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201.
We have proposed the mechanism of the <110> directional growth of microcrystalline silicon (μc-Si) thin films deposited by PECVD (plasma enhanced chemical vapor deposition) from SiH4 and H2 gas mixture, where dimeric radicals act a key role to form bridge nuclei for the ledge formation on the (110) facet. In order to look further into details of the mechanism, we investigated other important factors that influence the growth of μc-Si in <110> direction in terms of their impact on crystallinity with varying deposition temperature. The enhancement of surface diffusion length of radicals is inferred from the enlargement of the crystalline grain size accompanied with the increase of the deposition temperature. The growth in <110> direction is also promoted as the deposition temperature increases. Therefore, it is suggested that the surface diffusion length of radicals is another key factor that governs the crystalline growth in <110> direction. The growth mechanism of μc-Si thin films in <110> direction is discussed in terms of the relation between the surface diffusion length of monomeric radicals depending on the substrate surface temperature and the average space of bridges depending on the density of dimeric radicals on the growing surface. 相似文献
202.
Masahiro Kako Yuki Arikawa Shinji Kanzawa Michio Yamada Yutaka Maeda Makoto Furukawa Takeshi Akasaka 《Helvetica chimica acta》2019,102(5)
The reactions of novel S‐heterocyclic carbenes (SHCs), which were prepared by the cycloaddition of disilenes and digermenes to CS2, with C60 and Sc3N@Ih‐C80 afforded the corresponding methano‐bridged fullerenes. The [6,6]‐closed and [6,6]‐open structures were characterized for the SHC adducts of C60 and Sc3N@Ih‐C80, respectively. These derivatives exhibited relatively low oxidation potentials, indicative of the electron‐donating effects of the SHC addends. The electronic properties of the SHC derivatives were clarified by the density functional theory calculations. 相似文献
203.
Michio Tokuyama 《Physica A》2008,387(21):5003-5011
A statistical-mechanical theory of self-diffusion in glass-forming liquids is presented. A non-Markov linear Langevin equation is derived from a Newton equation by employing the Tokuyama-Mori projection operator method. The memory function is explicitly written in terms of the force-force correlation functions. The equations for the mean-square displacement, the mean-fourth displacement, and the non-Gaussian parameter are then formally derived. The present theory is applied to the glass transitions in the glass-forming liquids to discuss the crossover phenomena in the dynamics of a single particle from a short-time ballistic motion to a long-time self-diffusion process via a β (caging) stage. The effects of the renormalized friction coefficient on self-diffusion are thus explored with the aid of analyses of the simulation results by the mean-field theory proposed recently by the present author. It is thus shown that the relaxation time of the renormalized memory function is given by the β-relaxation time. It is also shown that for times longer than the β-relaxation time the dynamics of a single particle is identical to that discussed in the suspensions. 相似文献
204.
Michio Nishioka 《Fortschritte der Physik》1985,33(4):241-257
Using a manifestly gauge-invariant Lagrangian density of a system in which a real scalar field (matter field) is interacting with itself and with Weyl's gauge field, we shall study equations of the real scalar field and of Weyl's gauge field, and discuss the self-interacting term of the real scalar field. For a special self-interacting term, we shall obtain an equation of only Weyl's gauge field which plays an important role in solving the equation of Weyl's gauge field interacting with the real scalar field. By making use of the above mentioned equation we shall obtain a rigorous solution for Weyl's gauge field. Next, combining the equation of only Weyl's gauge field with the condition in Weyl's gauge field that the length scale of any vector changes under parallel transfer, we shall obtain a nonlinear equation for the length scale of Weyl's gauge field, which may be important in mathematical physics and is shown to have meron-type solution. By making use of the same techniques being used above, we shall study solution of equation of gradient Weyl's gauge field and as a result, obtain a nonlinear equation of the same type as being found above. Finally we shall study relation between local gauge transformation and symmetric connection in space-time. As a result, we can partly make clear relation between the change in the measure of length scale of a vector due to an infinitesimal parallel transfer and the coefficients of affine connection of Weyl's geometry. 相似文献
205.
13C‐TmDOTA as versatile thermometer compound for solid‐state NMR of hydrated lipid bilayer membranes
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Yuichi Umegawa Yuya Tanaka Matsumori Nobuaki Michio Murata 《Magnetic resonance in chemistry : MRC》2016,54(3):227-233
Recent advances in solid‐state nuclear magnetic resonance (NMR) techniques, such as magic angle spinning and high‐power decoupling, have dramatically increased the sensitivity and resolution of NMR. However, these NMR techniques generate extra heat, causing a temperature difference between the sample in the rotor and the variable temperature gas. This extra heating is a particularly crucial problem for hydrated lipid membrane samples. Thus, to develop an NMR thermometer that is suitable for hydrated lipid samples, thulium‐1,4,7,10‐tetraazacyclododecane‐1,4,7,10‐tetraacetate (TmDOTA) was synthesized and labeled with 13C (i.e., 13C‐TmDOTA) to increase the NMR sensitivity. The complex was mixed with a hydrated lipid membrane, and the system was subjected to solid‐state NMR and differential scanning calorimetric analyses. The physical properties of the lipid bilayer and the quality of the NMR spectra of the membrane were negligibly affected by the presence of 13C‐TmDOTA, and the 13C chemical shift of the complex exhibited a large‐temperature dependence. The results demonstrated that 13C‐TmDOTA could be successfully used as a thermometer to accurately monitor temperature changes induced by 1H decoupling pulses and/or by magic angle spinning and the temperature distribution of the sample inside the rotor. Thus, 13C‐TmDOTA was shown to be a versatile thermometer for hydrated lipid assemblies. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
206.
Hiroyuki Yamazaki Akiho Yagi Masanari Akaishi Ryota Kirikoshi Ohgi Takahashi Tatsuki Abe Satomi Chiba Kenta Takahashi Natsuki Iwakura Michio Namikoshi Ryuji Uchida 《Tetrahedron letters》2018,59(20):1913-1915
A new cladosporol derivative, 2-chloro-cladosporol D (6), was isolated together with known cladosporol (1), cladosporols B–D (2–4), and cladosporol F (5) from the culture broth of plant-associated Cladosporium sp. TMPU1621. The structure of 6 was elucidated from spectroscopic analyses including NMR and MS data. The productivity of 6 increased in 3% NaCl-supplemented medium; therefore, fermentation of the producing fungus TMPU1621 with 3% NaBr was investigated, leading to the induced production of a new halogenated cladosporol, 2-bromo-cladosporol D (7). Compound 2 showed the lowest MIC values of 3.13 and 12.5?μg/mL against two MRSA strains, ATCC43300 and ATCC700698, respectively. 相似文献
207.
The aim of this paper is to present the finite element method and its application to quasi-steady periodic two-layer tidal flow in estuaries and coastal seas. Formulating the weighted residual equations, using quadratic polynomials for velocity and linear polynomials for water elevation as interpolation functions and employing the periodic Galerkin method, the nonlinear simultaneous equations can be derived. The present method is used for the simulation analysis of the Niigata Port redevelopment planning. 相似文献
208.
Dye laser emission from 3-cyano-4-methylumbelliferone in alcoholic solutions containing various amounts of water, acid, or alkali was studied, and the best solvent compositions for the dye were determined. By nitrogen laser pumping, (1) anhydrous ethanolic solution gave very intense laser emission in 400–470 nm region. (2) Aqueous ethanol solutions containing more than 4% of water gave laser of longer-wavelength region, 440–510 nm. Among them, the solution of 16% in water content gave the highest powers. Addition of very small amount of perchloric acid solution to them resulted in a slight expansion of the tuning range toward the shorter wavelength without reducing the intensities. By flashlamp pumping, (3) only the laser of the longer-wavelength region was obtained with aqueous ethanol solutions. The optimum water content to give the highest power was 35–45%. 相似文献
209.
The phase transition behaviour of an optically isotropic, thermotropic cubic mesogen 1,2-bis-(4- n -octyloxybenzoyl)hydrazine, BABH(8), was investigated under pressures up to 200 MPa using a high pressure differential thermal analyser, wide-angle X-ray diffraction and a polarizing optical microscope equipped with a high pressure optical cell. The phase transition sequence, low temperature crystal (Cr 2 )-high temperature crystal (Cr 1 ) - cubic (Cub)-smectic C (SmC)-isotropic liquid (I) observed at atmospheric pressure, is seen in the low pressure region below about 30 MPa. The cubic phase disappears at high pressures above 30-40 MPa, in conjunction with the disappearance of the Cr 1 phase. The transition sequence changes to Cr 2 -SmC-I in the high pressure region. Since only the Cub-SmC transition line among all the phase boundaries has a negative slope (d T /d P ) in the temperature-pressure phase diagram, the temperature range for the cubic phase decreases rapidly with increasing pressure. As a result, a triple point was estimated approximately as 31.6 ±2.0 MPa, 147.0 ±1.0°C for the SmC, Cub and Cr 1 phases, indicating the upper limit of pressure for the observation of the cubic phase. Reversible changes in structure and optical texture between the Cub and SmC phases were observed from a spot-like X-ray pattern and dark field for the cubic phase to the Debye-Sherrer pattern and sand-like texture for the SmC phase both in isobaric and isothermal experiments. 相似文献
210.