Stability and Degradation Mechanisms of Copper-Based Catalysts for Electrochemical CO2 Reduction

To date, copper is the only monometallic catalyst that can electrochemically reduce CO₂ into high value and energy-dense products, such as hydrocarbons and alcohols. In recent years, great efforts have been directed towards understanding how its nanoscale structure affects activity and selectivity for the electrochemical CO₂ reduction reaction (CO₂RR). Furthermore, many attempts have been made to improve these two properties. Nevertheless, to advance towards applied systems, the stability of the catalysts during electrolysis is of great significance. This aspect, however, remains less investigated and discussed across the CO₂RR literature. In this Minireview, the recent progress on understanding the stability of copper-based catalysts is summarized, along with the very few proposed degradation mechanisms. Finally, our perspective on the topic is given.     

A synthesis of N-alkyl and N,N-dialkyl O-ethyl thiocarbamates from diethyl dixanthogenate using different oxidants

Abstract  

A novel synthesis of N-alkyl and N,N-dialkyl O-ethyl thiocarbamates from diethyl dixanthogenate and primary and secondary amines, using three oxidizing systems, has been developed on the laboratory scale, and the method using sodium hypochlorite has been applied on a semi-industrial scale. The effect of the oxidizing agents, sodium hypochlorite, in-situ-generated peracetic acid, and the manganese(II) acetate/oxygen system on product purity and yield was studied. The results obtained by use of these three methods were compared with those obtained by reaction of sodium ethyl xanthogenacetate and amines, and of sodium ethyl xanthate with amines in the presence of sulfated nickel zeolite catalyst. The reaction mechanism of sodium hypochlorite oxidation has been established on the basis of isolation of reaction intermediates and determination of their structure by use of Fourier-transform infrared, ¹H and ¹³C NMR, and mass spectrometric methods. The suggested sodium hypochlorite and manganese(II) acetate/oxygen systems have many advantages in comparison with commercial and catalytically promoted synthetic methods, because they are new ecologically friendly syntheses.     

Regularized trace of the inverse of the dirichlet laplacian

For the eigenvalues $( \lambda_{n}) _{n=1}^{\infty}$ of the Dirichlet Laplacian on a bounded convex domain $\font\open=msbm10 at 10pt\def\C{\hbox{\open C}}\Omega\subset{\C}$ , we find the sum of the series the regularized trace of the inverse of Dirichlet Laplacian. © 2011 Wiley Periodicals, Inc.     

Stability and Degradation Mechanisms of Copper‐Based Catalysts for Electrochemical CO2 Reduction

To date, copper is the only monometallic catalyst that can electrochemically reduce CO₂ into high value and energy‐dense products, such as hydrocarbons and alcohols. In recent years, great efforts have been directed towards understanding how its nanoscale structure affects activity and selectivity for the electrochemical CO₂ reduction reaction (CO₂RR). Furthermore, many attempts have been made to improve these two properties. Nevertheless, to advance towards applied systems, the stability of the catalysts during electrolysis is of great significance. This aspect, however, remains less investigated and discussed across the CO₂RR literature. In this Minireview, the recent progress on understanding the stability of copper‐based catalysts is summarized, along with the very few proposed degradation mechanisms. Finally, our perspective on the topic is given.     

Estimates for the norm of powers of Volterra's operator through its singular values

We prove that for every Volterra operator T the inequality holds, where b is an absolute constant and are its singular values. Received January 26, 2000 / Published online February 5, 2001     

Mobility of high-power solitons in saturable nonlinear photonic lattices

We theoretically study the properties of one-dimensional nonlinear saturable photonic lattices exhibiting multiple mobility windows for stationary solutions. The effective energy barrier decreases to a minimum in those power regions where a new intermediate stationary solution appears. As an application, we investigate the dynamics of high-power Gaussian-like beams finding several regions where the light transport is enhanced.     

Syntheses of N-alkyl, N,N-dialkyl, and N-(4-substituted phenyl) O-ethyl thioncarbamates: a kinetic study

Abstract  

The kinetics of the syntheses of N-alkyl, N,N-dialkyl, and N-(4-substituted phenyl) O-ethyl thioncarbamates from sodium ethyl xanthogenacetate, ten alkylamines, and eight substituted anilines were studied at 25, 30, 35, and 40 °C. The reactions were found to follow second-order kinetics. The kinetic (Arrhenius) parameters, such as the activation energy and the frequency factor, as well as the Eyring parameters, such as the standard entropy, the standard Gibbs energy, and the standard enthalpy of activation, were calculated from the second-order rate constants. The mechanism of the reaction was postulated based on the kinetic studies presented and the optimization of the reaction mechanism using the MOPAC PM6 semi-empirical method.     

On an inequality of Friedrich's type

In this paper the dependence of the constant in the inequality on simply connected bounded domains is found.