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11.
A variety of oxidative methods have been used for the preparation of sulfoxides from the corresponding sulfides2. However, only few of them permit the oxidation in a selective manner. These methods involve for example sodium metaperiodate3, dichloroiodobenzene4 and t-butyl hypochlorite5 as oxidising agent. It should be noted that it is necessary to use them in equivalent amounts in respect to sulfide in order to avoid the over-oxidation or α-halogenation reaction. 相似文献
12.
The thermal decomposition of 3-(α-trimethylsilyl)alkyl substituted 2-(phenylsulfinyl)cycloalkanones occurs via the γ-sila-Pummerer reaction, affording 3-substituted cycloalk-2-enones and unstable trimethylsilyl benzenesulfenate as an elimination by-product. The starting γ-silyl substituted cycloalkanoyl sulfoxides were obtained through the conjugate addition reaction of nucleophilic reagents to 2-(phenylsulfinyl)cycloalk-2-enones. The tandem conjugate addition/γ-sila-Pummerer reaction investigated here provides a new route to 3-substituted cycloalk-2-enones. 相似文献
13.
Piotr Łyżwa Marian Mikołajczyk 《Phosphorus, sulfur, and silicon and the related elements》2014,189(7-8):1174-1192
AbstractAminophosphonic acids have become important in different fields of chemistry, medicine and agriculture. In this review article, we highlight a new strategy developed in the author's laboratory of asymmetric synthesis of enantiomeric aminophosphonic acid that users chiral sulfinimines as reagents. A key reaction in the synthesis of enantiopure α-, β- and γ-aminophosphonic acids is a highly or fully diastereoselective addition of trivalent phosphorus nucleophiles and α-phosphonate carbanions to enantiopure sulfinimines. The steric course of these addition reactions is rationalized. The usefulness of the sulfinimine methodology is demonstrated by the synthesis of biologically active enantiopure 2-amino-3-phosphonopropanoic acid (AP3), 2-amino-4-phosphonobutanoic acid (AP4) and phosphoemeriamine. 相似文献
14.
The synthesis of both enantiomers of TEI-9826 has been accomplished in seven steps with an overall yield of 44% starting from diastereomeric camphor protected 3-[(dimethoxyphosphoryl)methyl]-4,5-dihydroxycyclopent-2-enones. The key steps include a fully diastereoselective hydrogenation of the endocyclic carbon–carbon double bond in the cyclopentenone ring controlled with a chiral diol moiety and the conversion of the latter into a new transposed olefinic bond. 相似文献
15.
R. Rakowski J. Miko?ajczyk A. Bartnik H. Fiedorowicz F. de Gaufridy de Dortan R. Jarocki J. Kostecki M. Szczurek P. Wachulak 《Applied physics. B, Lasers and optics》2011,102(3):559-567
In this paper a new approach to a laser-produced plasma EUV source based on a tin target is presented. A?thin layer of pure tin and composite layers consisting of Sn with Si, SiO and LiF are investigated. The target composed of several thin layers produces less debris than the other targets and provides a conversion efficiency (CE) in the 13.5-nm±1% band at least comparable to the CE for the pure tin slab target. The largest CE was observed for the target composed of a mixture of Sn and LiF, due to the fact that lithium, similarly to tin, is a strong emitter at 13.5?nm. 相似文献
16.
A. Dittmar-Wituski A. Grudziński ?. Lademann A. Miko?ajczyk ?. Andraszyk M. Roszak 《Applied Surface Science》2010,256(15):4789-766
In this paper, we present experimental results of target current (TCS) and LEED investigation of well-oriented InSb(1 1 0) and InSb(1 1 1)-A and InSb(1 1 1)-B crystals. TCS results are interpreted in terms of very low electron diffraction (VLEED) and empty band signatures. To examine to which extent the TCS spectra reflect the bulk or surface electronic properties of InSb(1 1 0), thin layers of indium have been evaporated and the corresponding spectrum changes have been investigated. 相似文献
17.
We show that every nonempty compact and convex space M of probability Radon measures either contains a measure which has ‘small’ local character in M or else M contains a measure of ‘large’ Maharam type. Such a dichotomy is related to several results on Radon measures on compact spaces and to some properties of Banach spaces of continuous functions. 相似文献
18.
Leszek Natkaniec Mikołaj F. Rudolf Bogusława Jeźowska-Trzebiatowska 《Theoretical chemistry accounts》1973,28(2):193-199
Results of SCCC MO calculations for the dimeric oxygen double-bridged [Mo2O4Cl4(H2O)2]2–ion are reported. On the basis of these results the previously reported spectra and magnetic properties may be explained. The strong direct molybdenum — molybdenum interaction in the Mo2O
4
2+
core was proved to exist.
Zusammenfassung Die Ergebnisse von SCCC MO-Rechnungen für das zweikernige Ion [Mo2O4Cl4(H2O)2]2– mit zweifacher Sauerstoffbrücke werden mitgeteilt. Danach können die früher angeführten magnetischen und spektralen Eigenschaften dieses Ions verstanden werden. Die Existenz starker unmittelbarer Molybdän-Molybdän Wechselwirkungen innerhalb des Mo2O 4 2+ Kerns wird nachgewiesen.
Résumé Résultats de calculs SCCCMO pour l'ion dimère Mo2O4Cl4(H2O) 2 2– . Sur la base de ces résultats les propriétés spectrales et magnétiques précédemment obtenues peuvent être expliquées. L'existence d'une forte interaction directe molybdène-molybdène dans le coeur Mo2O 4 2+ est clairement démontrée.相似文献
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