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101.
Rotationally resolved ultrahigh-resolution fluorescence excitation spectra of the S1 ← S0 transition of dibenzofuran have been observed using the technique of crossing a collimated molecular beam and the single-mode UV laser beam. 3291 rotational lines of the band and 3047 rotational lines of the band have been assigned. The band has been found to be a b-type transition, in which the transition moment is along the twofold symmetry axis of this molecule, and only the ΔKa = ± 1 transitions were observed. The excited state is identified to be the S11A1(ππ∗) state. In contrast with this, the band has been found to be an a-type transition in which the transition moment is along the long axis in plane. It indicates that the intensity of this vibronic band arises from vibronic coupling with the S21B2(ππ∗) state. We determined the accurate rotational constants and the molecule have been shown to be planar both in the ground and excited states. 相似文献
102.
Using a straightforward chemo-enzymatic procedure, 1-beta-O-acyl glucuronides of three non-steroidal anti-inflammatory drugs, diclofenac (DF) 5, mefenamic acid (MF) 6 and (S)-naproxen (NP) 7, were prepared. Caesium salts of these carboxylic acid drugs reacted with commercially available methyl 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-alpha-D-glucopyranuronate 4 to give exclusively the corresponding 1-beta-O-acyl glucuronides 8-10 in moderate yields. The protecting acetyl (for -OH group) and methyl ester (for -CO2H group) groups of each sugar moiety were easily removed to provide the corresponding free 1-beta-O-acyl glucuronides 1-3 in high yields. Deprotection was achieved through effective enzyme-catalysed chemo-selective hydrolyses of the acetyl groups using lipase AS Amano (LAS), and of the methyl ester group using esterase from porcine liver (PLE). 相似文献
103.
Yasuyuki Kowaka Noritaka Ashizawa Hitoshi Goto Umpei Nagashima Masaaki Baba 《Journal of Molecular Spectroscopy》2010,260(1):72-9519
A rotationally resolved ultrahigh-resolution fluorescence excitation spectrum of the S1 ← S0 transition of perylene has been observed using a collimated supersonic jet technique in conjunction with a single-mode UV laser. We assigned 1568 rotational lines of the band, and accurately determined the rotational constants. The obtained value of inertial defect was positive, accordingly, the perylene molecule is considered to be planar with D2h symmetry. We determined the geometrical structure in the S0 state by ab initio theoretical calculation at the RHF/6-311+G(d,p) level, which yielded rotational constant values approximately identical to those obtained experimentally. Zeeman broadening of each rotational line with the external magnetic field was negligibly small, and the mixing with the triplet state was shown to be very small. This evidence indicates that intersystem crossing (ISC) in the S11B2u state is very slow. The rate of internal conversion (IC) is also inferred to be small because the fluorescence quantum yield is high. The rotational constants of the S11B2u state were very similar to those of the S01Ag state. The slow internal conversion (IC) at the S1 zero-vibrational level is attributed to a small structural change upon electronic transition. 相似文献
104.
Uchida H Song JM Suzuki S Nakazawa E Baba N Watanabe M 《The journal of physical chemistry. B》2006,110(27):13319-13321
To confirm the superiority of newly developed electrocatalyst layer (ECL) for polymer electrolyte fuel cells, three-dimensional dispersion states of Nafion ionomer in Pt/carbon black agglomerates were analyzed by electron tomography based on multiple TEM images taken at different tilt angles. Uniform distribution of the ionomer has been first observed, proving the high catalyst utilization in the new ECL distinctive from that of the conventional one. 相似文献
105.
[reaction: see text] A boat-type of chelated bicyclic transition state involving highly diastereoselective construction of three contiguous stereogenic centers in the Reformatsky reaction of indium enolates with alpha-alkoxy/hydroxy ketones is proposed. alpha-Hydroxy ketones with indium enolates furnished highly diastereoselective lactones, while alpha-alkoxy ketones gave acyclic esters in moderate selectivities. X-ray structure analyses of key products unequivocally revealed the unexpected stereochemistry of products and the reaction pathway. 相似文献
106.
107.
S. Ota S. Shimoura H. Iwasaki M. Kurokawa S. Michimasa N. Aoi H. Baba K. Demichi Z. Elekes T. Fukuchi T. Gomi S. Kanno S. Kubono K. Kurita H. Hasegawa E. Ideguchi N. Iwasa Y.U. Matsuyama K.L. Yurkewicz T. Minemura T. Motobayashi T. Murakami M. Notani A. Odahara A. Saito H. Sakurai E. Takeshita S. Takeuchi M. Tamaki T. Teranishi Y. Yanagisawa K. Yamada M. Ishihara 《Physics letters. [Part B]》2008
108.
Devi Ritu Singh Jaydip Potukuchi Baba 《International Journal of Theoretical Physics》2022,61(10):1-14
International Journal of Theoretical Physics - We successfully realized symmetric and asymmetric cyclic quantum teleportation by using different controllers for each receiver. In this study, Alice... 相似文献
109.
Motohiro Aiba Takahiro Tokuyama Susumu Baba Hidetoshi Matsumoto Hiroki Tomioka Tomoya Higashihara Mitsuru Ueda 《Journal of polymer science. Part A, Polymer chemistry》2014,52(9):1275-1281
A new concept for the method to provide semipermeability in ultrathin and single‐component wholly aromatic polyamide membranes has been developed for the first time. It was found that water molecules could permeate through the membrane prepared not from polyamides containing flexible ether, bulky binaphthyl, or fluorene rigid units, but one with carboxylic acid groups under a reverse osmosis mode. However, the enhancement of water transport properties by introducing the hydrophilic group of polyamide was not substantial. Therefore, polyamide membranes were prepared from the solution containing aqueous additives in order to weaken hydrogen bonds between polymer chains and thereby to suppress the aggregation of the polymer chains. As a result, water flux was dramatically improved with slightly improved NaCl rejection. Our analyses based on attenuated total reflectance Fourier transform infrared spectroscopy and solid‐state carbon polarization and magic angle spinning nuclear magnetic resonance (13C CPMAS NMR) spectroscopy confirmed that the aggregation of polymer chains due to the hydrogen bonds among the amide linkages was suppressed by the co‐ordination of the aqueous additives to the amide linkage. The state of water in the membranes analyzed by differential scanning calorimetry also supported the formation of pores. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1275–1281 相似文献
110.
Synthesis,Structure, Optical,and Electrochemical Properties of Triple‐ and Quadruple‐Decker Co‐facial Tetrathiafulvalene Arrays
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Dr. Masashi Hasegawa Dr. Ken‐ichi Nakamura Saki Tokunaga Yumi Baba Ryota Shiba Prof. Dr. Takashi Shirahata Prof. Dr. Yasuhiro Mazaki Prof. Dr. Yohji Misaki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(29):10090-10101
Understanding the details of the electronic structure in face‐to‐face arranged tetrathiafulvalenes (TTFs) is very important for the design of supramolecular functional materials and superior conductive organic materials. This article is a comprehensive study of the interactions among columnar stacked TTFs using trimeric (trimer) and tetrameric (tetramer) TTFs linked by alkylenedithio groups (‐S(CH2)nS‐, n=1–4) as models of triple‐ and quadruple‐decker TTF arrays. Single‐crystal X‐ray analyses of neutral trimeric TTFs revealed that the three TTF moieties are oriented in a zigzag arrangement. Cyclic voltammetry measurements (CV) reveal that the trimer and tetramer exhibited diverse reversible redox processes with multi‐electron transfers, depending on the length of the ‐S(CH2)nS‐ units and substituents. The electronic spectra of the radical cations, prepared by electrochemical oxidation, showed charge resonance (CR) bands in the NIR/IR region (1630–1850 nm), attributed to a mixed valence (MV) state of the triple‐ and quadruple‐decker TTF arrays. In the trimeric systems, the dicationic state (+2; 0.66 cation per TTF unit) was found to be a stable state, whereas the monocationic state (+1) was not observed in the electronic spectra. In the tetrameric system, substituent‐dependent redox processes were observed. Moreover, π‐trimers and π‐tetramers, which show a significant Davydov blueshift in the spectra, are formed in the tricationic (trimer) and tetracationic (tetramer) state. In addition, these attractive interactions are strongly dependent on the length of the linkage unit. 相似文献