Synthesis,properties, and interaction with paraquat of new fluorenonocrownophanes containing a hydroquinone fragment

New crownophane family was synthesized containing fragments of 2,7-dioxyfluorenone and hydroquinone connected with residues of tri- and tetraethylene glycols. The formation of inclusion complexes of these ligands with paraquat was established by means of mass spectrometry (fast-atom bombardment), ¹H NMR and electronic spectroscopy. The crownophane with a larger ring formed the more stable complex.

     

Acoustic field generated by a beam of protons stopping in a water medium

In an experiment with a beam of protons accelerated up to an energy of 200 MeV, the space-time structure of the hydroacoustic field generated by protons stopping in the water medium was observed. The contributions of three components were separated: a cylindrical wave diverging from the middle part of the acoustic antenna and the signals from the ends of the antenna, namely, from the region of the maximal energy density release by protons (the Bragg peak) and from the other end corresponding to the beam entrance into water.     

Self-similar evolution of the surface morphology of a stressed amorphous alloy foil

A time-ordered sequence of topographic images of a stressed amorphous Fe₇₀Cr₁₅B₁₅ ribbon is presented. It is shown that the surface of this material (unlike polycrystalline metal foil) has a fractal structure due to the nonequilibrium conditions of its formation. As a tensile stress of about 500 MPa is applied to the surface, the fractal dimension of the surface increases from 1.21±0.02 to 1.34±0.03, then drops to 1.12±0.03, and finally increases to 1.22±0.02. In about 1.5 hours, a complex surface morphology characterized by a roughness amplitude of several tens of nanometers evolves into a regular pattern of shear bands with amplitude of about 300 nm. Self-affine changes in surface morphology are explained by competition between several processes, including crack propagation, surface smoothing, and self-diffusion.     

Energy criterion for relief formation on a strained surface

The strain-induced roughening revealed by scanning tunneling microscopy on the surface of elastically strained Ge(111) crystals and Fe₇₀Cr₁₅B₁₅ amorphous alloy foils is discussed. It is demonstrated that the strained-induced roughening can be considered a channel for a decrease in the elastic energy of the strained surface. The diffusion mechanism of relief formation on a strained Ge(111) surface is proposed and justified.     

Truncated Trust Region Methods Based on Preconditioned Iterative Subalgorithms for Large Sparse Systems of Nonlinear Equations

This paper is devoted to globally convergent methods for solving large sparse systems of nonlinear equations with an inexact approximation of the Jacobian matrix. These methods include difference versions of the Newton method and various quasi-Newton methods. We propose a class of trust region methods together with a proof of their global convergence and describe an implementable globally convergent algorithm which can be used as a realization of these methods. Considerable attention is concentrated on the application of conjugate gradient-type iterative methods to the solution of linear subproblems. We prove that both the GMRES and the smoothed COS well-preconditioned methods can be used for the construction of globally convergent trust region methods. The efficiency of our algorithm is demonstrated computationally by using a large collection of sparse test problems.     

Acylation of 1-methoxy-3-methyl-1-triazene 2-oxide

Chlorides and anhydrides of carboxylic (including dicarboxylic) acids react with salts of 1-methoxy-3-methyl-1-triazene 2-oxides to give the corresponding 3-acyl-1-methoxy-3-methyl-1-triazene 2-oxides.     

Single‐Crystal‐to‐Single‐Crystal Transition in an Enantiopure [7]Helquat Salt: The First Observation of a Reversible Phase Transition in a Helicene‐Like Compound

Here it is reported that crystals of an enantiopure [7]helquat salt undergo reversible thermal solid–solid phase transition at 404 K. Differential scanning calorimetry (DSC), capillary electrophoresis (CE), and X‐ray diffraction analysis were used to unravel the mechanistic details of this process. The single‐crystal‐to‐single‐crystal course enabled direct monitoring of the structural changes by in situ variable‐temperature X‐ray diffraction, thus providing the first direct evidence of a solid phase transition in a helicene‐like compound.     

Standard Koszul standardly stratified algebras

In this paper, we prove that every standard Koszul (not necessarily graded) standardly stratified algebra is also Koszul. This generalizes a similar result of [3 Ágoston, I., Dlab, V., Lukács, E. (2003). Quasi-hereditary extension algebras. Algebras Represent. Theory 6:97–117.[Crossref], [Web of Science ®] , [Google Scholar]] on quasi-hereditary algebras.     

Wax treatment of wood slows photodegradation

Waxes and wax emulsions are one of the most important solutions for non-biocidal wood protection. Wax treated wood is designed for outdoor use, therefore it is of considerable importance to elucidate the influence of weathering on the photodegradation processes. It is presumed, that wax treatment will reduce water uptake and thus reduce or slow down photodegradation processes. In order to test this hypothesis, three types of wax emulsions at two different concentrations were vacuum impregnated into Norway spruce wood specimens: an emulsion of montan wax (LGE), an emulsion of polyethylene (WE1) and an emulsion of oxidized polyethylene (WE6) wax. The samples were exposed to artificial accelerated weathering (AAW) for 500 cycles. Before and after AAW colour, the contact angle of water and moisture content were determined. Chemical and morphological changes at exposed surfaces were also investigated with FTIR spectroscopy and SEM. In parallel, the uptake of wax emulsions and water into the axial surfaces of samples was determined with a tensiometer. The moisture content measurements showed that the best hydrophobic effect was achieved with LGE treated wood, where the lowest colour and FTIR changes were observed as well. These results were supported by tensiometer measurements as well. Presented data clearly showed that high loadings of waxes reduce or at least slow down weathering. Among tested waxes, montan wax was found the most effective.     

Modification of proteins with cyclodextrins prevents aggregation and surface adsorption and increases thermal stability

This work describes a general approach for preventing protein aggregation and surface adsorption by modifying proteins with β-cyclodextrins (βCD) via an efficient water-driven ligation. As compared to native unmodified proteins, the cyclodextrin-modified proteins (lysozyme and RNase A) exhibit significant reduction in aggregation, surface adsorption and increase in thermal stability. These results reveal a new chemistry for preventing protein aggregation and surface adsorption that is likely of different mechanisms than that by modifying proteins with poly(ethylene glycol).