Diffusion and Velocity Correlations of the Phase Transitions in a System of Macroscopic Rolling Spheres

We study an air-fluidized granular monolayer composed of plastic spheres which roll on a metallic grid. The air current is adjusted so that the spheres never lose contact with the grid and so that the dynamics may be regarded as pseudo two dimensional (or two dimensional, if the effects of the sphere rolling are not taken into account). We find two surprising continuous transitions, both of them displaying two coexisting phases. Moreover, in all the cases, we found the coexisting phases display a strong energy non-equipartition. In the first transition, at a weak fluidization, a glass phase coexists with a disordered fluid-like phase. In the second transition, a hexagonal crystal coexists with the fluid phase. We analyze, for these two-phase systems, the specific diffusive properties of each phase, as well as the velocity correlations. Surprisingly, we find a glass phase at a very low packing fraction and for a wide range of granular temperatures. Both phases are also characterized by strong anticorrelated velocities upon a collision. Thus, the dynamics observed for this quasi two-dimensional system unveil phase transitions with peculiar properties, very different from the predicted behavior in well-know theories for their equilibrium counterparts.     

On the fractional integral of Weyl inL p

This work has been partially supported by D.G.C.Y.T., grant PS88-0115, Spain     

Gauge invariance and spontaneous symmetry breaking in two-gap superconductors

The gauge symmetry of the Ginzburg–Landau theory for two-gap superconductors is analyzed in this letter. We argue that the existence of two different phases, associated with the two independent scalar Higgs fields, explicitly breaks the gauge symmetry of the Ginzburg–Landau Hamiltonian, unless a new additional vector field is included. Furthermore, the interference term, or Josephson coupling, holding a direct dependence with the phase difference, also explicitly breaks down the gauge symmetry. We show that a solution for the problem is achieved by adding an additional kinetic coupling term between the two vector fields, which generates the desired terms through a spontaneous symmetry breaking mechanism. Finally, the electrodynamics of the system is also presented in terms of the supercurrents inside the superconducting region.     

Bifurcation and resonance in a fractional Mathieu-Duffing oscillator

The bifurcation and resonance phenomena are investigated in a fractional Mathieu-Duffing oscillator which contains a fast parametric excitation and a slow external excitation. We extend the method of direct partition of motions to evaluate the response for the parametrically excited system. Besides, we propose a numerical method to simulate different types of local bifurcation of the equilibria. For the nonlinear dynamical behaviors of the considered system, the linear stiffness coefficient is a key factor which influences the resonance phenomenon directly. Moreover, the fractional-order damping brings some new results that are different from the corresponding results in the ordinary Mathieu-Duffing oscillator. Especially, the resonance pattern, the resonance frequency and the resonance magnitude depend on the value of the fractional-order closely.     

Isoparametric submanifolds in two-dimensional complex space forms

We show that an isoparametric submanifold of a complex hyperbolic plane, according to the definition of Heintze, Liu and Olmos’, is an open part of a principal orbit of a polar action. We also show that there exists a non-isoparametric submanifold of the complex hyperbolic plane that is isoparametric according to the definition of Terng’s. Finally, we classify Terng-isoparametric submanifolds of two-dimensional complex space forms.     

High-Velocity Estimates for the Scattering Operator and Aharonov-Bohm Effect in Three Dimensions

We obtain high-velocity estimates with error bounds for the scattering operator of the Schrödinger equation in three dimensions with electromagnetic potentials in the exterior of bounded obstacles that are handlebodies. A particular case is a finite number of tori. We prove our results with time-dependent methods. We consider high-velocity estimates where the direction of the velocity of the incoming electrons is kept fixed as its absolute value goes to infinity. In the case of one torus our results give a rigorous proof that quantum mechanics predicts the interference patterns observed in the fundamental experiments of Tonomura et al. that gave conclusive evidence of the existence of the Aharonov-Bohm effect using a toroidal magnet. We give a method for the reconstruction of the flux of the magnetic field over a cross-section of the torus modulo 2π. Equivalently, we determine modulo 2π the difference in phase for two electrons that travel to infinity, when one goes inside the hole and the other outside it. For this purpose we only need the high-velocity limit of the scattering operator for one direction of the velocity of the incoming electrons. When there are several tori-or more generally handlebodies-the information that we obtain in the fluxes, and on the difference of phases, depends on the relative position of the tori and on the direction of the velocities when we take the high-velocity limit of the incoming electrons. For some locations of the tori we can determine all the fluxes modulo 2π by taking the high-velocity limit in only one direction. We also give a method for the unique reconstruction of the electric potential and the magnetic field outside the handlebodies from the high-velocity limit of the scattering operator.     

Closed-form BER analysis of variable weight MPPM coding under gamma-gamma scintillation for atmospheric optical communications

In this paper, the performance of the variable weight multiple pulse-position modulation (MPPM) coding technique in an atmospheric optical communication environment under gamma-gamma optical scintillation is analyzed, proposing a closed-form expression for the average bit error rate (BER). This study is based on a hyperexponential fitting of the conditional BER in absence of turbulence fluctuations, leading to closed-form expressions that characterize the behavior of this nonlinear coding scheme. Finally, conditional and average BER expressions proposed here are corroborated with Monte Carlo simulations results.     

Synthesis,Antiprotozoal Activity,and Cheminformatic Analysis of 2-Phenyl-2H-Indazole Derivatives

Indazole is an important scaffold in medicinal chemistry. At present, the progress on synthetic methodologies has allowed the preparation of several new indazole derivatives with interesting pharmacological properties. Particularly, the antiprotozoal activity of indazole derivatives have been recently reported. Herein, a series of 22 indazole derivatives was synthesized and studied as antiprotozoals. The 2-phenyl-2H-indazole scaffold was accessed by a one-pot procedure, which includes a combination of ultrasound synthesis under neat conditions as well as Cadogan’s cyclization. Moreover, some compounds were derivatized to have an appropriate set to provide structure-activity relationships (SAR) information. Whereas the antiprotozoal activity of six of these compounds against E. histolytica, G. intestinalis, and T. vaginalis had been previously reported, the activity of the additional 16 compounds was evaluated against these same protozoa. The biological assays revealed structural features that favor the antiprotozoal activity against the three protozoans tested, e.g., electron withdrawing groups at the 2-phenyl ring. It is important to mention that the indazole derivatives possess strong antiprotozoal activity and are also characterized by a continuous SAR.     

Use of hydrogen peroxide to achieve interference-free stripping voltammetric determination of copper at the bismuth-film electrode

In this work, a new approach is presented to allow interference-free determination of Cu (II) by stripping voltammetry using the bismuth-film electrode. The addition of hydrogen peroxide to the electroanalytical cell has promoted complete resolution between re-dissolution peaks of Bi (III) and Cu (II). The absence of interference could be evaluated by the correlation coefficient (r > 0.99) between Cu (II) concentration and its shifted current peak (at +212 mV) while achieving a slightly fluctuation of the bismuth current peak at −180 mV. Studies were performed aiming towards the optimum conditions for trace determination of Cu (II) using hydrogen peroxide. The methodology was applied to a real sample (sugarcane spirits) and the results were compared to those from graphite furnace atomic absorption spectrometry. The analytical parameters of merit and the results of the analysis indicated that the analytical methodology could be readily used for trace determination of Cu (II).     

Quantum dynamics study of the K+HF(v=0-2,j=0)-->KF+H reaction and comparison with quasiclassical trajectory results

Extensive quantum real wave packet calculations within the helicity decoupling approximation are used to analyze the influence of the HF vibrational excitation on the K+HF(v=0-2,j=0)-->KF+H reaction. Quantum reaction probabilities P and reaction cross sections sigma are compared with corresponding quasiclassical trajectory (QCT) results. Disregarding threshold regions for v=0 and 1 (v=2 has no threshold), both approaches lead to remarkably similar results, particularly for sigma, validating the use of the QCT method for this system. When moving from v=0 to v=1 there is a large increase in P and sigma, as expected for a late barrier system. For v=2 the reaction becomes exoergic and P approximately 0.95 (with the exception of large total angular momenta where centrifugal barriers play a role). While substantial vibrational enhancement of the reactivity is thus seen, it is still quite less than that inferred from experimental data in the intermediate and high collision energy ranges. The origin of this discrepancy is unclear.