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81.
Mary E. Neubert DAVID G. ABDALLAH Jr Sandra S. Keast Julie M. Kim Soonnam Lee Ryan M. Stayshich Margaret E. Walsh Rolfe G. Petschek Shin-Tson Wu 《Liquid crystals》2003,30(6):711-731
New diphenyldiacetylenes of the type with A, B = H and/or F; m = 0, 1; n = 1-4; and X = C n H 2n + 1 , F, CF 3 or CN were synthesized and their mesomorphic properties determined by hot stage polarizing microscopy and DSC. When m = 0, all of these compounds showed only a nematic phase except when X = CF 3 when both nematic and smectic A phases were seen. Both clearing and melting temperatures were higher than those reported for substitution with the corresponding alkyl chains but the much larger increase in clearing temperatures produced considerably wider nematic phases. Eutectic mixtures of a few of these olefins yielded nematic materials also having much wider temperature ranges and higher clearing temperatures than the eutectic mixtures of the alkyl compounds, while retaining their high birefringence and low viscosities. Such materials are of interest for beam-steering devices.
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
82.
本文给出递归集的Hausdorff维数的下界估计,并由此确定了一类递归集的维数,所获结果包含并推广了Bedford,Dekking及文志英、钟红柳等人的有关结果。 相似文献
83.
Yu-hai WU~ 《中国科学A辑(英文版)》2007,50(7):925-940
This paper concerns the number and distributions of limit cycles in a Z_2-equivariant quintic planar vector field.25 limit cycles are found in this special planar polynomial system and four different configurations of these limit cycles are also given by using the methods of the bifurcation theory and the qualitative analysis of the differential equation.It can be concluded that H(5)≥25=5~2, where H(5)is the Hilbert number for quintic polynomial systems.The results obtained are useful to study the weakened 16th Hilbert problem. 相似文献
84.
Benxin Wu 《Applied Surface Science》2007,253(8):4079-4084
The ultra-short laser metal ablation is a very complex process, the complete simulation of which requires applications of complicated hydrodynamics or molecular dynamics models, which, however, are often time-consuming and difficult to apply. For many practical applications, where the laser ablation depth is the main concern, a simplified model that is easy to apply but at the same time can also provide reasonably accurate predictions of ablation depth is very desirable. Such a model has been developed and presented in this paper, which has been found to be applicable for laser pulse duration up to 10 ps based on comparisons of model predictions with experimental measurements. 相似文献
85.
A novel heath monitoring system of the rocket based on fiber optic Bragg gratings is brought forward, its component units and working principle are also described. 相似文献
86.
87.
88.
Traveling wave Ti:LiNbO3 Mach-Zehnder optical modulators with buried electrodes and etched grooves in the SiO2 buffer layer are analyzed by the finite element method. The tradeoff between the bandwidth BW and the half-wave voltage Vπ is discussed. The value of BW/Vπ is used to weight the total performance of the modulator. Taking a thick buffer layer and etching deep grooves in the buffer layer are demonstrated as two effective methods to improve the performance of the modulator. A 3-dB optical bandwidth of 18 GHz with half-wave voltage 5V at a wavelength of 1.55 pm could be obtained even though the electrode is not very thick. When the requirement of half-wave voltage is not very critical, a bandwidth of more than 100 GHz can be obtained. 相似文献
89.
90.
The stability behaviour of a thin-film superconductor under a localized release of thermal disturbance is investigated. Two-dimensional conjugate film/substrate conduction equation with anisotropic thermal conductivity of the film, and Joule heat are employed to investigate effects of substrate and thermal properties on the intrinsic stability and quenching recovery. To consider the thermal boundary resistance between film and substrate, an interfacial-layer model (ILM) with very low diffusivity and an acoustic mismatch model (AMM) are employed. Results show that the thermal boundary resistance influences strongly the intrinsic stability. Thermal boundary resistance increases intrinsic stability if the thermal conductivity of the substrate or the disturbance energy is large. Higher Biot numbers and thermal conductivity ratios of film to substrate in longitudinal direction influence stability favorably. We demonstrate also that operation of a film/substrate system, such as YBCO/MgO, is either intrinsically stable or irrecoverably unstable.The authors wish to express their sincere appreciation to Dr. R. C. Chen for his invaluable advice and suggestions during the course of this paper. This research was supported by the National Science Council of the R. O. C. through grant NSC 83-0401-E-009-006. The computations were performed on the IBM ES/9000 at the National Center For High-Performance Computing. 相似文献