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排序方式: 共有159条查询结果,搜索用时 15 毫秒
61.
Cagdas Gonen Mine Gungormusler Nuri Azbar 《Applied biochemistry and biotechnology》2012,168(8):2136-2147
In this study, pumice stone (PS), which is a vastly available material in Turkey, was evaluated as an alternative immobilization material in comparison to other commercially available immobilization materials such as glass beads and polyurethane foam. All immobilized bioreactors resulted in much better 1,3-propanediol production from waste glycerol in comparison to the suspended cell culture bioreactor. It was also demonstrated that the locally available PS material is as good as the commercially available immobilization material. The maximum volumetric productivity (8.5?g?L?1?h?1) was obtained by the PS material, which is 220?% higher than the suspended cell system. Furthermore, the immobilized bioreactor system was much more robust against cell washout even at very low hydraulic retention time values. 相似文献
62.
Jan Perlich Mine Memesa Alexander Diethert Ezzeldin Metwalli Weinan Wang Stephan V. Roth Jochen S. Gutmann Peter Müller-Buschbaum 《Colloid and polymer science》2012,290(2):119-126
The fabrication of a functional multilayer system with a gradually hierarchical order formed by individual titania thin films
of different porosity is investigated. The porous or sponge-like nanostructures are fabricated using a diblock copolymer assisted
sol–gel process. The successive spin-coating of the sol–gel solution onto the silicon substrate deposits a thin polymer nanocomposite
film which is transformed to purely anatase titania nanostructures via calcination. In total, this procedure is repeated layer
by layer for three times. This layer-by-layer approach is monitored with grazing incidence small-angle X-ray scattering (GISAXS)
after each fabrication step. The GISAXS investigation is complemented in real space with a scanning electron microscopy characterization
of the respective preparation stages. From the characterization, a porous titania multilayer system with gradually structured
levels is clearly identified. 相似文献
63.
Erol Yldrm Mine Yurtsever Burcu Kenarl A. Levent Demirel 《Macromolecular theory and simulations》2011,20(5):340-349
The microphase‐separated morphologies of p‐phenylene oligomers with POx, PCL, PS, and PEO side chains are studied using DPD simulations. It is shown that the microphase‐separated morphologies depend significantly on the degree of chemical incompatibility between the components as indicated by the Flory‐Huggins interaction parameters. The good agreement of the microphase separated morphologies as simulated by DPD with the experimentally determined thin film morphologies suggests that DPD can produce convincing morphological information at the nanoscale. The results show that grafting of polymeric side chains can be an important tool to control the morphology of polymers with a rigid backbone.
64.
In this paper, we find bounds on the distribution of the maximum loss of fractional Brownian motion with and derive estimates on its tail probability. Asymptotically, the tail of the distribution of maximum loss over behaves like the tail of the marginal distribution at time . 相似文献
65.
The phase conversion of amorphous solid water (ASW) to crystalline ice (CI) has been investigated in the very thin (∼10 monolayers) film regime on a Ru(0 0 1) surface. We analyze the converted CI fraction with the Avrami model, and recognize that one-dimensional CI growth occurs, which can be contrasted to the three-dimensional CI growth generally established in the thick (≥50 monolayers) film regime. We evaluate activation energy for the ASW crystallization to be about 1.0 eV. We suggest that the ASW crystallization is not influenced by the substrate even near the substrate-ice interface. 相似文献
66.
We study the dynamics of Bose-Einstein condensates flowing in optical lattices on the basis of quantum field theory. For such a system, a Bose-Einstein condensate shows an unstable behavior which is called the dynamical instability. The unstable system is characterized by the appearance of modes with complex eigenvalues. Expanding the field operator in terms of excitation modes including complex ones, we attempt to diagonalize the unperturbative Hamiltonian and to find its eigenstates. It turns out that although the unperturbed Hamiltonian is not diagonalizable in the conventional bosonic representation the appropriate choice of physical states leads to a consistent formulation. Then we analyze the dynamics of the system in the regime of the linear response theory. Its numerical results are consistent with those given by the discrete nonlinear Schrödinger equation. 相似文献
67.
Eiichi Mine Mitsuaki Hirose Masaki Kubo Yoshio Kobayashi Daisuke Nagao Mikio Konno 《Journal of Sol-Gel Science and Technology》2006,38(1):91-95
A previously proposed method for preparing monodispersed titania particles was extended to preparation of titania-coated silica spherical particles. The core silica particles with an average size of 264 nm were prepared with Stöber method. The titania-coating was performed in ethanol/acetonitrile solvent in the presence of silica particles by a sol-gel method with the use of titanium tetraisopropoxide (TTIP) and methylamine (MA) catalyst. Average size of the silica-titania particles decreased from 457 to 292 nm with an increase in concentration of silica particles. Coefficient of variation for the particle size was less than 5%. Colloidal crystals could be fabricated with a dip-coating technique and a sedimentation process, respectively. Measurements of reflectance revealed peaks based on the Bragg diffraction. Those peaks red-shifted with an increase in titania shell thickness because of a high refractive index of titania. Annealing at high temperature transformed crystal structure of titania shell from amorphous to anatase (500°C) and rutile (1000°C), which led to red-shift of reflection peak because of an increase in refractive index of titania due to the crystallization. 相似文献
68.
69.
Mine Uygun-Sarıbay Ece Ergun Turhan Köseoğlu 《Journal of Radioanalytical and Nuclear Chemistry》2014,301(2):597-605
The aim of this study was to monitor the effects of gamma irradiation and storage on the content of lutein and zeaxanthin in egg yolk samples. Liquid, frozen and dried egg samples were subjected to gamma irradiation doses of 0, 1, 2 and 3 kGy followed by storage of liquid samples at +4 ± 1 °C for 21 days, frozen samples at ?18 ± 1 °C and dried samples at room temperature for 1 year. The xanthophyll concentrations were determined by high-performance liquid chromatography-diode array detector. It was observed that concentrations of both lutein and zeaxanthin were decreased significantly (P < 0.05) after irradiation and during storage. The mechanism for radiation-induced degradation was proposed as radical formation which initiate chain reactions. It was suggested that during storage active radical species and oxygen caused the degradation. 相似文献
70.
Gu S Kondo T Mine E Nagao D Kobayashi Y Konno M 《Journal of colloid and interface science》2004,279(1):281-283
Jingle bell-shaped hollow spheres were fabricated starting from multilayered particles composed of a silica core, a polystyrene inner shell, and a titania outer shell. Composite particles of silica core-polystyrene shell, synthesized by coating a 339-nm-sized silica core with a polystyrene shell of thickness 238 nm in emulsion polymerization, were used as core particles for a succeeding titania-coating. A sol-gel method was employed to form the titania outer shell with a thickness of 37 nm. The inner polystyrene shell in the multilayered particles was removed by immersing them in tetrahydrofuran. These successive procedures could produce jingle bell-shaped hollow spheres that contained a silica core in the titania shell. 相似文献