13C NMR spectral assignments of chlorpromazine and its 5-oxide. Literature correction

The ¹³C chemical shift assignments of title compounds were made on the basis of their coupled and decoupled spectra. The size of the ipso and allylic ¹³CH coupling constants establish unequivocally the identity of symmetry related carbon pairs and show that several assignments reported previously are incorrect.     

The influence of structure and conformation on electronic interactions of 4′-nitro-10-phenylphenothiazine

The crystal structure of 4′-nitro-10-phenylphenothiazine, 1 , has been determined by the single crystal x-ray diffraction studies and consists of two independent molecules in the asymmetric cell unit with a pseudo-center of symmetry. The crystal belongs to the monoclinic System with the space group P2₁/c. The central ring of the phenothiazine ring system is in a boat conformation and the 4′-nitro substituent is in a boat-axial conformation with respect to the central ring of phenothiazine. Compound 1 is the first reported 10-aryl phenothiazine in which the 10-phenyl ring is perpendicular to the plane bisecting the dihedral angle of the phenothiazine nucleus. This geometry allows for resonance interaction between the lone pair of electrons on N₁₀ and the 4′-nitro-10-phenyl ring which influences both the spectral properties and structure of the phenothiazine tricyclic ring. The correlation between the x-ray structure and ¹³C nmr spectral properties of 1 is discussed. The uv/vis and esr studies of the radical cation of 1 indicate that the 10-aryl ring is twisted with respect to the phenothiazine ring.     

Photocatalytic Giese-Type Reaction with Alkylsilicates Bearing C,O-Bidentate Ligands

Herein, a photocatalytic Giese-type reaction with alkylsilicates bearing C,O-bidentate ligands as stable alkyl radical precursors has been reported. The alkylsilicates were prepared in one step from organometallic reagents. Not only primary, secondary, and tertiary alkyl radicals, but also elusive methyl radicals, could be generated by using the present reaction system. The generated radicals were trapped by electron-deficient olefins bearing various functional groups to give the desired alkyl adducts. The silicon byproduct can be recovered after the photoreaction. The radical generation process was investigated by theoretical calculations, which provided an insight into the facile generation of methyl radicals from methylsilicate bearing C,O-bidentate ligands.     

Indecomosability of modular standard modules of schurian association schemes and $$\varvec{}$$-schemes

Let p be a prime number. It is known that the standard module of a p-association scheme over a field of characteristic p is indecomposable. By examples, the converse of the above fact is not true. We will prove that, for a schurian association scheme, the standard module is indecomposable if and only if the association scheme is a p-scheme.     

Classification of skew‐Hadamard matrices of order 32 and association schemes of order 31

Using a backtracking algorithm along with an essential change to the rows of representatives of known 13 710 027 equivalence classes of Hadamard matrices of order 32, we make an exhaustive computer search feasible and show that there are exactly 6662 inequivalent skew‐Hadamard matrices of order 32. Two skew‐Hadamard matrices are considered SH ‐equivalent if they are similar by a signed permutation matrix. We determine that there are precisely 7227 skew‐Hadamard matrices of order 32 up to SH ‐equivalence. This partly settles a problem posed by Kim and Solé. As a consequence, we provide the classification of association schemes of order 31.     

Indecomposable decompositions of modular standard modules for two families of association schemes

We investigate the indecomposable decomposition of the modular standard modules of two families of association schemes of finite order. First, we show that, for each prime number p, the standard module over a field F of characteristic p of a residually thin scheme S of p-power order is an indecomposable FS-module. Second, we describe the indecomposable decomposition of the standard module over a field of positive characteristic of a wreath product of finitely many association schemes of rank 2.