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991.
Computational design of tetrazolone‐based high‐energy density energetic materials: Property prediction and decomposition mechanism 下载免费PDF全文
The density functional theory methods are used to design a series of new highly energetic tetrazolone‐based molecules by the combination of the linked tetrazolone framework and versatile substitutes. The molecular and electronic structures, physicochemical, and energetic properties were analyzed and predicted. The decomposition mechanisms were computationally simulated, and 3 potential decomposition channels were proposed. These newly designed tetrazolone‐based compounds show high densities (up to 2.08 g/cm3) and highly positive heats of formation (407.0‐1377.9 kJ/mol) due to all right content of nitrogen and oxygen. Most of them exhibit good detonation velocity (8.31‐9.62 km/s) and detonation pressure (32.40‐43.86 GPa), and some are comparative to excellent explosive CL‐20. Results show that compounds 6 , 10 , 11 , 12 , 15 , 16 , 17 , 22 , 23 , and 24 own superior detonation performance than widely used explosive HMX and may be promising candidates of green high‐performance energetic materials. 相似文献
992.
Recently, Zhao-Hui Wei et al. (Int. J. Theor. Phys. 55, 4687, 2016) proposed an improved quantum teleportation scheme for one three-qubit unknown state with a four-qubit quantum channel based on the original one proposed by Binayak S. Choudhury and Arpan Dhara (Int. J. Theor. Phys. 55, 3393, 2016). According to their schemes, the three-qubit entangled state could be teleported with one four-qubit cluster state and five-qubit joint measurements or four-qubit joint measurements. In this paper, we present an improved protocol only with single-qubit measurements and the same four-qubit quantum channel, lessening the difficulty and intensity of necessary operations. 相似文献
993.
We investigate unidirectionally emitting quantum cascade microcavity lasers with semicircle-patterned top contacts. We employ novel patterned top contacts while fabricating notched ellipse-shaped cavity lasers. We study experimentally the microcavity-structure-based quantum cascade (QC) laser material with a long infrared wavelength of ~10 μm. Then we characterize microcavity lasers with patterned contacts and compare them with nonpatterned ones and observe a lower operating injection threshold current as a consequence of this relatively straightforward technique, with the unidirectional emission feature being kept. We obtain a maximum light output peak power of 16 mW with unidirectional emission at a far-field divergence angle of ~7° at a full width of half maximum, while the patterned device shows low threshold even in the microcavity laser with a size of 150 μm. Furthermore, we also carry out a reliability test of the QC microcavity lasers with semicircle-patterned top contacts, and the testing results show no sudden failure or severe light-output-power drop during an operating time of thousand hours. 相似文献
994.
Effective measurement of the reflective or transparent surface of an object has always been a disadvantage in laser scanning modeling. We propose a fast and complete three-dimensional (3D) reconstruction method for small static objects using laser scanning and the structure from motion (SFM) algorithm. Meanwhile, a complete reconstruction workflow is designed and a multi-angle 3d reconstruction system is set up. To generate the complete point cloud model of the object, the SFM algorithm is used to reconstruct the surface part of the object, the data for which cannot be obtained by the laser measuring instrument. The experimental results show that this method not only improves the speed, accuracy, integrity, and visual effect of 3D reconstruction of small objects, but also extends the scope of 3D reconstruction of laser measurement. 相似文献
995.
Room-temperature anomalous Hall effect and magnetroresistance in (Ga, Co)-codoped ZnO diluted magnetic semiconductor films 下载免费PDF全文
This paper reports that the(Ga,Co)-codoped ZnO thin films have been grown by inductively coupled plasma enhanced physical vapour deposition.Room-temperature ferromagnetism is observed for the as-grown thin films.The x-ray absorption fine structure characterization reveals that Co 2+ and Ga 3+ ions substitute for Zn 2+ ions in the ZnO lattice and exclude the possibility of extrinsic ferromagnetism origin.The ferromagnetic(Ga,Co)-codoped ZnO thin films exhibit carrier concentration dependent anomalous Hall effect and positive magnetoresistance at room temperature.The mechanism of anomalous Hall effect and magneto-transport in ferromagnetic ZnO-based diluted magnetic semiconductors is discussed. 相似文献
996.
997.
In this paper, a periodic stochastic human immunodeficiency virus (HIV) model with distributed delay and cytotoxic T lymphocytes (CTL) immune response is investigated. First, by It 's formula, we show that the solution with any positive initial value is global and positive. Then, by the stochastic comparison theorem, we obtain the sufficient conditions guaranteeing the existence and global attractivity of infection-free periodic solution. Furthermore, we discuss the existence of the infective periodic solution by Has'minskii theory. Finally, numerical examples are given to illustrate the results. 相似文献
998.
基于定量结构-活性相关性(QSAR)原理,研究了49种有机化合物结构与其蝌蚪麻醉活性的内在定量关系。首先应用分子电性作用矢量(molecular electronegativity interaction vector,MEIV)表征49种有机化合物的结构,再采用多元线性回归(MLR)方法建立了相应的QSAR预测模型,最后对所建模型分别进行了内部验证和外部验证。所建模型的复相关系数(Rcum)、留一法(LOO)交互校验复相关系数(RCV)和外部样本校验复相关系数(Qext)分别为0.9415、0.9127和0.9253,证明该模型均具有较高的稳定性和预测能力。 相似文献
999.
For controllable generation of an isolated attosecond relativistic electron bunch [relativistic electron mirror (REM)] with nearly solid-state density, we propose using a solid nanofilm illuminated normally by an ultraintense femtosecond laser pulse having a sharp rising edge. With two-dimensional (2D) particle-in-cell (PIC) simulations, we show that, in spite of Coulomb forces, all of the electrons in the laser spot can be accelerated synchronously, and the REM keeps its surface charge density during evolution. We also developed a self-consistent 1D theory, which takes into account Coulomb forces, radiation of the electrons, and laser amplitude depletion. This theory allows us to predict the REM parameters and shows a good agreement with the 2D PIC simulations. 相似文献
1000.
In this report, we demonstrate the efficient generation of collinearly propagating photon pairs in a bulk periodically poled potassium titanyl phosphate pumped by a cw laser. The detected coincidence counts are more than 7400/s with 3.58 mW pump power in a Hanbury-Brown-Twiss-type experiment. The estimated photon pair production rate is about 0.73 MHz/mW. This is very promising for some applications, such as quantum key distribution, proof of the Bell-inequality, preparation of single photon states in broadband wave packets, Franson-type interference and so on. 相似文献