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81.
Shigeyuki Tasaka Hirokazu Tanabe Yoshiyuki Sasaki Toshiki Machida Mayumi Iino Akira Kiue Seiji Naito Michihiko Kuwano 《Journal of heterocyclic chemistry》1997,34(6):1763-1767
We have investigated 3-substituted-2-phenylimidazo[2,1-b]benzothiazole derivatives and herein we have discussed their pharmaceutical activities. We found that some 2-phenyl-5,6,7,8-tetrahydroimidazo[2,1-b]-benzothiazoles could overcome multidrug resistance for tumor cells. Among them, 2-phenyl-3-(N-methyl-3-piperidyl)carbonylammomiinomemyl-5,6,7,8-tetrahydVoimidazo[2,1-b]benzothiazole [N276-12] demonstrated the most potent activity for overcoming multidrug resistance. 相似文献
82.
M. Ishii Y. Kuwano S. Asaba T. Asai M. Kawamura N. Senguttuvan T. Hayashi M. Koboyashi M. Nikl S. Hosoya K. Sakai T. Adachi T. Oku H. M. Shimizu 《Radiation measurements》2004,38(4-6):571-574
Lithium tetraborate single crystal doped with Cu seems to be a promising new material for neutron detection. With the presence of Li and B, both having large cross section for neutron capture, efficient neutron detection is expected with high-energy deposits. In the present work, we chose 14 different dopants from Ia, Ib, IIIa, IVa and Va groups in the periodic table besides the rare earth Ce ion. The crystals were grown to a size of 20 mm in diameter and 70 mm in length by vertical Bridgman method. The grown crystals were characterized by optical transmittance and excitation–emission studies. Transmittance and emission characteristics of Ce-doped lithium borate glass are also reported. 相似文献
83.
Takahide Oya Yoshiyuki Takahashi Masayuki Ikebe Tetsuya Asai Yoshihito Amemiya 《Superlattices and Microstructures》2003,34(3-6):253
A single-electron circuit can be operated as a discrete dynamical system because it changes its internal state discontinuously because of electron tunneling. To confirm this idea, we designed a sample circuit for discrete dynamical operation and confirmed by computer simulation that the circuit successfully generated a sequence of discrete-time outputs by following a return map. The concept of discrete dynamical systems will be useful in developing new functional systems that consist of quantum devices and nanostructures. 相似文献
84.
Diffusion of a Li atom in an anode material β-LiAl was studied over the composition range of 48.0–50.2 at % Li by the 7Li magnetic relaxation times. Dependence of T1 upon temperature and the resonance frequency was successfully explained by a vacancy diffusion on the Li sublattice involving a distribution of the activation energy for migration, Ea. The central value of Ea was almost independent of the composition (? 13.8 kJ mol-1), while the width of distribution increased with increase of the number of substituted Li on the Al sublattice. The obtained diffusion constants, extrapolated to 415°C, were larger by a factor of 1.8–3.4 than those obtained by the electrochemical method. 相似文献
85.
Michihiko Noguchi Noriyuki Tanigawa Shoji Kajigaeshi 《Journal of heterocyclic chemistry》1985,22(4):1049-1053
Some cyclohepta[ef]cycl[3.2.2]azines were prepared from cyclohepta[hi]indolizines and electron deficient acetylenes in the presence of appropriate oxidants. Also, benzo[ef]cycl[3.2.2]azines were obtained similarly in good yields. 相似文献
86.
R. Akers G. Alexander J. Allison N. Altekamp K. Ametewee K. J. Anderson S. Anderson S. Arcelli S. Asai D. Axen et al. 《Zeitschrift fur Physik C Particles and Fields》1995,67(3):365-378
The forward-backward asymmetry of
has been measured using approximately 2.15 million hadronicZ
0 decays collected at the LEP e+e– collider with the OPAL detector. A lifetime tag technique was used to select an enriched
event sample. The measurement of the
asymmetry was then performed using a jet charge algorithm to determine the direction of the primary quark. Values of:
相似文献
87.
Thermal reaction of 2-[N-(alk-2-enyl)benzylamino]-3-(2-substituted and 2,2-disubstituted)vinylpyrido[1,2-a]pyrimidin-4(4H)-ones gave azepine, the desired ene products, and/or pyran derivatives. The formation of the latter was responsible for the [4+2] cycloaddition reaction between the α,β-unsaturated ester carbonyl moiety as a diene part and the alkenylamino moiety as an ene one. The reaction features depended upon the kinds of substituents both on the vinyl and alkenyl counterparts; strongly electron-withdrawing substituents on the vinyl moiety or an electron-donating substituent on the alkenyl one changed the reaction feature from the ene reaction to the hetero Diels-Alder reaction. 相似文献
88.
A new catalytic system for beta-alkylation of secondary alcohols has been developed. In the presence of [CpIrCl(2)](2) (Cp = pentamethylcyclopentadienyl) catalyst and base, the reactions of various secondary alcohols with primary alcohols give beta-alkylated higher alcohols in good to excellent yields without any hydrogen acceptor or hydrogen donor. This reaction proceeds via successive hydrogen-transfer reactions and aldol condensation. [reaction: see text] 相似文献
89.
K. Akiyama K. Sueki H. Haba K. Tsukada M. Asai T. Yaita Y. Nagame K. Kikuchi M. Katada H. Nakahara 《Journal of Radioanalytical and Nuclear Chemistry》2003,255(1):155-158
We have, previously, reported on the HPLC elution behavior of the Th, Pa, U, Np, and Am metallofullerenes and the UV/vis/NIR absorption spectra of the Th@C84 and U@C82 species. In this paper, the followings are reported: (1) Pu metallofullerenes were produced and their HPLC elution behavior was investigated using a radiotracer technique. The HPLC chromatogram of this metallofullerene was found to be almost the same as that of the Np and Am metallofullerenes. (2) The oxidation states of Th@C84 and U@C82 produced in macroscopic quantities were examined by XANES (X-ray absorption near edge structure) measurements. The oxidation state of the U atom in the C82 fullerene cage was estimated to be 3+ with the formal charge of the ionic molecule being U3+@C82
3-. 相似文献
90.
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