全文获取类型
收费全文 | 25832篇 |
免费 | 3993篇 |
国内免费 | 3726篇 |
专业分类
化学 | 20028篇 |
晶体学 | 422篇 |
力学 | 1234篇 |
综合类 | 289篇 |
数学 | 3134篇 |
物理学 | 8444篇 |
出版年
2024年 | 55篇 |
2023年 | 449篇 |
2022年 | 663篇 |
2021年 | 827篇 |
2020年 | 1004篇 |
2019年 | 1042篇 |
2018年 | 803篇 |
2017年 | 764篇 |
2016年 | 1163篇 |
2015年 | 1218篇 |
2014年 | 1538篇 |
2013年 | 1955篇 |
2012年 | 2292篇 |
2011年 | 2370篇 |
2010年 | 1772篇 |
2009年 | 1607篇 |
2008年 | 1867篇 |
2007年 | 1654篇 |
2006年 | 1549篇 |
2005年 | 1334篇 |
2004年 | 1029篇 |
2003年 | 880篇 |
2002年 | 973篇 |
2001年 | 765篇 |
2000年 | 551篇 |
1999年 | 481篇 |
1998年 | 415篇 |
1997年 | 332篇 |
1996年 | 349篇 |
1995年 | 285篇 |
1994年 | 258篇 |
1993年 | 230篇 |
1992年 | 183篇 |
1991年 | 190篇 |
1990年 | 120篇 |
1989年 | 131篇 |
1988年 | 79篇 |
1987年 | 67篇 |
1986年 | 50篇 |
1985年 | 66篇 |
1984年 | 56篇 |
1983年 | 31篇 |
1982年 | 25篇 |
1981年 | 19篇 |
1980年 | 18篇 |
1979年 | 6篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
研究了不同比例的PVK与齐聚PPV衍生物DBVP掺杂体系的能量转移和发光特性.通过对PVK,DBVP及PVK:DBVP掺杂体系的UV-vis,PL和PLE光谱的研究,分析了PVK与DBVP之间的能量转移过程.利用PVK在体系中类似于溶剂的分散作用,制备了结构为ITO/PEDOT/PVK:DBVP/LiF/Al的电致发光器件,研究了掺杂体系的电致发光性能.结果表明,在掺杂体系的光致发光和电致发光中,PVK的发射被有效地抑制,PVK与DBVP之间发生了非常有效的能量转移,通过调节PVK与DBVP的比例,可以获得蓝色和绿色发光,同时可以改善器件的发光性能,当PVK与DBVP的重量比为1∶2时,器件的绿色发光效率达到1·06cd/A,此时发光亮度为52cd/m2. 相似文献
42.
We reveal that for a realistic system, interference effects are obtained such as the suppression of central line and inner sidebands and the narrowing of the outer fluorescence sidebands. For this purpose, we consider a spontaneous decay from an excited state to a metastable state when the excited and metastable states are resonantly coupled to an auxiliary metastable state by a laser field and a microwave field, respectively. The fluorescence spectrum evolves from a five-peaked structure into a doublet of ultrasharp lines as the ratio of the laser field Rabi frequency to the microwave Rabi frequency is decreased. The physical origin is presented in terms of dressed states. 相似文献
43.
针对刚性约束层、柔性约束层以及液体约束层,从激光诱导冲击波阵面状态、汽化物(包括气体和等离子体)扩散以及冲击波的反射进行分析,发现对于脉宽小于冲击波通过汽化物层的时间间隔的短脉冲激光,约束层并不能直接提高冲击波的冲量,而对于脉宽大于冲击波通过汽化层时间间隔的激光,其增强冲击效果是通过约束汽化物的扩散,提高压力幅值和由于冲击波在约束层与工件表面的多次反射而延长对工件的作用时间来实现的.刚性约束层能最大地增加冲击冲量,而柔性约束层和液体约束层的主要优点是其形状可与非平面形工件表面符合.
关键词:
激光
约束层
扩散
反射波 相似文献
44.
用经验赝势方法计算了体ZnSe以及ZnSe/GaAs单异质结系统中ZnSe外延层г、X、L等特殊对称点导带底能量随压力的变化。结果表明,同Si、Ge、GaAs等半导体材料不同,ZnSe的X点导带底具有正的压力系数,但比г点的压力系数小,这是ZnSe材料以及ZnSe基异质结构材料发生直接禁带向间接禁带的转变时所需转变压力较大的根本原因。研究了ZnSe/GaAs异质结构中晶格失配造成的应变对外延层г、X、L对称点压力系数的影响,表明这种晶格失配造成的应变可以极大地减小ZnSe外延层材料由直接禁带向间接禁带的转变压力。 相似文献
45.
Wei Shi Yujie J. Ding Changshui Fang Qiwei Pan Qingtian Gu 《Optics and Lasers in Engineering》2002,38(6):361-371
Mode-matching and effective index methods are used to analyze single-mode operation of optical rib polymer waveguides. Their single-mode waveguiding conditions are determined. Single-mode rib waveguides fabricated from guest–host polyetherketone are presented. The estimated propagation loss of straight rib-waveguides is 0.7 dB/cm at 1.55 μm. Furthermore, by using the mode field-transfer matrix method, 2×2 and 4×4 polymer Mach–Zehnder interference switch operating at 1.55 μm wavelength has been designed based on optical multi-mode interference. 相似文献
46.
AAS测定纸巾中的铅和镉 总被引:1,自引:0,他引:1
本文采用原子吸收光谱法测定纸巾中铅、镉的含量。结果表明,不同纸巾中的污染元素铅、镉的含量不同。同时还对一种纸巾的铅、镉元素进行了回收实验,回收率在92%-104%之间。 相似文献
47.
一类积分不等式的推广 总被引:1,自引:0,他引:1
对一些基本的积分不等式进行了推广,给出了含有n个无关变元的更广泛的非线性积分不等式.利用所得的不等式讨论了某些非线性积分方程解的有界性. 相似文献
48.
The Iyengar Type Inequalities with Exact Estimations and the Chebyshev Central Algorithms of Integrals 总被引:3,自引:0,他引:3
Xing Hua WANG Shi Jun YANG 《数学学报(英文版)》2005,21(6):1361-1376
In this paper, both low order and high order extensions of the Iyengar type inequality are obtained. Such extensions are the best possible in the same sense as that of the Iyengar inequality. hzrthermore, the Chebyshev central algorithms of integrals for some function classes and some related problems are also considered and investigated. 相似文献
49.
A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepared and characterized using the techniques of FTIR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectrometry, X-ray photoelectron spectroscopy (XPS), ICP atomic emission spectroscopy, and EDX. The results of ICP atomic emission spectroscopy, EDX, and TGA indicated that the prepared GdHCF sample had a stoichiometry of NaGdFe(CN)6·12H2O (when GdHCF was prepared in NaCl solution). The FTIR spectrum of GdHCF showed that there were two types of water molecules in the structure of GdHCF: one was the interstitial water (5 H2O), which resulted from the association of water due to H-bonding, and the other was water coordinated with Gd (7 H2O). The results obtained using XPS showed that the oxidation state of Fe and Gd in the GdHCF sample was +2 and +3, respectively. GdHCF was immobilized on the surface of spectroscopically pure graphite (SG) electrode forming the GdHCF/SG electrode, and the solid-state electrochemistry of the resultant electrode was studied using cyclic voltammetry. The cyclic voltammetric results indicated that the GdHCF/SG electrode exhibited a pair of well-defined and stable redox peaks with the formal potential of E0′=(197±3) mV. The effects of the concentration of the supporting electrolyte on the electrochemical characteristics of GdHCF were studied, and the results showed that the value of E0′ increased linearly with the activity of the cationic ion of the supporting electrolyte (lgaNa+), with a slope of 54.1 mV, which may become a novel method for determining the activity of Na+ in solution. Further experimental results indicated that GdHCF had electrocatalytic activities toward the oxidation of dopamine (DA) and ascorbic acid (AA), and the electrocatalytic current increased linearly with the concentration of DA (or AA) in the range of 1.0–10.0 mmol·L?1 (for DA) or 0.5–20.0 mmol·L?1 (for AA). 相似文献
50.
This paper proposes a new two-stage two-phase VPP charge pump configured in such a manner that the body effect and the threshold voltage loss are eliminated. The newly proposed circuit is fabricated using 0.18 μm triple-well CMOS process and the measurement result shows that the VPP level tracks 3VDD when VDD is above the threshold voltage. 相似文献