The amide bond rotation controlled by an unusual C-H···O hydrogen bonding that favors the 1,4-phenyl radical migration

Experimental evidence in support of the presence of a weak C-H···O hydrogen bonding that favors 1,4-phenyl radical migration in a chiral amide is provided.     

Glass forming region in the GeSe2–GeTe–PbTe system and some physicochemical properties of glassy alloys

New chalcogenide glasses from the GeSe₂–GeTe–PbTe system were synthesized. The glass forming region was determined using visual, X-ray diffraction and scanning electron microscopy analyses. It is extended towards the GeSe₂ and lies partially on the GeSe₂–GeTe (0–58 mol% GeTe) and GeSe₂–PbTe (20.0–57.5 mol% PbTe) sides. No glasses were obtained in the GeTe–PbTe system. The investigated physicochemical properties vary between 4.04–6.21 g/cm³ (density, d); 97–121 kgf/mm² (microhardness, HV); ?0.187 ÷ 0.007 (compactness, C) and 14.3–17.8 GPa (elasticity modulus, E), respectively.     

On smooth foliations with Morse singularities

Let M be a smooth manifold and let F be a codimension one, C^∞ foliation on M, with isolated singularities of Morse type. The study and classification of pairs (M,F) is a challenging (and difficult) problem. In this setting, a classical result due to Reeb (1946) [11] states that a manifold admitting a foliation with exactly two center-type singularities is a sphere. In particular this is true if the foliation is given by a function. Along these lines a result due to Eells and Kuiper (1962) [4] classifies manifolds having a real-valued function admitting exactly three non-degenerate singular points. In the present paper, we prove a generalization of the above mentioned results. To do this, we first describe the possible arrangements of pairs of singularities and the corresponding codimension one invariant sets, and then we give an elimination procedure for suitable center-saddle and some saddle-saddle configurations (of consecutive indices).In the second part, we investigate if other classical results, such as Haefliger and Novikov (Compact Leaf) theorems, proved for regular foliations, still hold true in presence of singularities. At this purpose, in the singular set, Sing(F) of the foliation F, we consider weakly stable components, that we define as those components admitting a neighborhood where all leaves are compact. If Sing(F) admits only weakly stable components, given by smoothly embedded curves diffeomorphic to S¹, we are able to extend Haefliger?s theorem. Finally, the existence of a closed curve, transverse to the foliation, leads us to state a Novikov-type result.     

Correlation Between Autofluorescence Intensity and Tumor Area in Mice Bearing Renal Cell Carcinoma

Protoporphyrin IX (PpIX) is a porphyrin derivative that is accumulated in cancerous tissue in consequence of the tumor-specific metabolic alterations. The aim of this study was to evaluate the accumulation of PpIX in mice bearing renal cell carcinoma by spectroscopy analysis. A total of 24 male Balb/c mice, 6 weeks old, were divided into six groups: Normal (without inoculation of tumor cells) and 4, 8, 13, 16, and 20 days after inoculation of tumor cells. The orthotopic tumor model of renal cancer was used. Murine renal cell carcinoma (Renca cells) were inoculated into the subcapsular space of the kidney. Normal and tumor-bearing kidneys in different progression stages were removed and analyzed by ex-vivo spectroscopy and by microscopy, for tumor histometric analysis. Emission spectra were obtained by exciting the samples at 405 nm. Significant differences between normal and tumor-bearing kidneys in autofluorescence shape occurred in the 600–700 nm spectral region. A good correlation was found between emission band intensity at 635 nm and the tumor area.     

Three-dimensional MgB2-type superconductivity in hole-doped diamond

We substantiate by numerical and analytical calculations that the recently discovered superconductivity below 4 K in 3% boron-doped diamond is caused by electron-phonon coupling of the same type as in MgB2, albeit in three dimensions. Holes at the top of the zone-centered, degenerate sigma-bonding valence-band couple strongly to the optical bond-stretching modes. The increase from two to three dimensions reduces the mode softening crucial for T(c) reaching 40 K in MgB2. Even if diamond had the same bare coupling constant as MgB2, which could be achieved with 10% doping, T(c) would be only 25 K. Superconductivity above 1 K in Si (Ge) requires hole doping beyond 5% (10%).     

Quantification of the Effect of an Impurity Addition on the Interaction Between Unlike Molecules in Mixed Liquids: A Theoretical Study

Journal of Solution Chemistry - The aim of this work is to develop a simple theory to study the effect of the addition of an impurity on the interaction between unlike molecules in mixed liquids....     

The synthesis of 4-benzylamino-6-methyl-1H-pyrrolo[3, 2-c]pyridine and 4-benzylamino-6-methyl-1H-pyrrolo[2, 3-b]pyridine

4-Benzylamino-6-methyl-1H-pyrrolo[3,2-c]pyridine ( 2 ) and 4-benzylamino-6-methyl-1H-pyrrolo[2,3-b]pyridine ( 3 ) were synthesized as deaza analogues of the anxiolytic agent 4-benzylamino-2-methyl-7H-pyrrolo[2,3-d]pyrimidine ( 1 ). The 1-deaza analogue (2) was prepared via a multi-step procedure from a pyrrole precursor, 1-benzyl-2-formylpyrrole ( 4 ) while the 3-deaza analogue 3 was synthesized from a pyridine precursor, 2-amino-3,6-dimethylpyridine ( 12 ).     

Synthesis and electric properties of the high-k ceramic composites based on potassium polytitanate modified by manganese

Research on Chemical Intermediates - Potassium polytitanates powders were modified by treatment in aqueous solutions of manganese sulfate at different pH, the obtained intermediates (PPT/Mn) were...     

Error Estimation for Discontinuous Galerkin Solutions of Two-Dimensional Hyperbolic Problems

We analyze the discretization errors of discontinuous Galerkin solutions of steady two-dimensional hyperbolic conservation laws on unstructured meshes. We show that the leading term of the error on each element is a linear combination of orthogonal polynomials of degrees p and p+1. We further show that there is a strong superconvergence property at the outflow edge(s) of each element where the average discretization error converges as O(h ^2p+1) compared to a global rate of O(h ^p+1). Our analyses apply to both linear and nonlinear conservation laws with smooth solutions. We show how to use our theory to construct efficient and asymptotically exact a posteriori discretization error estimates and we apply these to some examples.