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91.
Martínez-Martín D Jaafar M Pérez R Gómez-Herrero J Asenjo A 《Physical review letters》2010,105(25):257203
In this work we investigate possible ferromagnetic order on the graphite surface by using magnetic force microscopy (MFM). Our data show that the tip-sample interaction along the steps is independent of an external magnetic field. Moreover, by combining kelvin probe force microscopy and MFM, we are able to separate the electrostatic and magnetic interactions along the steps obtaining an upper bound for the magnetic force gradient of 16 μN/m. Our experiments suggest the absence of ferromagnetic signal in graphite at room temperature. 相似文献
92.
The structure of zero and nonzero minors in the Grassmannian leads to rich combinatorics of matroids. In this paper, we investigate an even richer structure of possible equalities and inequalities between the minors in the positive Grassmannian. It was previously shown that arrangements of equal minors of largest value are in bijection with the simplices in a certain triangulation of the hypersimplex that was studied by Stanley, Sturmfels, Lam and Postnikov. Here, we investigate the entire set of arrangements and its relations with this triangulation. First, we show that second largest minors correspond to the facets of the simplices. We then introduce the notion of cubical distance on the dual graph of the triangulation and study its relations with the arrangement of t-th largest minors. Finally, we show that arrangements of largest minors induce a structure of a partially ordered set on the entire collection of minors. We use this triangulation of the hypersimplex to describe a two-dimensional grid structure on this poset. 相似文献
93.
Julieta I. Paez Ariel L. Cappelletti Ana M. Baruzzi Verónica Brunetti Miriam C. Strumia 《Macromolecular Symposia》2010,290(1):37-45
Summary: The spontaneous adsorption of the dendron 3,5-Bis (3,5-dinitrobenzoylamino) benzoic acid (D-NO2) onto gold and carbon electrodes produced conductive surfaces with electroactive chemical functions. A comparative electrochemical behavior of both electrodes after dendron immobilization led us to conclude that the self-assembly of D-NO2 on carbon is faster and stronger. Considering this advantage, the surface of magnetic maghemite nanoparticles (MNPs) was modified using D-NO2. Firstly, MNPs were modified with APS as silane coupling agent and afterwards, D-NO2 was covalently attached to the surface, achieving nitro-functionalized MNPs. Subsequently, the immobilization of these modified MNPs onto glassy carbon surfaces was explored to generate a novel platform promising for biosensors development. 相似文献
94.
Summary: Chitosan films and microspheres were prepared and their surfaces were functionalized with first generation dendritic molecules. The films were modified by Weisocyanate dendron, while Behera's and bis Behera's amine dendrons were used to modify the microspheres. Prior to dendronization films were prepared by blending chitosan with 18% of polyvinyl pyrrolidone (PVP), and casting the resulting mixture. The degree of dendronization reached was 28%. The microspheres were prepared by coacervation/precipitation, after which the surfaces were activated with either epychlorohydrine (ECH) or 1,4-butanediol diglycidyl ether (BDGE). The oxirane groups were utilized to form covalent bonds between chitosan and dendrons. The degree of dendronization yielded with Behera's amine was 60% for both activating agents. When bis Behera's amine was used, the dendronization reached values of 15 and 21% when ECH or BDGE were used, respectively. The dendronized products were characterized through spectroscopic and microscopic studies and by determination of swelling indexes. Only one of the surfaces was dendronized in every film, which therefore presented a hydrophobic and a hydrophilic surface. Since these films maintain the properties of chitosan, they offer interesting potential as dressings for exuding wounds. The different surfaces make the microspheres potentially applicable as carriers for delivery and controlled release of drugs. 相似文献
95.
Miriam Cohen 《代数通讯》2013,41(12):4618-4633
We extend the notion of conjugacy classes and class sums from finite groups to semisimple Hopf algebras and show that the conjugacy classes are obtained from the factorization of H as irreducible left D(H)-modules. For quasitriangular semisimple Hopf algebras H, we prove that the product of two class sums is an integral combination of the class sums up to d ?2 where d = dim H. We show also that in this case the character table is obtained from the S-matrix associated to D(H). Finally, we calculate explicitly the generalized character table of D(kS 3), which is not a character table for any group. It moreover provides an example of a product of two class sums which is not an integral combination of class sums. 相似文献
96.
97.
Let R be a group graded ring . The map ( , ): R × R →1 defined by: (x,y) = (xy)1 , is an inner product on R. In this paper we investigate aspects of nondegeneracy of the product, which is a generalization of the notion of strongly G —graded rings,introduced by Dade. We show that various chain conditions are satisfied by R if and only if they are satisfied by R1 , and that when R1 is simple artinian, then R is a crossed product R1 * G. We give conditions for simple R-modules to be completely reducible R1 -modules . Finally, we prove an incomparability theorem,when G is finite abelian. 相似文献
98.
Miriam Kohagen Frank Uhlig Jens Smiatek 《International journal of quantum chemistry》2019,119(14):e25933
Recent experimental results indicate that the stability of non-Watson-Crick DNA i-motif structures can be influenced by the presence of various metal cations. Whereas Au+, Cu+, and Ag+ are stabilizing agents, alkali metal ions like Na+ or Li+ are known to destabilize the i-motif. In terms of reduced ion-cytosine complexes, we rationalize the experimental observations with the help of standard and conceptual density functional theory (DFT) calculations. Our results highlight the importance of coordinating electrostatic bonds with partially covalent character for the stability of the ion-cytosine complex. The occurrence of these bonds can be mainly attributed to charge transfer processes between two cytosines and the transition metal ions, which can be either explained by frontier molecular orbital theory in combination with a bond critical point analysis, or by the concept of chemical reactivity indices within a conceptual DFT approach. The results of our calculations establish a consistent theoretical framework to understand the experimentally observed behavior, and are also important in order to achieve more detailed insights into nucleobase pairing mechanisms in general. 相似文献
99.
Trigo M Sheu YM Arms DA Chen J Ghimire S Goldman RS Landahl E Merlin R Peterson E Reason M Reis DA 《Physical review letters》2008,101(2):025505
Ultrafast laser excitation of an InGaAs/InAlAs superlattice (SL) creates coherent folded acoustic phonons that subsequently leak into the bulk (InP) substrate. Upon transmission, the phonons become "unfolded" into bulk modes and acquire a wave vector much larger than that of the light. We show that time-resolved x-ray diffraction is sensitive to this large-wave vector excitation in the substrate. Comparison with dynamical diffraction simulations of propagating strain supports our interpretation. 相似文献
100.