Getting a Grasp of the Grasping Involved in Understanding

This paper investigates some epistemic properties that distinguish understanding from knowledge. In particular, the focus is on how to spell out the notion of grasping the relationships between propositions that constitute objectual understanding: what kind of epistemic access is required for grasping to occur and to what extent is the act of grasping voluntary? A modest form of access is suggested as an answer to the first question and a largely negative answer to the second. The worry that my suggestion is too permissive in crediting subjects with understanding is addressed. The results are then finally briefly contrasted to Ernest Sosa’s notion of knowing full well where one contrast precisely concerns the voluntary character of the respective epistemic states.     

Raman spectroscopic studies of terthiophenes for molecular electronics

The effect of thiol and selenol functionalization on the vibrational spectra and photochemical stability of terthiophene based molecular wires was investigated using surface-enhanced Raman scattering (SERS). The molecules were found to exhibit markedly different properties at the silver surface of the SERS substrate, despite having almost identical Raman spectra in solution and in the solid state. In contrast to terthiophene (3T), the bisthiolterthiophene (T3) and biselenol-terthiophene (Se3) molecules were stable against photoinduced structural changes when adsorbed to the metal surface at low concentrations. This indicates that the strong bonds to the silver surface, via S or Se terminal atoms, leads to a rapid decay of photoexcited states. Comparison with ab initio calculations shows that both T3 and Se3 bind with only one of the functional groups to the Ag surface.     

Mellin Transforms of Multivariate Rational Functions

This paper deals with Mellin transforms of rational functions g/f in several variables. We prove that the polar set of such a Mellin transform consists of finitely many families of parallel hyperplanes, with all planes in each such family being integral translates of a specific facial hyperplane of the Newton polytope of the denominator f. The Mellin transform is naturally related to the so-called coamoeba $\mathcal{A}'_{f}:=\mathrm{Arg}(Z_{f})$ , where Z _f is the zero locus of f and Arg denotes the mapping that takes each coordinate to its argument. In fact, each connected component of the complement of the coamoeba $\mathcal{A}'_{f}$ gives rise to a different Mellin transform. The dependence of the Mellin transform on the coefficients of f, and the relation to the theory of A-hypergeometric functions is also discussed in the paper.     

A continuation approach to mode-finding of multivariate Gaussian mixtures and kernel density estimates

This paper presents a novel method of multi-objective optimization by learning automata (MOLA) to solve complex multi-objective optimization problems. MOLA consists of multiple automata which perform sequential search in the solution domain. Each automaton undertakes dimensional search in the selected dimension of the solution domain, and each dimension is divided into a certain number of cells. Each automaton performs a continuous search action, instead of discrete actions, within cells. The merits of MOLA have been demonstrated, in comparison with a multi-objective evolutionary algorithm based on decomposition (MOEA/D) and non-dominated sorting genetic algorithm II (NSGA-II), on eleven multi-objective benchmark functions and an optimal problem in the midwestern American electric power system which is integrated with wind power, respectively. The simulation results have shown that MOLA can obtain more accurate and evenly distributed Pareto fronts, in comparison with MOEA/D and NSGA-II.     

Tautomeric populations of the charged species of 1,12‐diamino‐3,6,9‐triazadodecane (SpmTrien) studied with computer simulations and cluster expansions

Correct net charge and protonation pattern in the polyamine backbone is one of the major factors that define the interactions of this class of compounds. 1,12‐diamino‐3,6,9‐triazadodecane (SpmTrien) is a isosteric charge deficient analogue of naturally occurring spermine (Spm) with different biological features. The tautomeric populations of each SpmTrien charge state were estimated with computer simulations, molecular dynamics (MD) and quantum mechanical calculations, and cluster expansions separately. In the computer simulations, tautomeric populations of each charge state were obtained by constrained least‐squares fitting the theoretically calculated (GIAO B3LYP/6‐311 + G**) ¹⁵ N NMR chemical shieldings of SpmTrien tautomers to the experimentally measured chemical shifts. Theoretical chemical shieldings were calculated for water complexes of SpmTrien obtained from MD simulations in explicit water. Both methods gave highly similar realistic results. SpmTrien has many major populations of tautomers at biologically relevant charge states of three (+3) and four (+4) thus enabling a large variety of structures for specific ionic interactions. Copyright © 2013 John Wiley & Sons, Ltd.     

Weighted Composition Operators Between Zygmund Type Spaces and Their Essential Norms

Let ${u \in \mathcal{H}(\mathbb{D})}$ and φ be an analytic self-map of ${\mathbb{D}}$ . We estimate the essential norms of weighted composition operators uC _φ acting on Zygmund type spaces in terms of u, φ, their derivatives and the n-th power φ ⁿ of φ. Moreover, we give similar characterizations for boundedness of uC _φ between Zygmund type spaces.     

Negative Poisson's ratio materials via isotropic interactions

We show that under tension a classical many-body system with only isotropic pair interactions in a crystalline state can, counterintuitively, have a negative Poisson's ratio, or auxetic behavior. We derive the conditions under which the triangular lattice in two dimensions and lattices with cubic symmetry in three dimensions exhibit a negative Poisson's ratio. In the former case, the simple Lennard-Jones potential can give rise to auxetic behavior. In the latter case, a negative Poisson's ratio can be exhibited even when the material is constrained to be elastically isotropic.     

Optimized structures for photonic quasicrystals

A photonic quasicrystal consists of two or more dielectric materials arranged in a quasiperiodic pattern with noncrystallographic symmetry that has a photonic band gap. We use a novel method to find the pattern with the widest TM-polarized gap for two-component materials. Patterns are obtained by computing a finite sum of density waves, assigning regions where the sum exceeds a threshold to a material with one dielectric constant, epsilon1, and all other regions to another, epsilon0. Compared to optimized crystals, optimized quasicrystals have larger gaps at low constrasts epsilon1/epsilon0 and have gaps that are much more isotropic for all contrasts. For high contrasts, optimized hexagonal crystals have the largest gaps.