general m × r (resp. r × n) matrix such that s-minors of first a _s ? 1 rows (resp. b _s ? 1 columns) of U (resp. V) are all zero for s = 1, …, r. We investigate the B-algebra C generated by all the entries of UV and all the r-minors of U and V. We introduce a Hodge algebra structure, to which the discrete Hodge algebra associate is Cohen Macaulay, on C and prove that C is Cohen-Macaulay if so is B. Using this Hodge algebra structure, we show that C is the ring of absolute invariants of a certain group action, compute the divisor class group and the canonical class of C, and give a criterion of Gorenstein property of C in terms of a ₁ ,…, a _r and b ₁…, b _r .     

Physics in plasmonic and Mie scattered near-field for efficient surface-enhanced Raman scattering template

We describe the physics of the SERS based on the optical near-field intensity enhancement on the metallic (plasmonic) and the nonmetallic (Mie scattering) nanostructured substrates with two-dimensional (2D) periodic nanohole arrays. The calculation by the Finite-Difference Time-Domain (FDTD) method revealed that the optical intensity enhancement increases with the increase of the thickness of a gold film coating on the nonmetallic (dielectric) nanostructured Si, GaAs, and SiC substrates. The resonance spectrum shifts with the changes in the geometrical structure of the void diameter and inter-void distance. It was clarified that the optical intensity enhancement obtained with the gold-coated substrate is equivalent to that with a gold substrate at 70-nm thick gold coating on the dielectric substrates in this structure. The resonance spectral bandwidth for Mie scattering and plasmonic near-fields is different. Therefore, if the Stokes line of the Raman scattering is located within the resonance bandwidth, the SERS signal is enhanced proportionally to the fourth power of the electric near-field. However, if the Stokes shift is located out of the resonance bandwidth, the SERS signal enhancement is only proportional to the square of the scattered near-field.