全文获取类型
收费全文 | 1086篇 |
免费 | 14篇 |
国内免费 | 4篇 |
专业分类
化学 | 622篇 |
晶体学 | 15篇 |
力学 | 22篇 |
数学 | 117篇 |
物理学 | 328篇 |
出版年
2022年 | 10篇 |
2021年 | 19篇 |
2020年 | 13篇 |
2019年 | 15篇 |
2018年 | 18篇 |
2017年 | 16篇 |
2016年 | 19篇 |
2015年 | 21篇 |
2014年 | 32篇 |
2013年 | 74篇 |
2012年 | 56篇 |
2011年 | 73篇 |
2010年 | 44篇 |
2009年 | 51篇 |
2008年 | 61篇 |
2007年 | 60篇 |
2006年 | 56篇 |
2005年 | 53篇 |
2004年 | 28篇 |
2003年 | 20篇 |
2002年 | 20篇 |
2001年 | 21篇 |
2000年 | 12篇 |
1999年 | 13篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 13篇 |
1994年 | 13篇 |
1993年 | 9篇 |
1992年 | 15篇 |
1991年 | 11篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 9篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 13篇 |
1981年 | 17篇 |
1980年 | 8篇 |
1979年 | 14篇 |
1978年 | 8篇 |
1977年 | 17篇 |
1976年 | 6篇 |
1975年 | 13篇 |
1973年 | 9篇 |
1972年 | 5篇 |
排序方式: 共有1104条查询结果,搜索用时 15 毫秒
41.
This paper presents the design principles of a novel optimized microring-based uni-traveling carrier photodiode (MR-UTC-PD), for wavelength division multiplexing (WDM) optical systems. The fundamental parameters for output characteristics such as quantum efficiency and 3-dB bandwidth of MR-UTC-PD are discussed. We analyze the effects of basic parameters as effective ring radius, definite coupling condition and the suitable cross section on the MR-UTC-PD main characteristics for high performance of the device. It is shown that the maximum quantum efficiency and most efficient performance of the device can be obtained at critical coupling condition. We show that the maximum 3-dB bandwidth and an efficient approach for high bandwidth-efficiency product can be achieved at overcoupling condition. In this regard, some design curves are presented for the optimized MR-UTC-PD. 相似文献
42.
Mahboobeh Behnam Dehkordi Majid M. Heravi Parviz Khosrofar Ahmad Ziafat Mitra Ghassemzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2595-2598
Hexamethylenetetramine-bromine supported onto[3pc] silica gel rapidly converts trimethylsilyl ethers to their corresponding carbonyl compounds under microwave irradiation in solventless system. 相似文献
43.
Arnab Mitra 《Comptes Rendus Mathematique》2019,357(11-12):827-831
Let denote the quasi-split unitary group over 2n variables with respect to a quadratic extension of p-adic fields. In this short note, we relate -distinction of ladder representations of with irreducibility of its Siegel parabolic induction in . 相似文献
44.
Mitra Talaee Bahareh Lorestani Majid Ramezani Mehrdad Cheraghi Saeed Jamehbozorgi 《Journal of separation science》2019,42(14):2418-2425
A simple and fast method named microfunnel‐filter‐based emulsification microextraction is introduced for an efficient determination of some organophosphorus pesticides including diazinon, malathion, and chlorpyrifos in the environmental samples including the river, sea, and well water. This method is based upon the dispersion of a low‐toxicity organic solvent (dihexyl ether), as the extractant, in a high volume of an aqueous sample solution (45 mL). It is implemented without a centrifugation step, and using a syringe filter and a micro‐funnel, the phase separation and transfer of the enriched analytes to the gas chromatograph are simply achieved. By filtration of the extractant phase, a suitable sample clean‐up is obtained, and the total extraction time is just a few minutes. The factors influencing the extraction efficiency are optimized, and under the optimal conditions, the proposed method provides a good linearity (in the range of 15–1500 ng/mL (R2 > 0.996). A high enrichment factor is obtained (in the range of 306–342), and the method provides low limits of detection and quantification (in the ranges of 4–8 and 15–25 ng/mL, respectively). 相似文献
45.
Priyabrata Das Suvra Mandal Sudeshna Gangopadhyay Kalipada Das Arpita Ghosh Mitra Swati Dasgupta 《Natural product research》2016,30(4):474-477
Methylphophorbide a (MPa) has been isolated from the ethanol extract of the wheat grass plant. Its antioxidative efficacy is evaluated by hydroxyl radical scavenging activities and reducing capacity which are significantly up regulated in comparison with aqueous extract of the plant. The compound shows iron-binding capacity where the Fe2+ binds with MPa by two types of binding patterns with dissociation constants 157.17 and 27.89. It has antioxidative and cytotoxic effects on HeLa and Hep G2 cells. The cancerous cell survivability decreases with increasing concentration of MPa. These findings have provided evidence for the traditional use of the wheat grass plant in the treatment of cancers, oxidative stress and iron overloaded disorders. 相似文献
46.
Suparna Chakraborty Manoj Kumar Mitra Mahua Ghosh Chaudhuri Biswanath Sa Satadal Das Rajib Dey 《Applied biochemistry and biotechnology》2012,168(7):2043-2056
Sol/gel-derived silica gel was prepared at room temperature from tetraethyl orthosilicate precursor. The extracts of Terminalia chebula (Haritoki) were entrapped into the porous silica gel. Fourier transform infrared analysis revealed the proper adsorption of herbal values in the nanopores of the silica gel. Porosity was estimated by transmission electron microscope studies. The release kinetics of the extract in both 0.1 N HCl, pH 1.2, and Phosphate-buffer saline (PBS), pH 7.2, were determined using UV–Vis spectroscopy. Different dissolution models were applied to release data in order to evaluate the release mechanisms and kinetics. Biphasic release patterns were found in every formulation for both the buffer systems. The kinetics followed a zero-order equation for first 4 h and a Higuchi expression in a subsequent timeline in the case of 0.1 N HCl. In the case of PBS, the formulations showed best linearity with a first-order equation followed by Higuchi’s model. The sustained release of the extract predominantly followed diffusion and super case II transport mechanism. The release value was always above the minimum inhibitory concentration. 相似文献
47.
Saeed Kamali Hongxin Wang Devrani Mitra Hideaki Ogata Wolfgang Lubitz Brian C. Manor Thomas B. Rauchfuss Deborah Byrne Violaine Bonnefoy Francis E. Jenney Michael W. W. Adams Yoshitaka Yoda Ercan Alp Jiyong Zhao Stephen P. Cramer 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2013,125(2):752-756
48.
Synthesis and characterization of a Ni nanoparticle stabilized on Ionic liquid‐functionalized magnetic Silica nanoparticles for tandem oxidative reaction of primary alcohols
下载免费PDF全文
![点击此处可从《应用有机金属化学》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Rahim Hosseinzadeh‐Khanmiri Yaser Kamel Zahra Keshvari Ahmad Mobaraki Gholam Hossein Shahverdizadeh Esmail Vessally Mirzaagha Babazadeh 《应用有机金属化学》2018,32(9)
In this research, preparation of the magnetic nanoparticle, coating by a silica shell using (3‐aminopropyl) triethoxysilane and synthesis of a novel sulfonic acid‐substituted imidazolium‐based ionic liquid onto the surface of these particles via a multi‐component reaction, is described. The functionalized nanoparticles was loaded by Ni nanoparticles and characterized by means of techniques such as XRD, FTIR, SEM, EDX, TEM, TGA and ICP‐OES. The nanostructures have spherical shapes that ranged in size from 80 to 100 nm. The catalytic activity of these nanoparticles was tested in aerobic oxidation of primary alcohols that showed good performance in the wide range of primary alcohols in water at mild reaction conditions. As a second step of this work, the tandem oxidative synthesis of alkylacrylonitriles and bisindolylmethanes were investigated using primary alcohols under oxidation conditions. This catalyst system can be recovered using external magnet and reused for five consecutive cycles without significantly less of its activity. 相似文献
49.
50.
Majid M. Heravi Fereshteh Hydarzadeh Yahya Farhangi Mitra Ghassemzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1473-1475
Primary and secondary trimethylsilyl ethers are effeciently converted to the corresponding carbonyl compounds using HZSM-5 zeolite-supported CrO 3 under microwave irradiation in solventless system. 相似文献