Positron annihilation in polycrystalline metals

The empirical relation θ _p ⁶ /I _p=aK (where θ _p is the limiting angle of the parabolic component in the angular distributions of annihilation photons in metals, I _p is the integrated contribution of this component, K=1, 2, 3, ... is an integer, and a is a constant independent of the type of metal) observed earlier has been tested on magnesium, aluminum, copper, zinc, lead, and bismuth samples. The validity of this relation has been substantiated. The value of the dimensionless constant a has been determined and was found to coincide within experimental error with the result obtained in previous measurements. It is shown that the value of K for the same metal but for different samples may be different. It is conjectured that this may be due to different defect concentrations in samples. Fiz. Tverd. Tela (St. Petersburg) 40, 600–602 (April 1998)     

Experimental Determination of Four-Time Stimulated Echoes in Liquids, Colloidal Suspensions, and Crystals

Four-time stimulated echo experiments have been used to monitor the temporal evolution of the reorientation rates of deuterated molecules or colloidal suspensions. We present extended phase cycles for this seven-pulse experiment. In order to test its performance three vastly different materials are chosen. These include a crystal in which the molecules carry out well-defined 180° flips and a supercooled liquid characterized by a distribution of jump angles centered around 10°. As an example for rotational diffusion, data on a concentrated suspension of polystyrene spheres in a viscous medium are presented.     

Selective quenching of tryptophanyl fluorescence in bovine serum albumin by the iodide ion

Modified Stern-Volmer equation is obeyed by bovine serum albumin (BSA)-iodide system showing selective quenching of tryptophanyl fluorescence of BSA. The fraction of accessible protein fluorescence is 0.56 and the effective Stern-Volmer constant is 290 M^-1 at pH 7.4 in 0.005 M phosphate buffer at 25°C. Collisional quenching is operative both in the BSA -I⁻¹ system and the model system, tryptophan-I⁻¹. It is supported by the observed relationship between the ratio of quenching rate constants (k _q ) and diffusion coefficients and alsok _q with bulk viscosity.     

The anomalous 3-boson couplings as an implication of the Higgs sector

We discuss the possible new electroweak interactions which may be generated by the Higgs sector at the scale of theZ mass. For this purpose, we give a set ofSU(2)×U(1) gauge invariant operators constructed in terms ofW, Z, γ and Higgs fields which in the unitary gauge describe all possible γWW andZWW anomalous couplings. The dimension of these operators varies from 6 to 12. This fact allows us to consider various scenaria for the manifestations of the New Physics. We conclude that the underlying dynamics induced by the Higgs sector can be tested through a model-independent amplitude analysis of gauge boson pair production at LEP2 and future colliders.     

Effects of strong coupling in homonuclear correlation spectroscopy

A calculation of the complex signals in homonuclear correlation spectra (HOMCOR) of strongly coupled ABX three-spin systems is presented. It is shown that the presence of strong coupling causes the behavior of the cross-peaks to differ significantly from that found in the case of weak coupling. Two classes of connectivity patterns, namely weak and strong connectivity pairs of transitions are distinguished. Closed expressions for the real amplitudes are given. The dependence of the real amplitude on the flip angle of the mixing pulse and on the coupling strength is analyzed.     

EPMA of interfaces applied to the solid oxide fuel cell

Chemical interactions at the phase boundaries of materials applied for the solid oxide fuel cell (SOFC) have been studied by EPMA. The chemical reactivity at the interface of La_y-xSr_xMnO₃/ZrO₂-Y₂O₃ is dependent on the stoichiometry (y) and the Sr content (x) of the perovskite. Typical reaction products (zirconates) and a diffusion zone in the ZrO₂–Y₂O₃ have been observed. The extension of cation release (Mn) is related to the increasing chemical activity of Mn oxide in the perovskite by the Sr substitution for La. The wettability of the metal/oxide interface in the anode cermet (Ni/ZrO₂–Y₂O₃) has been found to be influenced by chemical reactions resulting from the applied reducing atmosphere with high carbon activity. The disintegration of ZrO₂–Y₂O₃ in contact with molten Ni or Ni-Ti and Ni-Cr alloys leads to the redeposition of Y₂O₃-enriched oxides and also to Zr-rich intermetallic compounds and eutectics.     

Observation of ionic thermocurrents in zirconia-based solid electrolytes

In ionic conductors, long range-migrating charges are a main cause of polarization processes. This has complicated, up to date, the study of ionic thermocurrents (ITC) in solid electrolytes. However, the method is appealing, as it probes directly charge-formation phenomena that are important both from a scientific point of view and for applications. This work reports on the observation of ITC in solid electrolytes. Under appropriate experimental conditions, the ITC response of a zirconia sample electroded with platinum is a reproducible one, thus opening the way to a new characterization method that may complement other well established methods, such as Impedance Spectroscopy and a number of electrochemical techniques. The general trends of the response, which is composed of two well resolved ITC peaks, is discussed. One of them, taking place at higher temperatures, conforms to the standard shape of a first order kinetics depolarization process. Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995     

MO analysis of macroscopic supercurrent flow in MgB 2

We present results from an extended magneto-optical (MO) analysis of two samples cut from high-density pellets of MgB₂. The first sample was studied in order to show that no matter how large the sample is and despite the bulk granularity, the material enters into a critical state in a crystal-like fashion. The second sample was chosen for the quantitative analysis. A numerical approach based on an inverted 2D Biot-Savart model was used to calculate the current paths across the homogeneous polycrystalline bulk, as well as in the vicinity and across some morphological defects. Local current densities in the homogeneous part were estimated as a function of the applied magnetic field at different temperatures, in three regimes: below full penetration, at full penetration and above full penetration, respectively. A hypothesis of interpretation of the apparent absence of magnetic granularity inside the polycrystalline microstructure is presented. It is related to a critical state likely reached by a network of strongly coupled Josephson junctions. Received 31 May 2001 and Received in final form 5 December 2001     

Formation on field emitters coated with fullerenes of microformations producing ordered emission images

Field emission projector studies of fullerene coatings deposited on tungsten tip field emitters reveal specific ordered patterns in the form of doublets, quadruplets, rings, disks, and other forms in the emitter images. The ways in which these types of ordered emission patterns arise and their relation to C₆₀ microformations have been established. Possible causes of the emergence of the ordered emission images are analyzed on the basis of published data and experimental results obtained. A modification of the model of field emission from the surface of microformations taking into account internal reflection of the electronic waves from the formation boundaries has been proposed.