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101.
Song and Mason equation of state (EOS) with a simple modification has been extended to modelling PVT properties of ionic liquids (ILs). The considered ILs are [C1mim][MeSO4], [C1mim][CH3OC2H5SO4], [C1mim][(CH3)2PO4], [C2mim][MeSO4], [C2mim][BF4], [C2mim][SCN], [C2eim][NTf2], [C4mim][C(CN)3], [C4mim][CF3SO3], [C4mim][SCN], [C5mim][NTf2], [C8mim][NTf2], [(C6H13)3P(C14H29)][Cl], [(C6H13)3P(C14H29)][NTf2], [(C6H13)3P(C14H29)][Ac], [C3mpyr][NTf2], [C4mpyr][NTf2] and [Py][C2H5OC2H4SO4]. Three temperature-dependent parameters in the proposed EOS have been scaled as functions of reduced temperature with the use of the law of corresponding states. It is shown that the knowledge of just critical temperature and critical density is sufficient to predict the PVT properties of these ILs. The overall average absolute deviation of calculated densities from literature values for 1347 data points of 18 ILs was found to be 0.58%. The predicted density of ILs from proposed EOS has been compared with those obtained by other literature work. Moreover, we indicate that the Zeno line regularity can well be predicted by proposed model for ILs. 相似文献
102.
Miró P Pierrefixe S Gicquel M Gil A Bo C 《Journal of the American Chemical Society》2010,132(50):17787-17794
Uranyl-peroxide nanoclusters display different topologies based on square, pentagonal and hexagonal building blocks. Computed complexation energies of different cations (Li(+), Na(+), K(+), Rb(+), and Cs(+)) with [UO(2)(O(2))(H(2)O)](n) (n = 4, 5, and 6) macrocycles suggest a strong cation templating effect. The inherent bent structure of a U-O(2)-U model dimer is demonstrated and justified through the analysis of its electronic structure, as well as of the inherent curvature of the four-, five-, and six-uranyl macrocyles. The curvature is enhaced by cation coordination, which is suggested to be the driving force for the self-assembly of the nanocapsules. 相似文献
103.
A simple, rapid and efficient sample preparation technique, dispersive liquid-liquid microextraction, coupled with gas chromatography-flame ionization detection has been developed to determine N-methylpyrrolidine in cefepime. The effect of various experimental factors on the preparation procedure, such as the nature and volume of extraction and disperser solvents, extraction time, the nature of buffer and its pH, and salt effect, was investigated, optimized and the following results were obtained: extraction solvent, chloroform; dispersive solvent and solvent for dissolving cefepime, a mixture of methanol/water (88:12, v/v); salting out agent, NaCl; and buffer, carbonate/bicarbonate (C=0.5?M, pH=12). The optimized conditions were applied to the real sample (cefepime) for the extraction and determination of N-methylpyrrolidine. The calibration graph is linear from 0.02 to 850?mg/L with the square of correlation coefficient 0.999. LOD and LOQ are 6.4 and 21.2?μg/L in solution, respectively, and 0.2 (2×10(-5) ) and 0.6 (6×10(-5) ) μg/g (%, w/w) in cefepime powder, respectively, using sample size 50?mg. Repeatability of the method is good and RSD% for six repeated experiments (C=170?mg/L) is 6.35%. 相似文献
104.
A selective and sensitive method for simultaneous determination of lead, zinc and copper by adsorptive differential pulse
cathodic stripping voltammetry is presented. The method is based on adsorptive accumulation of the complexes of Pb(II), Zn(II),
and Cu(II) ions with dopamine onto hanging mercury drop electrode (HMDE), followed by reduction of adsorbed species by differential
pulse cathodic stripping voltammetry. The effect of experimental parameters such as pH, dopamine concentration, accumulation
time and potential and scan rate were examined. Under the optimized conditions, linear calibration curves were established
for the concentration of Pb, Zn, and Cu in the ranges of 5–150, 5–250, and 1–150 ng/mL, respectively. Detection limits of
0.06, 0.25, and 0.04 ng/mL for Pb, Zn, and Cu were obtained. An application of the proposed method is reported for the determination
of these elements in some real samples such as natural waters and alloys. 相似文献
105.
S. Abbas Mousavi Susan Dadbin Masoud Frounchi David C. Venerus Teresita Guadarrama Medina 《Radiation Physics and Chemistry》2010,79(10):1088-1094
Chemical and electron beam irradiation methods were used to introduce a branched structure into polypropylene and propylene–ethylene copolymer. The chemical method was carried out in an internal mixer using initiator and TMPTMA monomer. In irradiation method, the polymer was irradiated by electron beam under air and nitrogen atmosphere. The branched structure in the modified polymer was confirmed by rheological measurements. While degradation was significant in chemical method, branching occurred efficiently by irradiation under air. Small amount of ethylene in the propylene copolymer promoted branching over degradation. 相似文献
106.
Hassan Saadat S. N. Mousavi A. M. Saadat 《International Journal of Theoretical Physics》2011,50(9):2878-2883
In this article we consider the holographic dark energy density. We study dark energy density in Universe with arbitrary spatially
curvature described by the Friedmann-Robertson-Walker metric. We use Jassal-Bagla-Padmanabhan parametrization to specify dark
energy density. 相似文献
107.
We first analyse the anti-BRST and double BRST structures of a certain higher derivative theory that has been known to possess
BRST symmetry associated with its higher derivative structure. We discuss the invariance of this theory under shift symmetry
in the Batalin–Vilkovisky (BV) formalism. We show that the action for this theory can be written in a manifestly extended
BRST invariant manner in superspace formalism using one Grassmann coordinate. It can also be written in a manifestly extended
BRST invariant manner and on-shell manifestly extended anti-BRST invariant manner in superspace formalism using two Grassmann
coordinates. 相似文献
108.
In this paper we consider a class of polynomials P(z) = a0+∑n v=t a v z v, t ≥ 1not vanishing in |z|k, k≥1 and investigate the dependence of max|z|=1|P(Rz)-P(rz)on max|z|=1|P(z)|, where 1 ≤ r R. Our result generalizes and refines some know polynomial inequalities. 相似文献
109.
110.
The circular Gaussian beam shape has been simulated by numerical evaluation on beam shape based on z-scan method through beam radius. This method is useful in many studies such as z-scan experiments. The validity of the relation between peak and valley separation in close aperture data and the diffraction length of the beam has been investigated by this method for some real cases. The results are in good agreement with the experimental studies. 相似文献