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101.
The preparation of alkenyl cyclopropanes 1 with a variety of common organic functionalities is reported. These substrates were subjected to the Fe(CO)(5)-mediated carbonylation process under a CO atmosphere, leading to the formation of 2,5-disubstituted cyclohexenones 2, important intermediates for target-directed synthesis. 相似文献
102.
Balakrishna Kolli Someshwarnath Pandey Sarada P. Mishra Tapan Kanai Mukesh P. Joshi Raj S. Mohan Tham Singh Dhami Lalit Mohan Kukreja Asit Baran Samui 《Journal of polymer science. Part A, Polymer chemistry》2013,51(20):4317-4324
Main chain polymers containing azo and bisbenzylidene moiety were synthesized by polycondensation method. The successful polymerization reaction was characterized by UV–vis absorption, FT‐IR and NMR spectroscopy. The resulting polymers were soluble in polar solvents like dimethyl formamide (DMF) and showed good thermal stability up to 250 °C. These polymers were blended with poly methyl methacrylate (PMMA) and corona poled for characterizing second harmonic generation (SHG) property. Temperature stability study of SHG intensity of poled polymer showed that it is stable up to 80 °C. To improve temperature stability further the crosslinking of polymer under UV light is proposed. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4317–4324 相似文献
103.
Suspensions consisting of particles of colloidal dimensions have been reported to form connected structures. When attractive forces act between particles in suspension they may flocculate and, depending on particle concentration, shear history and other parameters, flocs may build-up in a three-dimensional network which spans the suspension sample. In this paper a floc network model is introduced to interpret the elastic behavior of flocculated suspensions at small deformations. Elastic percolation concepts are used to explain the variation of the elastic modulus with concentration. Data taken from the suspension rheology literature, and new results with suspensions of magnetic -Fe2O3 and non-magnetic -Fe2O3 particles in mineral oil are interpreted with the model proposed.Non-zero elastic modulus appeared at threshold particle concentrations of about 0.7 vol.% and 0.4 vol.% of the magnetic and non-magnetic suspensions, respectively. The difference is attributed to the denser flocs formed by magnetic suspensions. The volume fraction of particles in the flocs was estimated from the threshold particle concentration by transforming this concentration into a critical volume concentration of flocs, and identifying this critical concentration with the theoretical percolation threshold of three-dimensional networks of different coordination numbers. The results obtained indicate that the flocs are low-density structures, in agreement with cryo-scanning electron micrographs. Above the critical concentration the dynamic elastic modulus G was found to follow a scaling law of the type G (
f
-
f
c
)
f
, where
f
is the volume fraction of flocs in suspension, and
f
c
is its threshold value. For magnetic suspensions the exponent f was found to rise from a low value of about 1.0 to a value of 2.26 as particle concentration was increased. For the non-magnetic a similar change in f was observed; f changed from 0.95 to 3.6. Two other flocculated suspension systems taken from the literature showed a similar change in exponent. This suggests the possibility of a change in the mechanism of stress transport in the suspension as concentration increases, i.e., from a floc-floc bond-bending force mechanism to a rigidity percolation mechanism. 相似文献
104.
Wong CP Shimada M Nagakura Y Nugroho AE Hirasawa Y Kaneda T Awang K Hadi AH Mohamad K Shiro M Morita H 《Chemical & pharmaceutical bulletin》2011,59(3):407-411
Five new limonoids, ceramicines E-I (1-5), have been isolated from the bark of Chisocheton ceramicus. The structures and relative stereochemistry of them were fully elucidated based on 1D- and 2D-NMR data. Ceramicines E-I (1-5) exhibited moderate cell growth inhibitory activities on a range of cell lines (HL-60, A549, MCF7, and HCT116). The absolute structure of previously isolated ceramicine B (6) was also elucidated by circular dichroism (CD) and X-ray analysis. 相似文献
105.
Exploring the Potential of Fulvalene Dimetals as Platforms for Molecular Solar Thermal Energy Storage: Computations,Syntheses, Structures,Kinetics, and Catalysis 下载免费PDF全文
Dr. Karl Börjesson Dr. Dušan Ćoso Victor Gray Prof. Dr. Jeffrey C. Grossman Prof. Dr. Jingqi Guan Prof. Dr. Charles B. Harris Dr. Norbert Hertkorn Dr. Zongrui Hou Prof. Dr. Yosuke Kanai Dr. Donghwa Lee Justin P. Lomont Prof. Dr. Arun Majumdar Dr. Steven K. Meier Prof. Dr. Kasper Moth‐Poulsen Dr. Randy L. Myrabo Son C. Nguyen Prof. Dr. Rachel A. Segalman Prof. Dr. Varadharajan Srinivasan Dr. Willam B. Tolman Dr. Nikolai Vinokurov Prof. Dr. K. Peter C. Vollhardt Dr. Timothy W. Weidman 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(47):15587-15604
A study of the scope and limitations of varying the ligand framework around the dinuclear core of FvRu2 in its function as a molecular solar thermal energy storage framework is presented. It includes DFT calculations probing the effect of substituents, other metals, and CO exchange for other ligands on ΔHstorage. Experimentally, the system is shown to be robust in as much as it tolerates a number of variations, except for the identity of the metal and certain substitution patterns. Failures include 1,1′,3,3′‐tetra‐tert‐butyl ( 4 ), 1,2,2′,3′‐tetraphenyl ( 9 ), diiron ( 28 ), diosmium ( 24 ), mixed iron‐ruthenium ( 27 ), dimolybdenum ( 29 ), and ditungsten ( 30 ) derivatives. An extensive screen of potential catalysts for the thermal reversal identified AgNO3–SiO2 as a good candidate, although catalyst decomposition remains a challenge. 相似文献
106.
Diffraction patterns of wedges are studied with special attention to the finish of the samples. We assume that the sharply finished vertex should generate two hemispherical waves by the end effect of the cylindrical waves issued from two sides of the wedge under illumination of the coherent light. It is found that the assumption is valuable to the investigation of the diffraction pattern appearing in the shadow region of the wedge. 相似文献
107.
Ogoshi T Kanai S Fujinami S Yamagishi TA Nakamoto Y 《Journal of the American Chemical Society》2008,130(15):5022-5023
Condensation of 1,4-dimethoxybenzene (DMB) with paraformaldehyde in the presence of BF3.O(C2H5)2 gave novel para-bridged pentacyclic pillar DMB (DMpillar[5]arene). Moreover, para-bridged pentacyclic hydroquinone (pillar[5]arene) was prepared. Pillar[5]arene formed 1:1 host-guest complexes with dialkyl viologen and alkyl pyridinium derivatives. However, pillar[5]arene did not form complexes with the diadamantyl viologen derivative since a bulky adamantyl group was unable to thread the cavity of pillar[5]arene. 相似文献
108.
Reactions proceeding through cationic intermediates that lack a Lewis or Br?nsted basic site present a challenge for traditional asymmetric catalysis based on chiral metals or organocatalysts. We present an enantioselective ring opening of tetrasubstituted meso-aziridinium ions with alcohol nucleophiles proceeding through a chiral ion pair with a binaphthol-phosphate anion. The reaction is initiated by silver-induced ring closure of beta-chloroamines using the Ag salt of the chiral anion as in situ generated catalyst. Use of insoluble Ag2CO3 as silver source is essential to obtain high enantioselectivity; we believe the chiral phosphate acts as a "chiral anion phase transfer catalyst" to bring silver ion into the organic phase. The chiral anion concept can also be extended to the related asymmetric opening of meso-episulfonium ions generated by protonation of trichloroacetimidates vicinal to sulfides. 相似文献
109.
Anion configuration at the air/liquid interface of ionic liquid [bmim]OTf studied by sum-frequency generation spectroscopy 总被引:1,自引:0,他引:1
Iwahashi T Miyamae T Kanai K Seki K Kim D Ouchi Y 《The journal of physical chemistry. B》2008,112(38):11936-11941
The air/liquid interface of a room temperature ionic liquid, 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([bmim]OTf), is investigated using infrared-visible sum frequency generation (SFG) spectroscopy. The SFG spectra clearly show low-frequency modes [CF 3-symmetric stretching (ss) mode and SO 3-symmetric stretching (ss) mode] of the OTf anion, demonstrating the existence of anions polar oriented at the interface. The amplitude of the CF 3-ss peak of the OTf anion has the opposite sign with respect to that of the SO 3-ss peak, indicating that OTf anions at the surface have polar ordering where the nonpolar CF 3 group points away from the bulk into the air, whereas the SO 3 group points toward the bulk liquid. The line width of the SFG peak from the submerged SO 3 group is appreciably narrower than that from IR absorption, suggesting the environment of the surface OTf anions is much more homogeneous than that of the bulk. The vibrational calculations also suggest that the anions and the cations form a more specific aggregated configuration at the surface as compared to the bulk. 相似文献
110.
Kanai A Takeda Y Kuramochi K Nakazaki A Kobayashi S 《Chemical & pharmaceutical bulletin》2007,55(3):495-499
The synthesis of the key intermediate (4) in the proposed route to D8646-2-6 is described. The aldol reaction of the carbohydrate-containing pyrone 7 with the aldehyde 6 was accomplished by using LiHMDS and Sc(OTf)3 or Sn(OTf)2. The stepwise dehydration reaction of the aldol adduct 14, followed by Stille coupling with vinyl stannane 5 which contained phosphonate gave the desired 4. 相似文献