Reduction of carbon monoxide by molybdenum-containing hydroxide systems

The reduction of CO by the nitrogen-fixing systems Ti(OH)₃−Mo(OH)₃ and MgTi₂O₄−Mo(OH)₃ was studied in aqueous and water-methanol media; in the latter,¹⁴CO was used as the reagent. The main reaction product is methanol, whose yield in the H₂O−MeOH−KOH mixture is almost an, order of magnitude higher than that in an aqueous alkaline solution. The data obtained were compared to those for the reduction of N₂ Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10 pp. 2081–2083, October, 1998.     

Synthesis and structural studies of (1R,2R,5R)-chloro{o-[β-(2-hydroxy-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylidenamino)ethyliminomethyl]phenoxy-O,N,N}palladium(II)

The reaction of (1R,2R,5R)-3-[{2-[(2-hydroxybenzylidene)amino]ethyl}imino]-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol with lithium tetrachloropalladate was studied. A chiral palladium(II) complex was thus obtained and its structure was confirmed by NMR spectroscopy and X-ray diffraction analysis.     

Simultaneous Determination of the Amplitude-Phase Structure of an Optical Signal and a Transfer Function with the Influence of the Medium Given by a Modulation Function

We consider a solution to the phase problem in optics as applied to registering and analyzing amplitude-phase structures of 1) d optical fields that form or transfer images and 2) transfer or spread functions of the medium where optically inhomogeneous fields propagate or those of the systems forming fields and producing distortions. The influence of the medium is characterized by the modulation function and is described by the operation of multiplication. In order to measure the amplitude and phase field characteristics and transfer or spread functions, we use an original development of the modulation-spectral method proposed earlier by the authors. There are two variants of optical schemes considered. They include identical parts designed to form the light field to be processed. Using the first optical system, one forms the spectrum of spatial frequencies and introduces the first additional space modulation in the plane of spatial frequencies. The second optical system is placed in the same plane to form the image of the investigated field in the input plane of the developing scheme after passing the transmitting medium. In the first variant, the second part of the scheme contains at the input the third optical system forming the spatial spectrum in the registration plane. At the input of this scheme, the second additional spatial modulation is introduced. In the second variant, the third optical system forms the image of the developing scheme input plane in the registration plane. The second additional spatial modulator is placed in the spatial frequency plane of the third optical system. In the output, in both cases four independent two-dimensional intensity distributions are registered, which allow one to solve the formulated problem.     

Optical system calibration by the correlation method

A simple method for determining and subsequent eliminating geometrical distortions, including chromatic aberrations, introduced by an imaging system is described. A virtual calibration object is transferred onto a plane surface and is photographed using a tested optical system. The image is compared by the correlation method with digital original matched with camera angle using projective transformations.     

Convective Flows in a Melt During Crystal Growth under Periodic Temperature Field Conditions

The results of an analysis of thermo-gravitational convection in Czochralski single-crystal growth from a melt under periodic temperature field conditions are presented. The numerical modeling is based on solving the unsteady 3-D Navier-Stokes and heat conduction equations in the Boussinesq approximation. It is shown that using different heating regimes for the crystal medium provides additional opportunities for controlling heat and mass transfer.     

Synthesis and physicochemical properties of the pectin complexes with Xymedon

Russian Chemical Bulletin - The formation of stable complexes of pectin polysaccharides with 1-(2-hydroxyethyl)-4,6- dimethyl-1,2-dihydropyrimidin-2-one (Xymedon drug) was shown by UV and IR...     

Molecular structure of 2-methoxy-4-pyrrolidinyl-6-trinitromethyl-1,3,5-triazine

An X-ray diffraction study of 2-methoxy-4-pyrrolidinyl-6-trinitromethyl-1,3,5-triazine was carried out. The crystals are triclinic; C₉H₁₁N₇O₇; M = 329.25; a = 8.536(1) Å, b = 9.378(2) Å, c = 9.7401(8) Å; α = 79.13(1)°, β = 73.974(8)°; γ = 72.76(1)°; V = 710.8(2) ų, d _c = 1.54 g/cm³, Z = 2, space group P1ˉ. The molecule on the whole is planar, except the pyrrolidine ring, which has a twist conformation. No significant π-π interactions and hydrogen bonds of C-H⋯N or C-H⋯O type were found in the crystal, and the molecule packing is stabilized only due to van der Waals interactions. Original Russian Text Copyright ? 2008 by V. V. Bakharev, A. A. Gidaspov, I. A. Litvinov, and E. V. Mironova __________ Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 187–189, January–February, 2008.