Divinylbenzene derivatives represent an important class of molecular building blocks in organic chemistry and materials science. Reported herein is the palladium‐catalyzed synthesis of divinylbenzenes by meta‐C? H olefination of sulfone‐based arenes. Successful sequential olefinations in a position‐selective manner provided a novel route for the synthesis of hetero‐dialkenylated products, which are difficult to access using conventional methods. Additionally, 1,3,5‐trialkenylated compounds can be generated upon successful removal of the directing group. 相似文献
Laser desorption ionization using time-of-flight mass spectrometer afforded with quadrupole ion trap was used to study As2Ch3 (Ch = S, Se, and Te) bulk chalcogenide materials. The main goal of the study is the identification of species present in the plasma originating from the interaction of laser pulses with solid state material. The generated clusters in both positive and negative ion mode are identified as 10 unary (Sp+/– and Asm+/–) and 34 binary (AsmSp+/–) species for As2S3 glass, 2 unary (Seq+/–) and 26 binary (AsmSeq+/–) species for As2Se3 glass, 7 unary (Ter+/–) and 23 binary (AsmTer+/–) species for As2Te3 material. The fragmentation of chalcogenide materials was diminished using some polymers and in this way 45 new, higher mass clusters have been detected. This novel approach opens a new possibility for laser desorption ionization mass spectrometry analysis of chalcogenides as well as other materials.
Journal of Sol-Gel Science and Technology - The influence of the hydration and drying process on the line shape and signal intensity of the electron paramagnetic resonance spectra recorded from... 相似文献
This article presents an arithmetic for the computation of Chebyshev models for factorable functions and an analysis of their convergence properties. Similar to Taylor models, Chebyshev models consist of a pair of a multivariate polynomial approximating the factorable function and an interval remainder term bounding the actual gap with this polynomial approximant. Propagation rules and local convergence bounds are established for the addition, multiplication and composition operations with Chebyshev models. The global convergence of this arithmetic as the polynomial expansion order increases is also discussed. A generic implementation of Chebyshev model arithmetic is available in the library MC++. It is shown through several numerical case studies that Chebyshev models provide tighter bounds than their Taylor model counterparts, but this comes at the price of extra computational burden. 相似文献
The article discusses the steady motion of a rigid disk of finite thickness rolling on its edge on a horizontal plane under the influence of gravity. The governing equations are presented and two cases allowing for a steady-state solution are considered: rolling on consistently rough ground and rolling on perfectly smooth ground. The conditions of steady motion are derived for both kinds of ground and it is shown that the possible steady motion of a disk is either on a straight line or in a circle. Oscillations about steady state are discussed and conditions for stable motion established. The bifurcations of steady motions on a smooth surface are also considered. 相似文献