Poly(aryl ether) bearing electroactive tetraaniline pendants and allyl groups: Synthesis,photo‐crosslinking and electrochemical properties

We describe the synthesis of a novel electroactive photo‐crosslinkable poly(aryl ether), containing tetraaniline pendants and allyl groups (EPPAE). The polymer structure and spectral properties are studied in detail. By introducing the electroactive tetraaniline pandents, EPPAE reveals reversible electrochemical activity, expected electrochromic behavior and good anticorrosive performance. After crosslinking the allyl groups with UV exposure, the resultant polymer (c‐EPPAE) shows drastic change in electrochemical properties. The c‐EPPAE/ITO electrode exhibits declining electroactivity but excellent electrochemical stability, which are associated with densification of the electroactive layer. Furthermore, in the corrosive protection measurements, c‐EPPAE reveals an outstanding protection efficiency (99.92%) for stainless steel substrates. A comprehensive study of electrochromic properties and corrosive protection of EPPAE before and after UV exposure will provide an insightful tool for the developing electrochromic smart windows, electrochromic displays, and anticorrosive paint. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2321–2330     

毛细管电泳电化学法监测甘露糖生产工艺

葡萄糖;葡萄糖酸钙;毛细管电泳电化学法监测甘露糖生产工艺;电化学检测     

一步法合成大孔丙烯酸交联树脂

悬浮聚合;二乙烯苯;一步法合成大孔丙烯酸交联树脂     

Investigation of synchroniser engagement in dual clutch transmission equipped powertrains

Transient response of a dual clutch transmission (DCT) powertrain to synchroniser mechanism engagements is investigated using a lumped inertia model of the powertrain. Original research integrates lumped inertia powertrain models for the DCT with a detailed synchroniser mechanism model and two separate engine models, comprising of a mean torque model and a harmonic torque model, using torque derived from piston firing. Simulations are used to investigate the synchroniser mechanism engagement process in a previously unscrutinised operating environment. Simulations are performed using both engine torque models, with the mean torque model demonstrates the highly nonlinear nature of synchroniser mechanism engagement, and the powertrain response to the engagement process. Through the introduction of harmonic engine torques, additional excitation is present in the mechanism during engagement, and increased vibration of the synchroniser sleeve results. The impact of vibrations is particularly important to the increased wear of indexing chamfer contact surfaces.     

Bi-Lipschitz maps in <Emphasis Type="Italic">Q</Emphasis>-regular Loewner spaces

By applying the theory of quasiconformal maps in measure metric spaces that was introduced by Heinonen-Koskela, we characterize bi-Lipschitz maps by modulus inequalities of rings and maximal, minimal derivatives in Q-regular Loewner spaces. Meanwhile the sufficient and necessary conditions for quasiconformal maps to become bi-Lipschitz maps are also obtained. These results generalize Rohde’s theorem in ℝ ⁿ and improve Balogh’s corresponding results in Carnot groups. This research is supported by China NSF (Grant No. 10271077)     

Application of Nanogold Probe Coupled with Silver Enhancement in Rapid cTnI Colorimetric Immunoassay

Cardiac troponin I (cTnI) in the serum of patients has been established as a principal biochemical marker of myocardial damage1-4. Fast detection of cTnI will be helpful for the diagnosis of acute myocardial infarction (AMI), the identification of myocardial injury (MI) and the stratification of cardiac risk. A number of serological tests have been developed for the detection of cTnI. As known, among many methods, enzyme-linked immunosorbent assay (ELISA) and radioimmunoassay (RIA) wer…     

Capillary Column Coated with Heptakis（2,3,6-tri-O-octyl）-β-cyclodextrin Using Sol-gel Technology

Heptakis(2,3,6-tri-O-octyl)-β-cyclodextrin was coated onto the fused silica capillary by sol-gel technology.Column efficiency and column selectivity were studied.The results indicated that high ability of separation was acquired.Positional isomers of aromatic compounds were well separated.     

Determination of Enantiomeric Purity of ν-Pyrrolidinyl Phenylpropanol by Capillary Electrophoresis Using β-Cyclodextrin Polymer as Chiral Selector

Determining the enantiomeric excess value of novel chiral compounds is of great importance in asymmetry synthesis. NMR1, HPLC and GC are the ordinary methods applied in this work. In recent years, capillary electrophoresis has been successfully used in chiral separation2. In this paper, we separated the enantiomer of (-pyrrolidinyl phenylpropanol (Figure 1) by capillary electrophoresis using (-cyclodextrin polymer as chiral selector. According to the ratio of peak area with migration time,…     

基于追踪控制的混沌异结构同步

针对连续混沌系统，提出一种混沌异结构同步追踪控制方案.利用Lyapunov方法证明了当受控系统满足Lipchitz条件时，即可使其状态输出指数收敛到任意给定的参考信号.设计的控制器结构对不同的混沌系统具有统一的形式，可实现任意混沌系统之间的异结构同步.数值仿真进一步表明了该方法的有效性. 关键词： 混沌系统 追踪控制 同步