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671.
Ao LinKaori Kobayashi Hua-Gen YuGregory E. Hall James T. MuckermanTrevor J. Sears Anthony J. Merer 《Journal of Molecular Spectroscopy》2002,214(2):216-224
The rotationally resolved Ã(010)-X?(000) spectrum of DCCl between 12 880 and 12 964 cm−1 was measured using frequency-modulated laser absorption spectroscopy of jet-cooled and ambient temperature samples. Transitions to levels with Ka′=0 and 1 were assigned, and their analysis leads to improved accuracy of both the ground state rotational constants of DCCl and, when combined with existing data for HCCl, the geometry of the radical. In addition to the expected perpendicular band structure, a number of parallel (Δ Ka=0) subbands were observed. Their intensity derives from a combination of c-type Coriolis coupling and axis-switching (J. T. Hougen and J. K. G. Watson, 1965, Can. J. Phys.43, 298) resulting from the change in geometry between the two states. The two contributions have been calculated for the (010)-(000) band of DCCl and previously recorded data for HCCl. Satisfactory agreement with experimental measurements was obtained. The Coriolis contributions are small for these transitions, but may add to or subtract from the axis-switching. For higher bending excitation in the upper state, Coriolis coupling is predicted to make larger contributions to the parallel subband intensities. 相似文献
672.
De‐Hui Tuo Chao Chen Huapeng Ruan Qi‐Qiang Wang Yu‐Fei Ao Xinping Wang De‐Xian Wang 《Angewandte Chemie (International ed. in English)》2020,59(33):14040-14043
Radical pimers are the simplest and most important models for studying charge‐transfer processes and provide deep insight into π‐stacked organic materials. Notably, radical pimer systems with magnetic bi‐ or multistability may have important applications in switchable materials, thermal sensors, and information‐storage media. However, no such systems have been reported. Herein, we describe a new pimer consisting of neutral N‐(n‐propyl) benzene triimide ([BTI‐3C]) and its anionic radical ([BTI‐3C]?.) that exhibits rare magnetic multistability. The crystalline pimer was readily synthesized by reduction of BTI‐3C with cobaltocene (CoCp2). The transition occurred with a thermal hysteresis loop that was 27 K wide in the range of 170–220 K, accompanied by a smaller loop with a width of 25 K at 220–242 K. The magnetic multistability was attributed to slippage of the π‐stacked BTI structures and entropy‐driven conformational isomerization of the side propyl chains in the crystalline state during temperature variation. 相似文献
673.
Yongqian Wang Yinchang Li Ao Yuan Bo Yuan Xinrong Lei Qun Ma Jun Han Junxia Wang Jieyu Chen 《Crystal Research and Technology》2014,49(10):800-807
In this work, a series of calcium sulfate whiskers were prepared successfully using carbide slag as raw material through hydrothermal method. The prepared gypsum observed is hemihydrate calcium sulfate and the formation of the calcium sulfate whiskers are influenced by preparation parameters. The optimal preparation conditions are as follows: seriflux concentration, 4 %; hydrothermal reaction time, 10 h; hydrothermal reaction temperature, 130°C; seriflux pH, 7; calcium‐magnesium ratio, 12 : 1. Some nanowires appear when seriflux pH is very low (e.g. 1). The length‐diameter ratio of the whiskers is about 60‐80. 相似文献
674.
Doppler effect widely exists in the signal from the moving acoustic source. In order to solve such problems as frequency shift and frequency band expansion, a time domain cor- rection method is presented in this paper. First, the discrete time vector for interpolation and the amplitude restoration formula is derived based on the moving relationship and the Morse acoustic theory, then the amplitude weights are corrected and the distortion signal is interpolated. Every point of the discrete signal is operated separately in time domain. Compared with the existing frequency domain methods, this method does not need to know the characteristic frequency beforehand and would not be influenced by the blending of the frequency band. Hence, this method can be employed to correct multiple frequency signals and it is also a simple and effective Doppler effect reduction method. 相似文献
675.
To develop polarizer functioning in the extreme ultraviolet (EUV) and soft X-ray region, the polarization performance of synthetic mica has been investigated theoretically with a simulation code using Fresnel equations and optical constants from the Henke database. The reflectance of synthetic mica crystal for s and p polarization was measured to investigate its polarization performance in a home-made synchrotron radiation soft X-ray polarimeter at beamline 3W1B, Beijing Synchrotron Radiation Facility (BSRF... 相似文献
676.
The enthusiasm surrounding the clinical potential of embryonic stem cells (ESCs) and induced pluripotent stem cells (iPSCs) is tempered by the fact that key issues regarding their safety, efficacy, and long-term benefits have thus far been suboptimal. Small molecules can potentially relieve these problems at major junctions of stem cell biology and regenerative therapy. In this review we will introduce recent advances in these important areas and the first generation of small molecules used in the regenerative context. Current chemical biology studies will provide the archetype for future interdisciplinary collaborations and improve clinical benefits of cell-based therapies. 相似文献
677.
X-ray magnetic circular dichroism (XMCD) has become an important and powerful tool because it allows the study of material properties in combination with elemental specificity, chemical state specificity, and magnetic specificity. A new soft X-ray magnetic circular dichroism apparatus has been developed at the Beijing Synchrotron Radiation Facility (BSRF). The apparatus combines three experimental conditions: an ultra-high-vacuum environment, moderate magnetic fields and in-situ sample preparation to measure the absorption signal. We designed a C-type dipole electromagnet that provides magnetic fields up to 0.5 T in parallel (or anti-parallel) direction relative to the incoming X-ray beam. The performances of the electromagnet are measured and the results show good agreement with the simulation ones. Following film grown in situ by evaporation methods, XMCD measurements are performed. Combined polarization corrections, the magnetic moments of the Fe and Co films determined by sum rules are consistent with other theoretical predictions and experimental measurements. 相似文献
678.
679.
Caiyu Song Dun Ao Xiaojin Wang Jian Zhang Yebang Tan 《Colloid and polymer science》2013,291(12):2815-2823
A series of amphiphilic copolymers with fluorocarbon groups (Poly(AMPS-co-FS), PAMFS) were synthesized by the radical copolymerization of sodium 2-acryamido-2-methylpropanesulfonate (AMPS) and styrene derivatives with a fluorocarbon side chain (FS). The structures and molecular characteristics of PAMFS were confirmed by 1H-NMR, 19F-NMR, elemental analysis, and static light scattering. The aggregation behavior of the copolymer in aqueous solution was studied by surface tension, electrical conductivity, dynamic laser light scattering, transmission electron microscopy, and fluorescence measurements at different conditions. The results indicated that the surface activity of PAMFS is dependent on the content of fluorocarbon groups in the copolymer structure. The surface tension (γ cmc) and critical micelle concentration of PAMFS decrease with the increase of sodium chloride concentration. The copolymers formed micelle-like aggregates and the fluorocarbon groups exhibited a strong tendency for intermolecular association. 相似文献
680.
以Bi(NO3)3·5H2O和Ti(OC4H9)4为原料,采用自组装单层膜技术,在负载有功能化三氯十八烷基硅烷(octadecyl-trichloro-silane,OTS)的FTO基板上制备了Bi2Ti2O7薄膜。基板表面的亲水性测试表明,紫外照射使OTS自组装单层膜表面由疏水转变为亲水,实现功能化。借助X射线衍射(XRD)、X射线能量色散谱(EDS)、扫描电子显微镜(SEM)和原子力显微镜(AFM)分析分别对Bi2Ti2O7薄膜的组成、结构和微观形貌进行了表征。结果表明,沉积溶液浓度为0.02 mol·L-1时,所得Bi2Ti2O7薄膜均匀致密。560℃热处理1 h、厚度为0.4μm的Bi2Ti2O7薄膜在100 kHz的介电常数为153,介电损耗为0.089。 相似文献