全文获取类型
收费全文 | 769篇 |
免费 | 19篇 |
国内免费 | 5篇 |
专业分类
化学 | 585篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 19篇 |
物理学 | 184篇 |
出版年
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 7篇 |
2018年 | 3篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 4篇 |
2014年 | 16篇 |
2013年 | 32篇 |
2012年 | 30篇 |
2011年 | 45篇 |
2010年 | 19篇 |
2009年 | 22篇 |
2008年 | 53篇 |
2007年 | 41篇 |
2006年 | 60篇 |
2005年 | 48篇 |
2004年 | 42篇 |
2003年 | 19篇 |
2002年 | 23篇 |
2001年 | 28篇 |
2000年 | 15篇 |
1999年 | 18篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 13篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 14篇 |
1984年 | 22篇 |
1983年 | 7篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 15篇 |
1975年 | 7篇 |
1974年 | 11篇 |
1973年 | 8篇 |
1968年 | 3篇 |
排序方式: 共有793条查询结果,搜索用时 0 毫秒
1.
Hiroshi Noguchi Masanori Ueda Yoshinobu Baba Masako Takasu 《Journal of Polymer Science.Polymer Physics》2003,41(12):1316-1322
The electrophoresis of DNA chains in uncrosslinked polymer solutions with a Brownian dynamics simulation with an anisotropic friction tensor was analyzed. According to the degree of anisotropy, three types of migration behavior are obtained: fluctuation without or with periodicity between U‐shaped and compact conformations, or migration with linear conformation. We found good agreement between our simulation results and the direct observations of DNA by fluorescence microscopy. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1316–1322, 2003 相似文献
2.
We theoretically investigated the mass dependence of the sympathetic cooling rate of gas-phase ions trapped in a linear radio-frequency-quadrupole
ion trap. Using an a priori molecular dynamical calculation, tracing numerically with Newtonian equations of motion, we found
that ions with a mass greater than 0.54±0.04 times that of the laser-cooled ions are sympathetically cooled; otherwise, they
are heated. To understand the mass dependence obtained using the molecular-dynamical calculation, we made a heat-exchange
model of sympathetic cooling, which shows that the factor of 0.54±0.04 is a consequence of absence of micro-motion along the
axis of the linear ion trap.
Received: 10 December 2001 / Revised version: 28 January 2002 / Published online: 14 March 2002 相似文献
3.
4.
Tatsushi Baba 《Tetrahedron letters》2004,45(31):5973-5975
New water-soluble porphycenes having sulfonic acid groups at the β-pyrrolic positions were synthesized and characterized by UV-vis, NMR, IR, and mass spectroscopy as well as elemental analyses. The series of mono- to tri-sulfonato derivatives were simply separated by the extraction method. 相似文献
5.
6.
The relative gamma-ray intensities in the energy region between 122 and 411 keV in the decay of152Eu were measured by using a Ge(Li) detector. Its efficiency calibration was carried out with the radioactive sources of241Am,57Co,203Hg,137Cs,133Ba,75Se,169Yb and192Ir. 相似文献
7.
Mechanism of gold adsorption by persimmon tannin gel. 总被引:1,自引:0,他引:1
Gold adsorption by persimmon tannin (PT) gel from a solution containing hydrogen tetrachloroaurate(III) was examined. A flow-rate examination in a column system indicated the reduction of Au(III) ion to Au(0). XRD patterns clarified the existence of Au(0) on the gel which adsorbed gold. The gel could also adsorb colloidal Au(0) prepared independently. A model consisting of ligand exchange, Au(III) reduction to Au(0), and resulting Au(0) adsorption by PT gel was presented for the gold adsorption mechanism. 相似文献
8.
Yuichiro Hori Miyako Nishiura Tomomi Tao Reisuke Baba Steven D. Bull Kazuya Kikuchi 《Chemical science》2021,12(7):2498
Reversible enzymatic post-translational modification of the ε-amino groups of lysine residues (e.g. N-acylation reactions) plays an important role in regulating the cellular activities of numerous proteins. This study describes how enzyme catalyzed N-deprotection of lysine residues of non-fluorescent peptide-coumarin probes can be used to generate N-deprotected peptides that undergo spontaneous O- to N-ester transfer reactions (uncatalyzed) to generate a highly fluorescent N-carbamoyl peptide. This enables detection of enzyme catalyzed N-deacetylation, N-demalonylation, N-desuccinylation and N-demethylation reactions activities towards the N-modified lysine residues of these probes using simple ‘turn on’ fluorescent assays.We developed “turn-on” fluorescent probes that detect enzymatic lysine deacylation and demethylation critical for epigenetic and other cellular phenomena, using intramolecular O- to N-ester transfer reactions. 相似文献
9.
10.
The simultaneous ultramicrodetermination of heterogeneous halogens in organic compounds was carried out by the potentiometric titration with 0.002 M silver nitrate after the sample was decomposed by the flask combustion method. In examination of the titration, it was found that clear potential break at the end point was obtained by controlling the delivery speed of the titrant at 0.2 ml/min or slower and the temperature of the solution to be titrated at ca. 10 °C when chloride ion is present. The error due to coprecipitation during the titration and the effect of the mole ratio of heterogeneous halide ions in the sample solution was examined and discussed. The analysis of organic halogen compounds resulted in an error of within 0.4% and standard deviation of less than 0.25%. 相似文献