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101.
102.
Chiral Phosphoric Acid Catalyzed Asymmetric Ugi Reaction by Dynamic Kinetic Resolution of the Primary Multicomponent Adduct
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Yun Zhang Dr. Yu‐Fei Ao Prof. Dr. Zhi‐Tang Huang Prof. Dr. De‐Xian Wang Prof. Dr. Mei‐Xiang Wang Prof. Dr. Jieping Zhu 《Angewandte Chemie (International ed. in English)》2016,55(17):5282-5285
Reaction of isonitriles with 3‐(arylamino)isobenzofuran‐1(3H)‐ones in the presence of a catalytic amount of an octahydro (R)‐binol‐derived chiral phosphoric acid afforded 3‐oxo‐2‐arylisoindoline‐1‐carboxamides in high yields with good to high enantioselectivities. An enantioselective Ugi four‐center three‐component reaction of 2‐formylbenzoic acids, anilines, and isonitriles was subsequently developed for the synthesis of the same heterocycle. Mechanistic studies indicate that the enantioselectivity results from the dynamic kinetic resolution of the primary Ugi adduct, rather than from the C?C bond‐forming process. The resulting heterocycle products are of significant medicinal importance. 相似文献
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CAO Zhong LIU Wei-Ren WANG Li-Lie XIE Shi-Liang JIANG Li-Ping DING Mei-Song ZHAO Ji-Lai REN You-Lai SHAN Bing ZHAO Zheng CUI Ming-Qi 《中国物理C(英文版)》1990,14(8):677-683
By using BWS-5k II streak camera made in China,we have measured the time structure of Synchrotron Radiation (SR) from the relatrivistic electron and positron beam bunches of Beijing Electron Positron Collider (BEPC).The dependence of SR width to the intensity of beam current and the voltage of RF source was also measured.The main data taken with 30ps time resolution in the experiment are as follows: The length of VR at Ee=1.549GeV is changed from 220ps to 670ps when the average beam current from 2mA to 30mA,the variation range of CR length at 20mA beam current is 500—700ps with RF source voltage varying between 250kV and 500kV.The time calibration uncertainty of the experiment is ±15%.The trigger jitter is less than ±200ps. 相似文献
106.
Pinanyldioxy styrylboronic ester (1) was employed for asymmetric 1,3-dipolar cycloaddition with nitrile oxides, optically active △2-isoxazolines (3) or 4-hydroxy-△2-isoxazolines (4) were obtained. The effect of different bases on the selectivity of the cycloaddition reaction was studied. 相似文献
107.
Room temperature phosphorescent(RTP) materials have a variety of applications ranging from bioimaging, optoelectronic devices to information security protection. However, the preparation procedures for these materials are always tedious and time-consuming. Here, we report a micro-wave approach to prepare RTP carbon dots(CDs) in only 8 min. The micro-wave promoted the carbon and boron bond formation using natural compounds glucose and boric acids. This result has been confirmed using TEM,FTIR, XP... 相似文献
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二维正方晶格光子晶体平板的近场成像特性 总被引:1,自引:1,他引:0
光子晶体是由两种或两种以卜不同介电函数的材料周期性排列组成的一种人工晶体.由于介电甬数的周期性分布对入射光的调制作用,使得特定频率区域的人射光在光子晶体中传播时的群速度方向和相速度方向相反,因而使得光子晶体平板表现出负折射特性.系统研究了介质柱的形状对二维正方品格光子品体近场成像特性的影响.通过对分别由正方形、三角形、椭网形、长方形等形状介质柱组成的二维正方品格光子晶体平板近场成像特性的理论分析,发现当介质柱形状的对称性降低到一定程度后可以实现光子晶体近场成像的纵向平移.进一步通过对相应等频率曲线形状的分析,明确了光子晶体近场成像是由于自准直效应和负折射效应的共同作用形成的. 相似文献
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Molecular hydrogen storage at room temperature in Al-doped bulk graphite with wider layer distances was studied using density functional theory calculation. Hydrogen storage capacity of 3.48 wt% or volume density of 51 kg/m3 was predicted at T=300 K and P=0.1 GPa with adsorption energy Eb=?0.264 eV/H2. This is close to the target of volume density 62 kg/m3 and satisfies the requirement of immobilization hydrogen with binding strength of 0.2–0.7 eV/H2 at ambient temperature and modest pressure for commercial applications specified by the U.S. Department of Energy. 相似文献