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81.
Harward CN Baren RE Parrish ME 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(14):6861-3429
A technique has been developed for the determination of molecular parameters, including infrared absorption line positions, strengths, and nitrogen-broadened half-widths for 1,3-butadiene (C(4)H(6)) and propylene (C(3)H(6)). The parameters for these two molecules are required for quantitation using Tunable Diode Laser Absorption Spectroscopy (TDLAS). These molecules have populations of highly overlapping infrared absorption lines in their room temperature spectra. The technique reported here provides a procedure for estimating the molecular parameters for these overlapping absorption lines from quantitative reference spectra taken with the TDLAS instrument at different pressures and concentrations. The system was developed for the quantitation of gaseous constituents in a single puff of cigarette smoke and this paper will describe the procedure and some of the factors that influence the accuracy of quantitation for 1,3-butadiene, including the approach taken to minimize the adverse effects of the absorption due to propylene in the same spectral region. 相似文献
82.
Baren RE Parrish ME Shafer KH Harward CN Shi Q Nelson DD McManus JB Zahniser MS 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(14):3437-3447
A compact, fast response, infrared spectrometer using four pulsed quantum cascade (QC) lasers has been applied to the analysis of gases in mainstream (MS) and sidestream (SS) cigarette smoke. QC lasers have many advantages over the traditional lead-salt tunable diode lasers, including near room temperature operation with thermoelectric cooling and single mode operation with improved long-term stability. The new instrument uses two 36 m, 0.3 l multiple pass absorption gas cells to obtain a time response of 0.1s for the MS smoke system and 0.4s for the SS smoke system. The concentrations of ammonia, ethylene, nitric oxide, and carbon dioxide for three different reference cigarettes were measured simultaneously in MS and SS smoke. A data rate of 20Hz provides sufficient resolution to determine the concentration profiles during each 2s puff in the MS smoke. Concentration profiles before, during and after the puffs also have been observed for these smoke constituents in SS smoke. Also, simultaneous measurements of CO(2) from a non-dispersive infrared (NDIR) analyzer are obtained for both MS and SS smoke. In addition, during this work, nitrous oxide was detected in both the MS and SS smoke for all reference cigarettes studied. 相似文献
83.
Marilyn Daisy Milton Sarbjot Singh Sokhi Monika Maheshwari Minakshi Asnani 《Tetrahedron letters》2004,45(48):8941-8944
A novel class of multifunctional and multinucleate chalcogen (selenium and tellurium) containing derivatives (1-10) has been developed based on sequential chloride substitution of 2,4,6-trichloro-1,3,5-triazine with chalcogen-bearing amines. The structure of compound 1 has been determined in the solid state by X-ray crystallography. 相似文献
84.
Dynamic nuclear polarization studies of nitroxyl spin probes in agarose gel using Overhauser‐enhanced magnetic resonance imaging
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V. Meenakumari Hideo Utsumi Fuminori Hyodo A. Jawahar A. Milton Franklin Benial 《Magnetic resonance in chemistry : MRC》2017,55(11):1022-1028
Agarose is a tissue‐equivalent material and its imaging characteristics similar to those of real tissues. Hence, the dynamic nuclear polarization studies of 3‐carboxy‐2,2,5,5‐tetramethyl‐pyrrolidine‐1‐oxyl (carboxy‐PROXYL) in agarose gel were carried out. The dynamic nuclear polarization parameters such as spin lattice relaxation time, longitudinal relaxivity, leakage factor, saturation parameter and coupling parameter were estimated for 2 mM carboxy‐PROXYL in phosphate‐buffered saline solution and water/agarose mixture (99 : 1). From these results, the spin probe concentration was optimized as 2 mM, and the reduction in enhancement was observed for carboxy‐PROXYL in water/agarose mixture (99 : 1) compared with phosphate‐buffered saline solution. Phantom imaging was also performed with 2 mM concentration of carboxy‐PROXYL in various concentrations of agarose gel at various radio frequency power levels. The results from the dynamic nuclear polarization measurements agree well with the phantom imaging results. These results pave the way for designing model system for human tissues suited to the biological applications of electron spin resonance/Overhauser‐enhanced magnetic resonance imaging. 相似文献
85.
Michael J. Quast Gary E. Martin Vincent M. Lynch Stanley H. Simonsen John G. Stuart Marvin L. Tedjamulia Raymond N. Castle Milton L. Lee 《Journal of heterocyclic chemistry》1986,23(4):1115-1118
The crystal structure of 9-methylphenanthro[4,3-a]dibenzothiophene, C25H16S, Mr = 348.47, has been determined. Monoclinic, P21/c, a = 11.364(3), b, = 14.257(3), c = 11.575(2)Å, β = 116.26(2)°, V = 1681.9(7)Å3, Z = 4, Dx = 1.38 g/cc, MoKα radiation λ = .71069 Å, F(000) = 728, T = 163K, R = .0458 for 2330 reflections. The structure compares favorably with that of hexahelicene and methylated derivatives. The thiophene moiety increases the helical core radius and decreases the pitch with respect to hexahelicene and its derivatives. 相似文献
86.
87.
Eliete Marçal Guimarães Raso Maria Esperanza Cortes Karina Imaculada Teixeira Milton Batista Franco Nelcy Della Santina Mohallem Ruben Dario Sinisterra 《Journal of inclusion phenomena and macrocyclic chemistry》2010,67(1-2):159-168
The purpose of this study was to prepare and characterize a controlled release system based on porous silica loaded with chlorhexidine (Cx) and its inclusion compounds in β-cyclodextrin (βcd), and to evaluate its antimicrobial activity. Acetate chlorhexidine (CxA), gluconate chlorhexidine (CxG), βcd:chlorhexidine acetate 2:1 (βcd:CxA) and βcd:chlorhexidine gluconate 2:1 (βcd:CxG) were incorporated into porous silica. Drug loading was characterized by FTIR, powder X-ray diffraction, thermal analysis and BET, and was shown to be in an amorphous state and porous matrix. The kinetics release parameter of the drug was established, which showed that the Cx systems release profile followed zero order release until 400 h and Higuchi model release until 750 h, after the burst effect at the first 8 h. Chlorhexidine therapeutic range was reached near first hour for all systems. The chlorhexidine porous silica system was biologically active against Enterococcus faecalis and Candida albicans in vitro. The systems showed an efficient Cx controlled release modulated by the presence of the β-cyclodextrin and by the porous silica matrices, providing effective antimicrobial activity. 相似文献
88.
2-Furoic acid (2FA), an organic third order nonlinear optical single crystal, has been synthesized and grown successfully by slow solvent evaporation technique. The space group and lattice parameters of the grown crystals were obtained by single crystal X-ray diffraction analysis. The presence of the functional groups was confirmed by Fourier Transform Infrared (FTIR) spectroscopy. Optical absorption studies reveal low absorption in the UV and visible regions and the UV cut-off wavelength is found to be at 240 nm. The thermal stability of the material examined by TGA analysis, reveals that the material is thermally stable up to 130 °C. The third order nonlinear optical parameters (nonlinear refractive index, nonlinear absorption coefficient and real and imaginary parts of the third order nonlinear optical susceptibility) were derived by Z-scan technique. This reveals that the crystal has a negative refractive index, which indicates the defocusing nature of the material. 相似文献
89.
K. ParasuramanK. Sakthi Murugesan R. UthrakumarS. Jerome Das B. Milton Boaz 《Physica B: Condensed Matter》2011,406(20):3856-3860
Good quality single crystals of pure and metal ion (Ni2+) doped bis-thiourea zinc chloride (BTZC) possessing excellent nonlinear optical properties have been grown from aqueous solution by the slow solvent evaporation technique. The lattice parameters of the grown crystals are determined by single crystal X-ray analysis. The well defined sharp peaks in the powder X-ray diffraction pattern reveals the crystalline perfection and the EDAX spectrum confirms the presence of dopant in the lattice of the parent crystal. The DRS UV-visible spectral study reveals improved transparency for the doped crystal, ascertaining the inclusion of metal ion in the lattice. The optical band gap of the pure and doped crystals was calculated to be 4.8 and 5.2 eV respectively from the UV transmission spectrum. The vickers hardness test brings forth higher hardness value for Ni2+doped BTZC as compared to pure BTZC crystal. The dielectric measurement exhibits very low dielectric constant and dielectric loss at higher frequencies for both the pure and Ni2+doped BTZC. The existence of second harmonic generation signals in the crystal also has been confirmed by performing the Kurtz powder test. 相似文献
90.
We present detailed thermodynamic and transport measurements on single crystals of the recently discovered binary intermetallic superconductor, SrSn(4). We find this material to be a slightly anisotropic three-dimensional, strongly coupled, possibly multiband, superconductor. Hydrostatic pressure causes a decrease in the superconducting transition temperature at the rate of ≈?-?0.068?K?kbar(-1). Band structure calculations are consistent with experimental data on the Sommerfeld coefficient and upper superconducting critical field anisotropy, and suggest a complex, multi-sheet Fermi surface formed by four bands. 相似文献