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101.
Mondal M Kumar S Chand M Kamlapure A Saraswat G Seibold G Benfatto L Raychaudhuri P 《Physical review letters》2011,107(21):217003
We analyze the occurrence of the Berezinskii-Kosterlitz-Thouless (BKT) transition in thin films of NbN at various film thickness, by probing the effect of vortex fluctuations on the temperature dependence of the superfluid density below T(BKT) and of the resistivity above T(BKT). By direct comparison between the experimental data and the theory, we show the crucial role played by the vortex-core energy in determining the characteristic signatures of the BKT physics, and we estimate its dependence on the disorder level. Our work provides a paradigmatic example of BKT physics in a quasi-two-dimensional superconductor. 相似文献
102.
Aminopeptidase N (APN) inhibitors have been reported to be effective in treating of life threatening diseases including cancer. Validated ligand- and structure-based pharmacophore mapping approaches were combined with Bayesian modeling and recursive partitioning to identify structural and physicochemical requirements for highly active APN inhibitors. Based on the assumption that ligand- and structure-based pharmacophore models are complementary, the efficacy of ‘multiple pharmacophore screening’ for filtering true positive virtual hits was investigated. These multiple pharmacophore screening methods were utilized to search novel virtual hits for APN inhibition. The number of hits was refined and reduced by recursive partitioning, drug-likeliness, pharmacokinetic property prediction, and comparative molecular-docking studies. Four compounds were proposed as the potential virtual hits for APN enzyme inhibition. 相似文献
103.
Arijit Halder Dr. Biswajit Bhattacharya Fazle Haque Susanta Dinda Dr. Debajyoti Ghoshal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12196-12205
A pair of supramolecular isomers of CdII-based MOF have been synthesized by utilizing a flexible N,N′-donor linker and a dicarboxylate with ESIPT (excited-state intramolecular proton transfer) fluorophore by varying the reaction media. One of the MOFs has a 3D four-fold interpenetrating framework with guest solvent in the structure that undergoes a solvent-dependent crystalline-to-crystalline structural transformation, which has been extensively studied by powder XRD and IR spectroscopy. The other MOF is structurally rigid in nature and has a two-fold interpenetrating structure without any guest molecules. Both the compounds show moderate CO2 adsorption and one of them, the MOF with the four-fold interpenetrating structure, also shows moderately high H2 adsorption. Furthermore, both the compounds show interesting luminescence behavior. In the solid state, the two compounds show single-peak spectra, whereas upon suspension of these compounds in polar solvents, the maxima split into two peaks with a large Stokes shift. On the other hand, in nonpolar solvents, only one emission maximum is observed. This solvatochromic dual-emission phenomenon is due to ESIPT, which has been extensively studied. 相似文献
104.
The current methodology reveals a green and proficient electro-oxidative tandem selenocyclization of thioallyl benzoimidazoles manufacturing selenylated dihydro-benzoimidazo-thiazine derivatives. Both C−Se and C−N bond formation were achieved via this mild protocol which exhibits good functional group tolerability affording an extensive range of substrate scope up to 96% isolated yields. Complete control over the regioselective formation of the six-membered heterocycle and stereoselective construction of the contiguous stereocenters was established. The practical electrochemical method operates in an undivided cell at ambient temperature without using any metal and external chemical oxidant. 相似文献
105.
106.
Joydeb Chanda Pulok K. Mukherjee Amit Kar Prasanta Kr. Maitra Seha Singha Pallab Kanti Halder Rahul Gajbhiye Ravichandiran Vishnuvardh 《Biomedical chromatography : BMC》2020,34(12):e4950
Coccinia grandis is an important food crop of the Cucurbitaceae family, widely used for culinary purposes in India. It is reported to possess hypoglycemic, hypolipidemic and antioxidant activities. The current study was aimed to explore the inhibition kinetics as well as major constituents of the active fraction of C. grandis against α-glucosidase. The kinetic study was performed through spectrophotometric assay, with p-nitrophenyl-α-d -glucopyranoside as a substrate with varying concentrations. An in vitro antioxidant study was performed by DPPH assay. In addition, UPLC–QTOF–MS analysis was carried out for metabolite profiling of the bioactive fraction of C. grandis. The results showed that the difference between the α-glucosidase inhibitory activity of the ethyl acetate fraction of C. grandis (EFCG) (IC50 2.43 ± 0.27 mg/ml), and standard inhibitor, acarbose (2.08 ± 0.19 mg/ml), was not statistically significant at a P-value of 0.05. The enzyme kinetics confirmed the inhibition mode in a mixed manner. The EFCG also showed the highest antioxidant activity (101.74 ± 1.95 μg/ml) among all of the fractions. A significant correlation between antioxidant and α-glucosidase inhibitory activity of EFCG was observed. The LC–QTOF–MS study of the EFCG putatively identified 35 metabolites, which may be responsible for its antioxidant and α-glucosidase inhibitory properties. Thus, C. grandis fruits can serve as a functional food to address diabetes-related disorders associated with α-glucosidase. 相似文献
107.
Shock diffraction over a two-dimensional wedge and subsequent shock–vortex interaction have been numerically simulated using the AUSM $+$ + scheme. After the passage of the incident shock over the wedge, the generated tip vortex interacts with a reflected shock. The resulting shock pattern has been captured well. It matches the existing experimental and numerical results reported in the literature. We solve the Navier–Stokes equations using high accuracy schemes and extend the existing results by focussing on the Kelvin–Helmholtz instability generated vortices which follow a spiral path to the vortex core and on their way interact with shock waves embedded within the vortex. Vortex detection algorithms have been used to visualize the spiral structure of the initial vortex and its final breakdown into a turbulent state. Plotting the dilatation field we notice a new source of diverging acoustic waves and a lambda shock at the wedge tip. 相似文献
108.
S. Halder K. Parida S.N. Das S.K. Pradhan S. Bhuyan R.N.P. Choudhary 《Physics letters. A》2018,382(10):716-722
A polycrystalline vanadium doped lead free dielectric material of Bi(Zn2/3V1/3)O3 (BZV) has been prepared using a standard high-temperature solid state reaction technique. Its temperature and frequency dependent capacitive, conductive and resistive characteristics are outlined though experimental investigation. The formation of single phase compound of BZV material with orthorhombic crystal symmetry is identified through X-ray diffraction data analysis, and the homogeneous distribution of grains are realized through scanning electron micrograph. The acquaintance of frequency–temperature dependent electrical parameters with the obtained micrograph provides the experimental evidence of contributions of grain as well as grain boundary in its capacitive and resistive characteristics. The negative temperature coefficient of resistance behaviour of the material is revealed from impedance characteristic, and non-Debye type relaxation has been realized from the Nyquist plot. The charge carriers of this electronic compound have both long & short range order that has been validated from the complex modulus and impedance analysis. The prepared electronic material substantiate some important dielectric features which props up the material as promising component for electronic devices. 相似文献
109.
Reduced graphene oxide supported gold nanoparticles for electrocatalytic reduction of carbon dioxide
Electrochemical reduction of carbon dioxide is one of the methods which have the capability to recycle CO2 into valuable products for energy and industrial applications. This research article describes about a new electrocatalyst “reduced graphene oxide supported gold nanoparticles” for selective electrochemical conversion of carbon dioxide to carbon monoxide. The main aim for conversion of CO2 to CO lies in the fact that the latter is an important component of syn gas (a mixture of hydrogen and carbon monoxide), which is then converted into liquid fuel via well-known industrial process called Fischer-Tropsch process. In this work, we have synthesized different composites of the gold nanoparticles supported on defective reduced graphene oxide to evaluate the catalytic activity of reduced graphene oxide (RGO)-supported gold nanoparticles and the role of defective RGO support towards the electrochemical reduction of CO2. Electrochemical and impedance measurements demonstrate that higher concentration of gold nanoparticles on the graphene support led to remarkable decrease in the onset potential of 240 mV and increase in the current density for CO2 reduction. Lower impedance and Tafel slope values also clearly support our findings for the better performance of RGOAu than bare Au for CO2 reduction. 相似文献
110.
S. Sengupta N. Halder S. Chakrabarti Miriam Herrera Marta Bonds Nigel D. Browning 《Superlattices and Microstructures》2009
Effect of growth pause or ripening time on structural and optical properties of self-assembled InAs/GaAs quantum dot (QD) heterostructures grown by solid state molecular beam epitaxy (MBE ) technique with two different growth rates of InAs (0.032 MLs−1 and 0.197 MLs−1) has been investigated. The QD heterostructures were grown at 520 °C with InAs monolayer coverage of 2.7 ML. The results were explained on the basis of high angle annular dark field scanning transmission electron microscope (HAADF-STEM), scanning electron microscope (SEM) and photoluminescence (PL) measurements. Introduction of growth pause leads the QD system towards a thermodynamic equilibrium state which in turn makes interesting changes on the morphology of the samples. Coagulation of some smaller dots occurs because of ripening to produce evolved QDs and the dot density reduces with growth pause. 相似文献