输液管振动与稳定性研究的新进展:从宏观尺度到微纳米尺度

本文围绕不同尺度级的输液管结构,针对液流引起的管道振动与稳定性综述了目前已有的几种物理和数学模型,详细介绍了梁模型输液管的各类振动控制方程,重点讨论了宏观尺度、微米尺度和纳米尺度下输液管振动方程的异同点.在此基础之上,进一步概述了近几年这些输液管振动与稳定性问题研究的现状和一些重要研究结果,其中也包括作者们近期的相关工作.最后对未来的研究趋势作了分析和预测.通过本文可以看到,输液管振动问题仍有不少难题尚未很好解决,特别是微纳米输液管的建模和流固耦振机理方面的研究亟需加强.     

含非线性能量汇的简支输液管非线性振动控制研究

论文建立了一个含有非线性能量汇(NES)装置并输运脉动内流的简支输液管道理论模型,研究了NES装置对管道的非线性动力学特性与振动控制的影响.利用Galerkin和龙格库塔法,得到了在含NES和不含NES装置时管道动力学响应的数值结果.研究表明,NES装置能有效地抑制管道振动.通过对比可知,NES对管道系统的稳定性和非线性振动控制有着明显的影响.此外,论文还详细讨论了NES装置相关参数对系统的动力学影响.结果表明,增大NES的弹簧刚度k、阻尼σ和质量比e有利于管道减振,且最佳安装位置在管道中点.此外,增大阻尼σ能缩小失稳激励频率区域,而其他参数的变化对失稳激励频率区域影响较小.     

国产复合功能光纤实现万瓦激光输出

正作为长距离分布式侧面泵浦技术的典型代表,泵浦增益一体化复合功能激光光纤(Pump-gain integrated Functional Laser Fiber,PIFL-fiber)是包含单根增益光纤与多根泵浦光纤的多功能集成器件。基于倏逝波耦合效应巧妙地解决了超大泵浦功率注入的技术难题,已成为高功率光纤激光放大技术的主流技术方案之一。2018年2月,中国工程物理研究院激光聚变研究中心科研人员成功制备(8+1)型PIFL复合功能激光光     

谐激励作用下输流曲管的混沌振动研究

研究了谐激励作用下输流曲管在系统参数区域内的混沌振动.基于牛顿法导出了输流曲管模型的非线性控制方程,并利用微分求积法对此方程在空间域进行离散,导出了输流曲管的非线性动力学方程组.在此基础上,对输流管道的动力响应进行了数值模拟.采用分岔、相平面、时间历程和庞加莱映射图等手段分析发现,在流速和激励频率的参数区域内,系统将可能发生包括混沌振动在内的多种运动形式.系统可经由倍周期分岔或概周期运动通向混沌.分析结果为工程输流管道模型的合理设计提供了参考.     

Preparation and Luminescence Properties of the Ternary Europium Complex Incorporated into an Inorganic/Polymer Matrix by a Sol-Gel Method

Ternary europium complexes with thenoyltrifluoroacetone (TTA) and phenanthroline (phen) were incorporated into SiO₂/polymer matrix by a sol-gel method. The gels exhibit the characteristic emission bands of europium ion. In addition, Eu³⁺ presents a longer fluorescence lifetime in gel than in the corresponding pure complex powder. Concentration effects on the luminescence intensity were investigated. The reasons that are responsible for above results are also discussed in the context.     

One-pot synthesis of 2,5-disubstituted-1,3,4-thiadiazoles under ultrasonic irradiation

A facile one-pot synthesis of 2,5-disubstituted-1,3,4-thiadiazoles was achieved by ultrasonic irradiation of a mixture of 1- naphthylacetyl chloride,NH_4CNS,CH_2Cl_2 and PEG-400 for 1.5 h at 10-20℃and subsequent irradiation for 1.5h in the presence of N-arylglycine hydrazides.This method requires short time and gives thiadiazoles in high yields.     

Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes

Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)₂]₆[Mn(5-Brsalpn)]₆·12H₂O (1), [Co(bpmb)(CN)₂]₆[Mn(5-Brsalpn)]₆·12H₂O (2) and [Co(bpmb)(CN)₂]₆[Mn(5-Clsalpn)]₆·24H₂O·8CH₃CN (3) [bpmb²⁻= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-Brsalpn²⁻ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-Clsalpn²⁻ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)₂]⁻ anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of J _CrMn = −2.65(6) cm⁻¹ on the basis of a one-dimensional alternating chain model with the Hamiltonian $ H = - J_{CrMn} \sum\limits_{i = 0}^N {S_i \cdot S_{i + 1} } $ H = - J_{CrMn} \sum\limits_{i = 0}^N {S_i \cdot S_{i + 1} } .     

Preparation of poly(vinylphenylboronic acid) chain grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads for the selective enrichment of glycoprotein

Surface‐initiated atom transfer radical polymerization was successfully used to prepare 4‐vinylphenylboronic acid functionalized poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads for the selective enrichment of glycoprotein from complex biological samples in this study. The modified bead surfaces were characterized using Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy. The sorption behaviors, including adsorption isotherms, incubation time, and pH effect, were investigated. The results demonstrated that the boronated beads have a high affinity for glycoprotein, which is due to the well‐defined boronic acid brushes on the beads surfaces. Furthermore, the polyvinylphenylboronic acid grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads were used to efficiently enrich and purify glycoprotein from real egg white samples and α‐fetoprotein from human serum samples. The mass spectrometry results demonstrated that the polyvinylphenylboronic acid grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads are a suitable material for the enrichment of glycosylated protein from complex biological samples.     

Capillary electrochromatography with a silica column with a dynamically modified cationic surfactant.

A novel mode of capillary electrochromatography (CEC), called dynamically modified silica-capillary electrochromatography, is described in this paper. The column packed with bare silica was dynamically modified with long chain quaternary ammonium salt, cetyltrimethylammonium bromide (CTAB), which was added into the mobile phase. CTAB ions were adsorbed onto the surface of bare silica, and the resulted hydrophobic layer on the silica gel was used as the stationary phase. Using the dynamically modified silica column, neutral solutes were separated by CEC. The highest number of theoretical plates obtained was about 71,500/m and the relative standard deviations for t0 and capacity factor of toluene were 4.7% and 4.9% for 20 consecutive runs, respectively. The separation mechanism of neutral solutes and the influence of mobile phase composition on the separation was investigated. The separation of nitrogen-containing solutes was carried out with this mode and the peak tailing of basic solute was effectively eliminated because the adsorption of basic solute on silica was blocked by the preferred adsorption of CTAB.     

Mild and efficient CO-mediated eliminative deoxygenation of epoxides catalyzed by supported gold nanoparticles

Supported gold nanoparticles (NPs), which are well-known epoxidation catalysts, were found to be exceptionally active for the selective deoxygenation of epoxides into alkenes using cheap and easily accessible CO and H(2)O as the reductant.