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991.
Omar El Tall Nicole Jaffrezic‐Renault Monique Sigaud Olivier Vittori 《Electroanalysis》2007,19(11):1152-1159
Boron‐doped Diamond (BDD) electrode has become one of the important tools for heavy metal detection. By studying some analytical parameters of DPASV method, like deposition time and potential in different electrolyte concentrations (acetate buffer), the conditions for detecting very low metal ion levels (Zn, Cd, Pb, and Cu) could be chosen. Diluted electrolyte (0.01 M buffer) was one of the factors favoring low detection and quantification limits, but its quantification range is short in comparison to more concentrated media. For ?1.7 V deposition potential, the detection of single metal at ppb levels was reached in 60 s deposition time. Understanding different metal‐metal interactions shows the limits to the simultaneous determination of heavy metals at BDD. Quantification was possible for the simultaneous determination of Zn, Cd and Pb despite the overlapping of Zn and Cd peaks. The performance of the BDD was compared with that of another C‐based solid electrode: the glassy carbon electrode (without mercury plating). A lower base line current, wider potential range, higher sensitivity (3 to 5 times higher than GC) and longevity of the material were noticed for the BDD. 相似文献
992.
Guo Hua GAO Jin Bao GAO Wen Juan ZHOU Liang LU Ming Yuan HE 《中国化学快报》2006,17(10):1293-1296
Since much more attention has been paid to the sustainable development, many researchers try to improve conventional chemical process and find new and more, environmentally friendly routes1. Aqueous-phase reactions are of interest as environ- mentally ben… 相似文献
993.
Based on the classifications of the four nucleic acid bases, we introduce a new 2-D method of DNA representation: TB-curve, which avoids loss of information accompanying alternative 2-D representation in which the curve standing for DNA overlaps and intersects itself. The method is illustrated on the coding sequence of the first exon of human beta-globin gene. 相似文献
994.
Xiongyu Wu 《Tetrahedron letters》2005,46(9):1501-1504
A fast and efficient microwave promoted one-pot method for deoxygenation of heterocyclic halo-benzyl alcohols has been developed. The method does not cause dehalogenation of the substrates and provides the deoxygenated products in high yield after only 30 min. 相似文献
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997.
大肠杆菌有限生长的微量热及非线性动力学研究 总被引:2,自引:0,他引:2
The finite growth of Escherichia coli was studied by using a LKB 2277 BioActivity Mollitor. We found that the finite growth is a nonliear dynamic process. The nonlinear dynamic behaviour in the finite growth process and the nonlinear dynamic models describing the process were discovered and established. The curve of logistic map corresponding to the finite growth thermogram of Escherichia coli was obtained and the nonlinear dynamic parameters were calculated by means of a computer. Moreover, we also discussed the nonlinear dynamic characters of Escherichia colt in its finite growth process. 相似文献
998.
ResearchonReactivitiesofMoCluster.ASelectiveSubstitutionReactionoftheBridging(dtp)LigandandStructureofTetranuclearMolybdenumC... 相似文献
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