1987年9月23日日环食所产生的大气内重力波

在日食期间,月影以超声速移过地球大气而使局部大气冷却。Chimonas和Hines认为大气冷却的结果产生激波,诱发大气重力波。这时在电离层中可检测到TID而在地面上可检测到大气压力变化。虽然在电离层中这种重力波信号很弱,但仍可检测到。地面压力变化发生在日食附近地区,甚至离主食带相当远的地方也可以测到。本文报告了在中国首次直接观测日环食引起地面压力波的检测结果。1987年9月23日日环食期间,位于环食带的乌鲁木齐,太原,徐州,苏州及位于偏食带的北京和贵阳共六个次声观测站用电容式微气压计在我国首次探测到日环食产生的声重力波,其周期为10—60min,振幅为7—20Pa(峰-峰值)。动态谱分析的结果表明,各地的重力波周期都有连续的谱分布,其主周期为40min。此外,各地记录到出现时间不同而周期更长的波,对这些结果本文作了初步计论。     

Synthesis,Characterization,and Reactivity of Metalla-Chalcogenirenium Compounds

Main observation and conclusion Chalcogenirenium cations,featuring an unsaturated three-membered organic ring,are limited but known to be synthesizable from alk...     

基于几何区域分解的三维输运问题并行迭代算法

对三维直角坐标下的输运隐式差分方程,研究了基于几何区域分解的并行迭代算法,给出了串、并行迭代误差估计.并对相关数值结果进行了分析、比较.     

Synthesis of Poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole]and Poly(2,5-benzimidazole)by Microwave Irradiation

A rapid way assisted by microwave irradiation was proposed to synthesize poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole](PBI) and poly(2,5-benzimidazole)(ab-PBI).Synthesis of PBI in polyphosphoric acid is conducted for 20 h or even more.Under microwave irradiation,the polycondensations could be completed in polyphosphoric acid within 3 h from 3,3'-diaminobenzidine tetrahydrochloride(DAB·4HCl·2H2O) and isophthalic acid for PBI,and from 3,4-diaminobenzoic acids(DABA) for ab-PBI,respectively.The conditions for t...     

Synthesis and Anti-Hepatocarcinoma Effect of Amino Acid Derivatives of Pyxinol and Ocotillol

Aiming at seeking an effective anti-hepatocarcinoma drug with low toxicity, a total of 24 amino acid derivatives (20 new along with 4 known derivatives) of two active ocotillol-type sapogenins (pyxinol and ocotillol) were synthesized. Both in vitro and in vivo anti-hepatocarcinoma effects of derivatives were evaluated. At first, the HepG2 human cancer cell was employed to evaluate the anti-cancer activity. Most of the derivatives showed obvious enhanced activity compared with pyxinol or ocotillol. Among them, compound 2e displayed the most excellent activity with an IC₅₀ value of 11.26 ± 0.43 µM. Next, H22 hepatoma-bearing mice were used to further evaluate the anti-liver cancer activity of compound 2e. It was revealed that the growth of H22 transplanted tumor was significantly inhibited when treated with compound 2e or compound 2e combined with cyclophosphamide (CTX) (p < 0.05, p < 0.01), and the inhibition rates of tumor growth were 35.32% and 55.30%, respectively. More importantly, compound 2e caused limited damage to liver and kidney in contrast with CTX causing significant toxicity. Finally, the latent mechanism of compound 2e was explored by serum and liver metabolomics based on ultra-performance liquid chromatography quadrupole time-of-flight mass spectrometry (UPLC-QTOF-MS) technology. A total of 21 potential metabolites involved in 8 pathways were identified. These results suggest that compound 2e is a promising agent for anti-hepato-carcinoma, and that it also could be used in combination with CTX to increase efficiency and to reduce toxicity.     

Surface modification boosts exciton extraction in confined layered structure for selective oxidation reaction

Science China Chemistry - Extracting photogenerated species from bulk to surface is an essential process for gaining efficient semiconductor-based photocatalysis. However, compared with charged...     

Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point

Herein, a new congruently melting mixed-anion compound Cs₄B₄O₃F₁₀ has been characterized as the first fluorooxoborate with [BF₄] involving heteroanionic units. Compound Cs₄B₄O₃F₁₀ possesses two highly fluorinated anionic clusters and therefore its formula can be expressed as Cs₃(B₃O₃F₆) ⋅ Cs(BF₄). The influence of [BF₄] units on micro-symmetry and structural evolution was discussed based on the parent compound. More importantly, Cs₄B₄O₃F₁₀ shows the lowest melting point among all the available borates and thus sets a new record for such system. This work is of great significance to enrich and tailor the structure of borates using perfluorinated [BF₄] units.     

电场极化调控聚(3-己基噻吩)薄膜润湿性

本文首次采用电场极化技术精确控制共轭聚合物P₃HT薄膜表面的润湿性,通过调节极化条件,成功实现了对P₃HT薄膜表面润湿性的精确控制,薄膜表面水接触角可以实现从疏水性到亲水性的转变.通过光谱学、形貌学及接触角等表征手段,详细研究了电场极化作用下共轭聚合物分子取向聚集形态及作用机理.该工作不但扩展了共轭聚合物薄膜材料的应用范围,也为分子形态学的研究奠定了基础.     

Non-Covalent Dimer as Donor Chromophore for Constructing Artificial Light-Harvesting System in Water

Dynamic emissive materials in aqueous media have received much attention owing to their ease of preparation, tunable luminescence and environmental friendliness. However, hydrophobic fluorophores usually suffer from aggregation-caused quenching in water. In this work, we constructed an artificial light-harvesting system by using a non-covalent aggregation-induced emission dimer as antenna and energy donor. The dimer is quadruple hydrogen bonded from a ureidopyrimidinone derivative (M) containing a tetraphenylethylene group. The dispersed nano-assemblies based on the dimer in aqueous media were fabricated with the help of surfactant. By loading a hydrophobic acceptor molecule DBT into the nano-assemblies, man-made light-harvesting nanoparticles were fabricated, showing considerable energy transfer efficiency and a relatively high antenna effect. Additionally, the fluorescence color of the system can be gradually tuned by varying the content of the acceptors. This study provides a general way for the construction of an aqueous light-harvesting system based on a supramolecular dimer, which is important for potential application in luminescent materials.     

含有部分脱胶的浅埋圆衬砌对SH波的散射

采用复变函数法研究了含有部分脱胶的浅埋圆形衬砌对SH波的散射问题.首先,将所研究的区域分成两个域,在圆形衬砌中构造一个满足脱胶部分应力自由的散射波函数,将其展开为含有一个待定系数的Fourier级数;而在介质半空间中应满足脱胶部分应力自由,公共边界处位移和应力连续的边界条件.然后,在"公共边界"上实施"契合",与此同时,可构造出脱胶结构,进而得到求解该同题的无穷代数方程组.最后,针对目前工程上应用较广的两种典型浅埋衬砌进行算例分析,给出了地表位移的数值结果,并讨论了入射波参数、脱胶位置以及埋深对地表位移的影响结果.