Novel types of boronated chlorin e6 conjugates via ‘click chemistry’

Conjugates of chlorin e₆ with closo‐dodecaborate and cobalt bis(dicarbollide) anions were synthesized for the first time in high yields using the advanced ‘click’ methodology. In vitro study on A549 human lung adenocarcinoma cells revealed that the synthesized boronated conjugates are able to penetrate and accumulate in cancer cells, but their intracellular concentration is not sufficient for effective photodynamic and boron neutron capture therapy of cancer. Copyright © 2009 John Wiley & Sons, Ltd.     

Adaptive Runge–Kutta discontinuous Galerkin method for complex geometry problems on Cartesian grid

A Cartesian grid method using immersed boundary technique to simulate the impact of body in fluid has become an important research topic in computational fluid dynamics because of its simplification, automation of grid generation, and accuracy of results. In the frame of Cartesian grid, one often uses finite volume method with second order accuracy or finite difference method. In this paper, an h‐adaptive Runge–Kutta discontinuous Galerkin (RKDG) method on Cartesian grid with ghost cell immersed boundary method for arbitrarily complex geometries is developed. A ghost cell immersed boundary treatment with the modification of normal velocity is presented. The method is validated versus well documented test problems involving both steady and unsteady compressible flows through complex bodies over a wide range of Mach numbers. The numerical results show that the present boundary treatment to some extent reduces the error of entropy and demonstrate the efficiency, robustness, and versatility of the proposed approach. Copyright © 2013 John Wiley & Sons, Ltd.     

On a problem by Beidar concerning the central closure

We give an example of a prime ring with zero center such that its central closure is a simple ring with an identity element. It solves a problem posed by Beidar.     

Modeling the Behavior of Heat-Shrinkable Thin Films

We describe an asymptotic model for the behavior of PET-like heat-shrinkable thin films that includes both membrane and bending energies when the thickness of the film is positive. We compare the model to Koiter’s shell model and to models in which a membrane energy or a bending energy are obtained by Γ-convergence techniques. We also provide computational results for various temperature distributions applied to the films.     

On local convergence of sequential quadratically-constrained quadratic-programming type methods,with an extension to variational problems

We consider the class of quadratically-constrained quadratic-programming methods in the framework extended from optimization to more general variational problems. Previously, in the optimization case, Anitescu (SIAM J. Optim. 12, 949–978, 2002) showed superlinear convergence of the primal sequence under the Mangasarian-Fromovitz constraint qualification and the quadratic growth condition. Quadratic convergence of the primal-dual sequence was established by Fukushima, Luo and Tseng (SIAM J. Optim. 13, 1098–1119, 2003) under the assumption of convexity, the Slater constraint qualification, and a strong second-order sufficient condition. We obtain a new local convergence result, which complements the above (it is neither stronger nor weaker): we prove primal-dual quadratic convergence under the linear independence constraint qualification, strict complementarity, and a second-order sufficiency condition. Additionally, our results apply to variational problems beyond the optimization case. Finally, we provide a necessary and sufficient condition for superlinear convergence of the primal sequence under a Dennis-Moré type condition. Research of the second author is partially supported by CNPq Grants 300734/95-6 and 471780/2003-0, by PRONEX–Optimization, and by FAPERJ.     

On association schemes all elements of which have valency 1 or 2

In the present note, we investigate schemes S in which each element s satisfies n_s2 and n_s^*s≠2. We show that such a scheme is schurian. More precisely, we show that it is isomorphic to G//t, where G is a finite group and t an involution of G weakly closed in C_G(t).

Groups G with an involution t weakly closed in C_G(t) have been described in Glauberman's Z^*-Theorem [G. Glauberman, Central elements in core-free groups, J. Algebra 4 (1966) 403–420] with the help of the largest normal subgroup of G having odd order.     

Small deviation probability via chaining

We obtain several extensions of Talagrand’s lower bound for the small deviation probability using metric entropy. For Gaussian processes, our investigations are focused on processes with sub-polynomial and, respectively, exponential behaviour of covering numbers. The corresponding results are also proved for non-Gaussian symmetric stable processes, both for the cases of critically small and critically large entropy. The results extensively use the classical chaining technique; at the same time they are meant to explore the limits of this method.