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61.
Katsuma Hiraki Toshihiro Itoh Katsuya Eguchi Masayoshi Onishi 《Journal of organometallic chemistry》1983,241(1):C16-C20
Benzylchlorobis(triphenylphosphine)palladium(II) reacted with dimethyl acetylenedicarboxylate to give [Pd[C(CO2Me)=C(CH2Ph)(CO2Me)]Cl(PPh3)2] (II) and [(Ph3P)ClPdμ-C(CO2Me)=C(CO2Me)PdCl(PPh3) (III). Complexes II and III reacted with Tl(acac) to afford [PdC(CO2Me=C(CH2Ph)(CO2Me)-(acac)(PPh3)] and [(Ph3P)(acac)Pdμ-C(CO2Me)=C(CO2Me)Pd(acac)(PPh3)], respectively. 相似文献
62.
63.
Dispersion behavior of aqueous solutions containing oleic acid (RH), sodium oleate (R-Na+), and NaCl was investigated by turbidity and dynamic light-scattering measurements. Changes of the size of scattering particles
in solution composed of 1 mM oleic acid and 100 mM NaCl were traced as a function of the degree of ionization α, in terms
of radius of the equivalent hydrodynamic sphere. Large associated micelles with a radius of 30 nm appeared by a slight decline
of α and existed at α higher than 0.75. They were responsible for the three-phase equilibrium (solution, micelle and aggregated
micelle, and acid–soap, (R-Na+)3RH) characterized by a constant pH of 9.75. The appearance of a new phase, (R-Na+)3RH, contributed to increase both the turbidity and averaged scattering particle size. As the breakdown of the three-phase
equilibrium, radius of scattering particles increased significantly. Finally, oleic acid oil droplets were separated from
aqueous phase at low α. When the system was buffered by tris(hydroxymethyl)aminomethane (Tris), scattering particles with
a weight-averaged hydrodynamic radius of 75 nm existed in a wide range of α from 0.85 to 0.65. In Tris buffered solution,
turbidity formation was induced by the increase in the number of aggregated particles.
Received: 12 November 1996 Accepted: 4 April 1997 相似文献
64.
A crucial enzyme in the biosynthesis of the 2-deoxystreptamine aglycon of clinically important aminocyclitol antibiotics is 2-deoxy-scyllo-inosose synthase (DOIS), which converts ubiquitous D-glucose 6-phosphate (G-6-P) into the specific carbocycle 2-deoxy-scyllo-inosose. Among all the oxygenated carbons of the substrate, C-1, -4, -5, and -6 are directly involved in the chemical transformation. To get insight into the roles of C-2 and C-3 hydroxy groups, 2-deoxy-2-fluoro-, 3-deoxy-3-fluoro-, 2-amino-2-deoxy-, and 3-amino-3-deoxy-D-glucose 6-phosphates (2-F-G-6-P, 3-F-G-6-P, 2-NH(2)-G-6-P, and 3-NH(2)-G-6-P, respectively) were subjected to the DOIS reaction as probe, since a fluorine substituent generally acts as a hydrogen-bond acceptor, and an ammonium functionality derived physiologically from an amino group as a hydrogen-bond donor. Among those tested, 2-F-G-6-P and 3-NH(2)-G-6-P were used as substrates by DOIS and were converted into the corresponding deoxyfluoro- and aminodeoxy-scyllo-inososes, respectively. In contrast, 3-F-G-6-P and 2-NH(2)-G-6-P were inactive in the cyclization reaction. Clearly, DOIS recognizes the G-6-P substrate through specific hydrogen-bonding interactions, i.e., through a hydrogen-donating group for C-2 and an accepting group for C-3 of the substrate. Modeling of DOIS based on the structure of evolutionary-related dehydroquinate synthase is also described. 相似文献
65.
Motoki Kaneno Shunro Yamaguchi Hirokazu Nakayam Keisuke Miyakubo Takahiro Ueda Taro Eguchi 《Molecular Crystals and Liquid Crystals》2013,570(2):561-566
Abstract The intercalation compound between α-zirconium phosphate and N,N′-bis-(3-aminopropyl)-1, 3-propanediamine has two different modifications with respect to the conformation of the guest amine molecules: one is “bent form” and the other “straight form”. Reactivity of each phase with a series of aldehydes was examined. 13C CP/MAS NMR indicated that the tetraamine reacts stereoselectively with aldehydes to form cis-imine in the interlayer spacing. Depending on the molecular size of aldehyde, it is found that a significant difference can be recognized in the yields of the imine products for the two phases of intercalation compounds. It is also noted that residual water molecules in the interlayer spacing play an important role in the imine formation reaction. 相似文献
66.
In addition to our previous paper on the photochemical behaviors of chrysanthemic acid,2 we wish to report preliminary results on its photosensitized oxygenation, in which a marked reactivity difference has been observed between the cis- and trans isomers. 相似文献
67.
68.
We use the representation theory of \({\mathcal{N}=2}\) superconformal algebra to study the elliptic genera of Calabi–Yau (CY) D-folds. We compute the entropy of CY manifolds from the growth rate of multiplicities of the massive (non-BPS) representations in the decomposition of their elliptic genera. We find that the entropy of CY manifolds of complex dimension D behaves differently depending on whether D is even or odd. When D is odd, CY entropy coincides with the entropy of the corresponding hyperKähler (D ? 3)-folds due to a structural theorem on Jacobi forms. In particular, we find that the Calabi–Yau 3-fold has a vanishing entropy. At D > 3, using our previous results on hyperKähler manifolds, we find \({S_{CY_D}\sim 2\pi \sqrt{\frac{(D-3)^2}{2(D-1)}n}}\). When D is even, we find the behavior of CY entropy behaving as \({S_{CY_D}\sim 2 \pi\sqrt{\frac{D-1}{2}n}}\). These agree with Cardy’s formula at large D. 相似文献
69.
The ring expansion of homoadamant-4-en-2-one (7) via the corresponding aminomethyl alcohol (9) gave 1,3-bishomoadamant-7-en-4-one (10) as the major product which was converted to 1,3-bishomoadamant-4-ene (14) and 1,3-bishomoadamanta-4,7-diene (16) via the alcohols 13 and 15. Catalytic hydrogenation of 14 and 16 afforded 1,3-bishomoadamantane (2). The ring expansion of homoadamantan-2-one (17) via the aminomethyl alcohol (19) afforded a 9:1 mixture of 1,3-bishomoadamantan-4-one (12) and 5-one (20). The same mixture was also obtained directly from 17 on treatment with diazomethane. The Wolff-Kishner reduction of 12 and 20 gave also 2. 相似文献
70.
Plastic optical fibers are typical large-core multimode optical fibers. High-bandwidth graded-index plastic optical fibers, which support a great number of propagation modes compared with conventional silica-glass multimode optical fibers, were developed in the 1990s. However, because they support a great number of propagation modes, their modal analyses have been limited to the WKB analysis. We obtain all the propagation modes of a convex-index large-core multimode optical fiber by use of the finite-element method, which has a strong advantage for arbitrary core profiles. 相似文献