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81.
Luis E. Piñero Carmelo García Virginie Lhiaubet‐Vallet Rolando Oyola Miguel A. Miranda 《Photochemistry and photobiology》2009,85(4):895-900
Chlorprothixene (CPTX, Taractan®) is a low potency antipsychotic mainly used for the treatment of psychotic disorders (e.g. schizophrenia) and acute mania occurring as part of bipolar disorders. As in the case of other numerous drugs used in the treatment of psychiatric disorders, CPTX presents geometric isomerism. Therefore, in vitro irradiation induces a rapid Z/E isomerization, which can affect its pharmacokinetic properties. This photoisomerization is not dependent on the oxygen concentration. The Z/E quantum yields determined for zCPTX in acetonitrile are 0.22 and 0.21 in anaerobic and aerobic environments, respectively. In the presence of water, both isomers decompose to produce 2‐chlorothioxanthone (CTX) after prolonged irradiation. This process strongly depends on the water concentration and the irradiation time, i.e. it is autocatalyzed by the CTX through a triplet‐energy transfer mechanism. The protonation state of the terminal amino group, on the other hand, has no effect on the isomerization process, but inhibits the formation of CTX. These results indicate that the phototoxicity of zCPTX is somehow affected by the formation of CTX. 相似文献
82.
R. F.S. Andrade J. G.V. Miranda S. T.R. Pinho T. P. Lobão 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(2):247-256
A concept of higher order neighborhood in complex networks,
introduced previously [Phys. Rev. E 73, 046101 (2006)], is systematically
explored to investigate larger scale structures in complex networks. The
basic idea is to consider each higher order neighborhood as a network in
itself, represented by a corresponding adjacency matrix, and to settle a
plenty of new parameters in order to obtain a best characterization of the
whole network. Usual network indices are then used to evaluate the
properties of each neighborhood. The identification of high order
neighborhoods is also regarded as intermediary step towards the evaluation
of global network properties, like the diameter, average shortest path
between node, and network fractal dimension. Results for a large number of
typical networks are presented and discussed. 相似文献
83.
84.
A series of supports functionalized with different alkyl chains and covered with magnetite were synthesized, characterized and applied in the sample pre-concentration of four non-steroidal anti-inflammatory drugs (acetaminophen, naproxen, diclofenac and ibuprofen) contained in wastewater samples. The general methodology involved magnetic solid phase dispersion followed by the analysis by high-performance liquid chromatography with ultraviolet detection. The magnetic supports were initially dispersed in the samples with the aid of Triton X-100, then supports were magnetically isolated and the analytes were eluted with methanol. Finally the extract was injected into the HPLC system. The highest recovery percentage (>90%) was obtained with the support containing octyl chains (C8) at pH 3. The lowest limits of detection achieved ranged within 1-2 μg L−1 with repeatability (expressed as RSD) below 5% in all cases. The method was applied in the analysis of wastewater samples. 相似文献
85.
The combined effects of an in-growth direction applied electric field and hydrostatic pressure on the exciton binding energy and photoluminescence energy transitions are reported in this work for triple vertically coupled quantum dots. The calculations have been carried out within the effective mass approximation, and using a variational procedure. The results show that the exciton binding energy and the photoluminescence energy transitions are functions of external probes like the hydrostatic pressure and the applied electric field. 相似文献
86.
A problem of decision making under uncertainty in which the choice must be made between two sets of alternatives instead of two single ones is considered. A number of choice rules are proposed and their main properties are investigated, focusing particularly on the generalizations of stochastic dominance and statistical preference. The particular cases where imprecision is present in the utilities or in the beliefs associated to two alternatives are considered. 相似文献
87.
V. Rodríguez-Lugo L. Ortiz-Velázquez J. Miranda M. Ortiz-Rojas V. M. Castaño 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(2):561-569
The characterization of samples of painted plasters obtained from the archaeological site of Xochicalco, in Central Mexico,
is presented. Elemental concentrations of the painted layers were obtained by using proton induced X-ray emission (PIXE).
The main crystalline structures of the samples are identified with the help of X-ray diffraction (XRD), while the microstructure
is studied by scanning electron microscopy (SEM). The information resulting from the application of these three techniques
is used to achieve more accurate values for the elemental concentrations. Additional data regarding organic components of
the paintings was obtained through Fourier transform infrared spectrometry (FTIR). Although the latter results only provided
reliable data on inorganic components, they help to clarify the results from XRD and confirm those of SEM. 相似文献
88.
M. Agostinha R. Matos Margarida S. Miranda Victor M. F. Morais Joel F. Liebman 《Molecular physics》2013,111(2-3):221-228
The standard molar enthalpies of combustion, sublimation, and formation in the crystalline and gaseous phase at a temperature of 298.15?K have been experimentally determined for saccharin and for benzenesulfonamide. These compounds were also studied theoretically using density functional theory, the B3LYP functional and extended basis sets. 相似文献
89.
90.
A cohomological method for computing the set of similarity classes of endomorphisms locally similar to a given endomorphism is presented and several calculations are made. 相似文献