Chemical reactions of water molecules on Ru(0 0 0 1) induced by selective excitation of vibrational modes

Tunneling electrons in a scanning tunneling microscope were used to excite specific vibrational quantum states of adsorbed water and hydroxyl molecules on a Ru(0 0 0 1) surface. The excited molecules relaxed by transfer of energy to lower energy modes, resulting in diffusion, dissociation, desorption, and surface-tip transfer processes. Diffusion of H₂O molecules could be induced by excitation of the O-H stretch vibration mode at 445 meV. Isolated molecules required excitation of one single quantum while molecules bonded to a C atom required at least two quanta. Dissociation of single H₂O molecules into H and OH required electron energies of 1 eV or higher while dissociation of OH required at least 2 eV electrons. In contrast, water molecules forming part of a cluster could be dissociated with electron energies of 0.5 eV.     

On well-posedness of incompressible two-phase flows with phase transitions: the case of non-equal densities

The basic model for incompressible two-phase flows with phase transitions consistent with thermodynamics is studied. The latter means that the total energy is conserved and the total entropy is nondecreasing. We consider the case of constant but non-equal densities of the phases, complementing our previous paper (Prüss et?al. in Evol Equ Control Theory 1:171–194, 2012) where the case of equal densities is analyzed. The local well-posedness of such problems is proved by means of the technique of maximal L _p -regularity, in a configuration where the interface is nearly flat and initial data are small.     

Higher Harmonic Operations of Submillimeter Wave Gyrotrons (Gyrotron FU Series)

Higher harmonic operation of gyrotrons is necessary to obtain high frequencies. Some gyrotrons included in the Gyrotron FU series developed at Fukui University have achieved operation at the third and even fourth harmonics of the electron cyclotron frequency. The output lies in the millimeter to submillimeter wavelength range and the output powers are several watts to several tens of watts. In this paper, the gyrotrons and the conditions under which they operate are described in detail.     

The inverse scattering problem and the equivalent local potential

We examine the role of the non-locality of the potential in the two-body scattering by taking the nucleon-Σ system as an example. We employ a non-local potential for the nucleon-Σ channel which has the characteristic features of the quark model and reproduces the phase shifts of widely used local potentials. We use inverse scattering methods to obtain the equivalent local potential from the non-local potential, and show that the obtained local potential has a strong short range repulsion.     

Achievement of a 920-MHz high resolution NMR

We have developed a 920-MHz NMR system and performed the proton NMR measurement of H(2)O and ethylbenzene using the superconducting magnet operating at 21.6 T (920 MHz for proton), which is the highest field produced by a superconducting NMR magnet in the persistent mode. From the NMR measurements, it is verified that both homogeneity and stability of the magnet have a specification sufficient for a high resolution NMR.     

Surface-enhanced emission from single semiconductor nanocrystals

The fluorescence behavior of single CdSe(ZnS) core-shell nanocrystal (NC) quantum dots is dramatically affected by electromagnetic interactions with a rough metal film. Observed changes include a fivefold increase in the observed fluorescence intensity of single NCs, a striking reduction in their fluorescence blinking behavior, complete conversion of the emission polarization to linear, and single NC exciton lifetimes that are >10(3) times faster. The enhanced excited state decay process for NCs coupled to rough metal substrates effectively competes with the Auger relaxation process, allowing us to observe both charged and neutral exciton emission from these NC quantum dots.     

Dynamic fracture behavior of ceramics at elevated temperatures by caustics

The fracture behavior of partially stabilized zirconia (PSZ) and silicon-nitride ceramics (Si₃N₄) is investigated under dynamic loading at elevated temperatures up to 1200°C using the caustic method combined with an ultra high-speed camera. The values of the dynamic fracture toughnessK _Id and the crack-propagation fracture toughnessK _ID are obtained, and it is shown that a dynamic effect on these values is observed in PSZ but not in Si₃N₄. The dynamic crack arrest toughnessK _Ia is found to exist for PSZ.     

Investigation of elemental shape for 3D DEM modeling of interaction between soil and a narrow cutting tool

Discrete Element Method (DEM) has been applied in recent studies of soil cutting tool interactions in terramechanics. Actual soil behavior is well known to be inexpressible by simple elemental shapes in DEM, such as circles for 2D or spheres for 3D because of the excessive rotation of elements. To develop a more effective model for approximating real soil behavior by DEM, either the introduction of a rolling resistance moment for simple elemental shape or the combination of simple elements to form a complex model soil particle shape cannot be avoided. This study was conducted to investigate the effects of elemental shape on the cutting resistance of soil by a narrow blade using 3D DEM. Six elemental shapes were prepared by combining unit spheres of equal elemental radius. Moreover, cutting resistance was measured in a soil bin filled with air-dried sand to collect comparative data. The elemental shape, with an axial configuration of three equal spheres overlapped with each radius, showed similar results of soil cutting resistance to those obtained experimentally for the six elemental shapes investigated.