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31.
Amidinothiourea immobilized glass bead (AGB) was applied as the microcolumn packing for the flow-injection online separation
and preconcentration of Au(III) and Pd(II) coupled with FAAS determination. The peak-area absorbance (A) and the peak-height
absorbance (H) were all used as the evaluating modes. Au(III) and Pd(II) in 0.50 M HCl solution were absorbed onto AGB completely
and then eluted into AAS with thiourea solution. Base metal ions with a concentration of 2.0 mg/mL and anions with a concentration
of 20.0 mg/mL caused no interference in the determination of Au(III) and Pd(II). The LODs of Au(III) and Pd(II) for a preconcentration
time of 60 s with a sampling flow rate of 5.0 mL/min for 0.20 μg/mL of Au(III) and 0.30 μg/mL of Pd(II) were 2.7 and 6.5 ng/mL
with the H mode and 4.6 and 10.2 ng/mL with the A mode, respectively. The RSD of seven replicate determinations of 0.20 μg/mL
of Au(III) and 0.30 μg/mL of Pd(II) were 0.018 and 0.024 for the H mode and 0.013 and 0.018 for the A mode, respectively.
The method was successfully applied to the determination of Au and Pd in real samples.
__________
From Zhurnal Analiticheskoi Khimii, Vol. 60, No. 10, 2005, pp. 1023–1029.
Original English Text Copyright ? 2005 by Liu, Pu, Su.
The text was submitted by the authors in English. 相似文献
32.
A method is presented that allows novel measurement of the effect of microstructure on the oxygen permeability of highly condensed, polycrystalline phospholipid monolayers. Oxygen permeability of the polycrystalline shell coating a stationary microbubble is measured directly using an apposing microelectrode in the induced transfer mode and modeling oxygen flux through the shell and intervening aqueous medium. Varying cooling rate through the phospholipid main phase transition permits control of shell microstructure by manipulation of crystalline domain size and shape. Domain boundary density, defined as the ratio of the mean domain perimeter to the mean domain area, of the microbubble shell is determined by fluorescence microscopy. Oxygen permeability was shown to increase linearly with domain boundary density at a constant phospholipid acyl chain length and, accordingly, was shown to decrease exponentially with increasing chain length at a constant domain boundary density. Modification of the energy barrier theory to account for microstructural effects, in terms of the domain boundary density, provides a general equation to model passive transport through polycrystalline monolayer films. Results from this method show promise in determining the gas transport kinetics of medical microbubbles and the gas exchange characteristics of biological monolayers. 相似文献
33.
34.
The shuttle effect is understood to be the most significant issue that needs to be solved to improve the performance of lithium–sulfur batteries. In this study, ultrathin two-dimensional Fe–Co bimetallic oxide nanosheets were prepared using graphene as a template, which could rapidly catalyze the conversion of polysulfides and inhibit the shuttle effect. Additionally, such ultrathin nanostructures based on graphene provided sufficient active sites and fast diffusion pathways for lithium ions. Taking into account the aforementioned benefits, the ultrathin two-dimensional Fe–Co bimetallic oxide nanosheets modified separator assembled lithium–sulfur batteries delivered an incredible capacity of 1044.2 mAh g−1 at 1 C and retained an excellent reversible capacity of 859.4 mAh g−1 after 100 cycles. Even under high loading, it still achieved high area capacity and good cycle stability (92.6% capacity retention). 相似文献
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在神光Ⅲ主机装置上,利用已经建成的两个激光束组,开展了激光间接驱动内爆物理磨合实验,是神光Ⅲ主机装置首次出中子实验。实验采用f1400 mm2100 mm黑腔,f500 mm的塑料靶丸充1 MPa的DD燃料,激光从黑腔两端55注入。实验获得的最高中子产额为9.7108。实验结果表明,实验黑腔的耦合效率约为50%;使用的黑腔偏长,靶丸被压缩为薄饼形;中子产额和激光能量正相关;中子发射峰值时刻主要依赖于烧蚀层厚度。 相似文献
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38.
Pu Lin Peifu Luo Yating Guo Honglong Qiu Min Wang Guoming Huang 《Particle & Particle Systems Characterization》2021,38(10):2100113
In this study, the synthesis of TaN nanosheets and their application in theranostic agents is reported. After coating polyethylene glycol (PEG) on the TaN nanosheets, the as-synthesized PEG-modified TaN nanosheets (TaN-PEG) show good stability and biocompatibility. Because of their high absorbance in the near-IR region, TaN-PEG can be utilized as photoacoustic imaging contrast agents for tumor imaging. Moreover, TaN-PEG has significant photothermal conversion performance, exhibiting effective laser-induced tumor ablation capability. The TaN-PEG possessing excellent photoacoustic contrast effect and photothermal properties thus have great promise in theranostic applications, especially imaging-guided cancer treatment. 相似文献
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投料顺序对动态硫化PP/EPDM性能影响及其机理的研究 总被引:12,自引:0,他引:12
针对PP降解在PP/EPDM动态硫化中对体系产生的不利影响。考察了四种不同投料顺序对PP/EPDM动态硫化物的冲击韧性,加工流动性,交联程度和断面形貌等宏观和微观性能,并进行了不同EPDM含量的动态硫化和非硫化PP/EPDM的性能比较。结果表明,优化投料顺序能实现对动态硫化体系中化学反应对象和化学反应程度的有效干预。 相似文献