全文获取类型
收费全文 | 1441篇 |
免费 | 40篇 |
国内免费 | 14篇 |
专业分类
化学 | 882篇 |
晶体学 | 7篇 |
力学 | 46篇 |
数学 | 328篇 |
物理学 | 232篇 |
出版年
2023年 | 6篇 |
2022年 | 16篇 |
2021年 | 17篇 |
2020年 | 25篇 |
2019年 | 14篇 |
2018年 | 31篇 |
2017年 | 26篇 |
2016年 | 55篇 |
2015年 | 57篇 |
2014年 | 41篇 |
2013年 | 96篇 |
2012年 | 81篇 |
2011年 | 105篇 |
2010年 | 84篇 |
2009年 | 55篇 |
2008年 | 84篇 |
2007年 | 84篇 |
2006年 | 58篇 |
2005年 | 60篇 |
2004年 | 64篇 |
2003年 | 37篇 |
2002年 | 45篇 |
2001年 | 23篇 |
2000年 | 32篇 |
1999年 | 21篇 |
1998年 | 14篇 |
1997年 | 14篇 |
1996年 | 13篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 12篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1966年 | 6篇 |
1965年 | 4篇 |
1962年 | 6篇 |
1959年 | 7篇 |
1958年 | 7篇 |
1957年 | 22篇 |
1956年 | 13篇 |
1955年 | 15篇 |
排序方式: 共有1495条查询结果,搜索用时 15 毫秒
941.
Ehrl L Soos M Morbidelli M 《Langmuir : the ACS journal of surfaces and colloids》2008,24(7):3070-3081
The steady-state size and structure of aggregates produced under turbulent conditions in stirred tank, for primary particle diameter, d(p), equal to 420 nm and 120 nm, were studied experimentally for various values of the volume average shear rate, G, and solid volume fraction, phi, and compared with data for d(p) = 810 nm. To exclusively investigate the effect of dp, polystyrene latexes with same type and similar density of surface charge groups (sulfate) were used. The mass fractal dimension, d(f), obtained by image analysis, was found to be invariant of d(p) and G, with a value equal to 2.64 +/- 0.18. Small-angle static light scattering was used to characterize the cluster mass distributions by means of the root-mean-square radius of gyration, R(g), and the zero-angle intensity of scattered light, I(0), whose steady-state values proved to be fully reversible with respect to G. The absolute values of R(g) obtained for similar phi and G proved to be independent of d(p), and for all studied conditions, R(g) was proportional to G-1/2. At very low phi, a critical aggregate size for breakage was obtained and used to evaluate the aggregate cohesive force, as a characteristic for the aggregate strength. The aggregate cohesive force was found to be independent of aggregate size, with similar values for the investigated dp. Due to large d(p) and high d(f), the effect of multiple light scattering within the aggregates was found to be present, and by relating the scaling of R(g) with I(0) to d(f), the corresponding correction factors were evaluated. By combination of the independently measured aggregate size and structure, it is possible to experimentally determine the relation between the maximum stable aggregate mass and the hydrodynamic stresses independent of the multiple light scattering present for large d(p) and compact aggregates. 相似文献
942.
p-Nitroaniline was explored as a derivatising reagent for UV absorbance detection of carbohydrates after separation by CE. This derivatising agent has three advantages: first, it has excellent water solubility; second, it has high molar absorptivity; and third, it is possible to obtain sensitive detection using a UV or blue light-emitting diode (LED) as the light source. The labelling reaction took less than 30 min to complete with high reaction yield. The separation process was modelled and optimised using an artificial neural network. Nine carbohydrates were separated by a CE system within 16 min using a 0.17 M boric acid buffer at pH 9.7. On-column LED detection at 406 nm allowed the detection of carbohydrates with good detection limits (<1.1 microM or 8.8 fmol) and reproducible quantification in the concentration range of 2.6-200 microM. This method was applied successfully to the determination of component carbohydrates in some food samples. 相似文献
943.
Thermal curing and water re‐exposure of silane–PVA/PVAc complex film on glass fiber surface 下载免费PDF全文
Daniel Repovsky Miroslav Michalka Dusan Velic 《Surface and interface analysis : SIA》2015,47(4):482-490
Because glass fiber reinforced composites are in industrial demand, chemistry and topography of the glass fiber sizing are of interest. Silane–PVA/PVAc (polyvinyl alcohol/polyvinyl acetate) complex film on the glass fiber surface is studied during thermal curing and water re‐exposure by using atomic force microscopy. The complex film consists of silane with the honeycomb structure film and PVA/PVAc with the hexagonal close pack structure of ellipsoidal shaped microspheres (270 × 620 nm). The thermal curing at 100 °C is leading to the evaporation of water contained in the microspheres. Because of water evaporation, the average roughness value of 1‐min thermal curing decreases from initial 7.3 to only 2.7 nm. Such a collapse of microsphere is followed by an intermixing between silane film and PVA/PVAc microspheres leading to a change of silane honeycomb structure along with silane tips. The average value of the silane honeycomb structure wall width decreases from 144 nm to 54 nm, for curing times of 15 and 30 min, respectively. A re‐exposure to an aqueous environment after 100 °C curing leads to almost completely restored microspheres regarding shape and size. The average complex film thickness increases from 180 nm for thermal curing for 30 min to 225 nm for water re‐exposed film. Interestingly, the pits in the microsphere structure are observed presumably because of the tips from intermixing. The thermal curing at 200 °C enhances the intermixing, and after 15 min, an intramixing is suggested to occur between PVAc core and PVA shell of the microsphere. The water re‐exposure after 15 min of 200 °C curing leads to a re‐containing of water but without restored microsphere structure; Because of the intramixing, leaving the silane–PVA/PVAc film is not complex anymore. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
944.
Marián Kucharík Michal Korenko Du?an Jani?kovi? Magdaléna Kadle?íková Miroslav Bo?a Jozef Vincenc Oboňa 《Monatshefte für Chemie / Chemical Monthly》2010,38(5):7-13
Abstract
Rapid solidification processing (with a cooling rate in the interval 105–106 K s−1) was used to prepare deeply undercooled cryolite–alumina melts. These samples were analyzed by XRD, infrared, and Raman spectroscopy. Besides cryolite, the amorphous phase and a low amount of ι-Al2O3 were detected. Annealing of the quenched sample revealed the transformation of metastable amorphous phases into different products depending on the annealing conditions. The results obtained showed that all of the elements (Na, Al, O, and F) are probably present in the amorphous parts of the quenched samples. 相似文献945.
V Novakova RZ Kobak R Kučera K Kopecky M Miletin V Krepsová J Ivincová P Zimcik 《Dalton transactions (Cambridge, England : 2003)》2012,41(35):10596-10604
A series of azaphthalocyanines (AzaPc) bearing one, two, four or eight isopropylidene-protected galactosyl units was prepared by azide-alkyne click reaction or by classical Pc template cyclotetramerization of the corresponding dicyanopyrazine and AzaPc properties important for photodynamic therapy were compared. All compounds absorbed at long wavelengths (above 650 nm) and belonged to strong singlet oxygen producers (Φ(Δ) = 0.58-0.64) retaining significant fluorescence emission (Φ(F) = 0.026-0.23). The only exception was the compound with four isopropyliden-protected galactosyl units where partial aggregation was observed. Removal of protecting groups increased the polar character of all AzaPc. However, only AzaPc bearing eight galactoses was found to be water-soluble (105 mg mL(-1)) but noticeably aggregated in water as well as in organic solvents (DMF, DMSO). Amphiphilic AzaPc bearing one deprotected galactose was incorporated into the lipidic bilayer of liposomes in a nonaggregated form. Liposomes may therefore be a suitable delivery system for this amphiphilic photosensitizer. 相似文献
946.
A sequential injection (SI) method in a lab-on-valve (LOV) format for simultaneous spectrophotometric determination of copper and iron has been devised. The detection chemistry is based on the complex formation of 2-(5-bromo-2-pyridylazo)-5-[N-n-propyl-N-(3-sulfopropyl)amino]aniline (5-Br-PSAA) with copper(II) and/or iron(II) at pH 4.6. Copper(II) reacts with 5-Br-PSAA to form the complex which has an absorption maximum at 580 nm but iron(III) does not react. In the presence of a reducing agent only iron(II)-5-Br-PSAA complex is formed and detected at 558 nm. Under the optimum experimental conditions, the determinable ranges are 0.1-2 mg l−1 for copper and 0.1-5 mg l−1 for iron, respectively, with a sampling rate of 18 h−1. The limits of detection are 50 μg l−1 for copper and 25 μg l−1 for iron. The relative standard deviations (n = 15) are 2% for 0.5 mg l−1 copper and 1.8% for 0.5 mg l−1 iron when determined in standard solutions. The recoveries range between 96 and 105% when determining 0.25-2 mg l−1 of copper and 0.2-5 mg l−1 of iron in artificial mixtures at copper/iron ratios of 1:10 to 5:1. The proposed SI-LOV method is successfully applied to the simultaneous determination of copper and iron in multi-element standard solution and in industrial wastewater samples. 相似文献
947.
Mashlan Miroslav Yevdokimov Viktor Pechousek Jiri Zboril Radek Kholmetskii Alexander 《Hyperfine Interactions》2004,159(1-4):15-19
Temperature-dependent 57Fe Mössbauer spectroscopy has been used to elucidate the hyperfine parameters and dynamical behavior of the metal atom in several organo-iron complexes which have one or more η5 P5 ring structures as ligated groups. The spin-lattice relaxation of the (paramagnetic) one-electron oxidation products occurs on a time scale fast compared to τ1/2 (ME) at temperatures in the range 85 < T < 320 K. 相似文献
948.
Andrej Vincze Jaroslav Bruncko Miroslav Michalka Daniel Figura 《Central European Journal of Physics》2007,5(3):385-397
One of the most important and promising materials from metal oxides is ZnO with specific properties for near UV emission and
absorption optical devices. The properties of ZnO thin films strongly depend on the deposition method. Among them, pulsed
laser deposition (PLD) plays an important role for preparing various kinds of ZnO films, e.g. doped, undoped, monocrystalline,
and polycrystalline. Different approaches — ablation of sintered ZnO pellets or pure metallic Zn as target material are described.
This contribution is comparing properties of ZnO thin films deposited from pure Zn target in oxygen atmosphere and those deposited
from sintered ZnO target. There is a close connection between final thin film properties and PLD conditions. The surface properties
of differently grown ZnO thin films are measured by secondary ion mass spectrometry (SIMS), atomic force microscopy (AFM)
and scanning electron microscopy (SEM). Furthermore, different approaches — ablation of sintered ZnO pellet or pure metallic
Zn as target materials are described. The main results characterize typical properties of ZnO films versus technological parameters
are presented.
Presented at 5-th International Conference Solid State Surfaces and Interfaces, November 19–24, 2006, Smolenice Castle, Slovakia 相似文献
949.
Lattice dynamics and stability of four fcc crystals (Al, Ir, Pt and Au) under isotropic (hydrostatic) tensile loading are studied from first principles using the linear response method and the harmonic approximation. The results reveal that, contrary to former expectations, strengths of all the studied crystals are limited by instabilities related to soft phonons with finite or vanishing wavevectors. The critical strains associated with such instabilities are remarkably lower than those related to the volumetric instability. On the other hand, the corresponding reduction of the tensile strength is by 20% at the most. An analysis of elastic stability conditions is also performed and the results obtained by means of both approaches are compared. 相似文献
950.
Miroslav Pardy 《International Journal of Theoretical Physics》2003,42(1):99-110
After the classical approach to acceleration of a charged particle by -form impulsive force, we consider the corresponding quantum theory based on the Volkov solution of the Dirac equation. We determine the modified Compton formula for frequency of photons generated by the scattering of the -form laser pulse on the electron in a rest frame. 相似文献