全文获取类型
收费全文 | 1254篇 |
免费 | 38篇 |
国内免费 | 8篇 |
专业分类
化学 | 905篇 |
晶体学 | 15篇 |
力学 | 26篇 |
数学 | 49篇 |
物理学 | 305篇 |
出版年
2022年 | 8篇 |
2021年 | 14篇 |
2020年 | 14篇 |
2019年 | 17篇 |
2016年 | 24篇 |
2015年 | 21篇 |
2014年 | 25篇 |
2013年 | 53篇 |
2012年 | 47篇 |
2011年 | 70篇 |
2010年 | 36篇 |
2009年 | 44篇 |
2008年 | 61篇 |
2007年 | 74篇 |
2006年 | 54篇 |
2005年 | 58篇 |
2004年 | 54篇 |
2003年 | 49篇 |
2002年 | 62篇 |
2001年 | 40篇 |
2000年 | 32篇 |
1999年 | 29篇 |
1998年 | 14篇 |
1997年 | 8篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 14篇 |
1993年 | 17篇 |
1992年 | 37篇 |
1991年 | 21篇 |
1990年 | 19篇 |
1989年 | 17篇 |
1988年 | 20篇 |
1987年 | 13篇 |
1986年 | 7篇 |
1985年 | 19篇 |
1984年 | 16篇 |
1983年 | 15篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 14篇 |
1976年 | 10篇 |
1974年 | 9篇 |
1973年 | 15篇 |
1969年 | 6篇 |
1968年 | 9篇 |
1965年 | 6篇 |
排序方式: 共有1300条查询结果,搜索用时 15 毫秒
141.
The growing curve of light-induced dangling bonds under illumination has been observed for various intensities of illumination in a-Si:H. It is fitted to a stretched exponential function and then two parameters β and τ involved in the function are estimated as a function of saturated dangling bond density . The experimental values of β, τ, and are compared with those calculated based on our model of light-induced defect creation in a-Si:H. 相似文献
142.
Velocity profile measurement by ultrasonic doppler method 总被引:11,自引:0,他引:11
Yasushi Takeda 《Experimental Thermal and Fluid Science》1995,10(4):444-453
The ultrasonic velocity profile measuring method has been developed at PSI for application in fluid mechanics and fluid flow measurement. It uses pulsed ultrasonic echography together with the detection of the instantaneous Doppler shift frequency. This method has the following advantages over the conventional techniques: (1) an efficient flow mapping process, (2) applicability to opaque liquids, and (3) a record of the spatiotemporal velocity field. After a brief introduction of its principle, the characteristics and specifications of the present system are given. Then examples in fluid engineering for oscillating pipe flow, T-branching flow of mercury, and recirculating flow in a square cavity are described that confirm the method's advantages. Several other works under way by other investigators are introduced. A potential for in-depth study of fluid dynamics is demonstrated by several examples from an investigation of modulated wavy flows in a rotating Couette system. The position-averaged power spectrum and the time-averaged energy spectral density were used to study the dynamic characteristics of the flow, and subsequently the velocity field was decomposed into its intrinsic wave structure based on two-dimensional Fourier analysis. 相似文献
143.
Spatio-temporal velocity fields of an axisymmetric sudden expansion were measured using an ultrasonic velocity profiler and analyzed to investigate the transitional scheme of the spatial structure using two-dimensional Fourier transform and proper orthogonal decomposition techniques. The variation of the zero-crossing point, the fluctuation energy directed upstream and the eigenmode spectrum all have the same transitional scheme as a function of the Reynolds number. The transitional scheme can be classified Re d<1,000 for the laminar regime, Re d=1,000–3,000 for the transitional regime and Re d>3,000 for the turbulent regime. Especially, in the transitional regime, we found large changes in the flow structure at Re d=1,500 and 2,000. The jump at Re d=2,000 is caused by the change in the flow condition upstream. The jump at Re d=1,500 clearly shows a change in the spatial structure of the flow. 相似文献
144.
Nakayama Masanobu Nishimura Norimitsu Kondo Yuki Takeda Hayami Kasuga Toshihiro 《Journal of Solid State Electrochemistry》2017,21(4):1137-1143
Journal of Solid State Electrochemistry - We demonstrate the Laplace transform (LT) impedance technique for measuring electrochemical lithiation and delithiation in the two-phase system of spinel... 相似文献
145.
Junko Takeda Rieko Nakata Hiroshi Ueno Akio Murakami Mineo Iseki Masakatsu Watanabe 《Photochemistry and photobiology》2014,90(5):1043-1049
Our previous studies of action spectra for UV‐B‐induced anthocyanin accumulation in cultured carrot cells indicated that a reduced form of pterin, possibly tetrahydrobiopterin, contributes to UV‐B photoreception. In this report, we provide additional evidence for the involvement of pterin in UV‐B light sensing. UV‐B‐induced phenylalanine ammonia‐lyase (PAL) activity was considerably suppressed by N‐acetylserotonin (an inhibitor of tetrahydrobiopterin biosynthesis), and this suppression was partially recovered by adding biopterin or tetrahydrobiobiopterin. In addition, protein(s) specifically bound to biopterin were detected by radiolabeling experiments in N‐acetylserotonin‐treated cells. Furthermore, diphenyleneiodonium, a potent inhibitor of electron transfer, completely suppressed UV‐B‐induced PAL activity. These results suggest the occurrence of an unidentified UV‐B photoreceptor (other than UVR8, the tryptophan‐based UV‐B sensor originally identified in Arabidopsis) with reduced pterin in carrot cells. After reexamining published action spectra, we suggest that anthocyanin synthesis is coordinately regulated by these two UV‐B sensors. 相似文献
146.
Takeda K 《Analytical sciences》2011,27(12):1213-1216
A chemical dosimetry system based on the radiochemical formation of phenol from aqueous benzene solutions was applied to measure the intensity of γ-ray irradiation. Using a simple and sensitive isocratic fluorometric HPLC system, radiochemically generated phenol was determined. The radiochemical formation of phenol was linear up to 100 Gy and the lower limit of detection calculated from the detection limits of phenol was estimated to be 7 mGy. The phenol formation rates were not affected by the oxygen saturation. The chemical dosimetry system investigated in this study was sensitive and was easier to use than traditional chemical dosimeters. 相似文献
147.
Yasuda M Nakajima H Takeda R Yoshioka S Yamasaki S Chiba K Baba A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(14):3856-3867
Boron complexes that contain new tridentate ligands, tris(o‐oxyaryl)methanes and ‐silanes, were prepared. These complexes had a cage‐shaped structure around a boron center and showed higher Lewis acidity and catalytic activity than open‐shaped boron compounds. The cage‐shaped ligands determined the properties of the borates by altering the geometry and were consistently bound to the metal center by chelation. The synthesized compounds were L?B(OC6H4)3CH, L?B(OC6H4)3SiMe, and its derivatives (L=THF or pyridine as an external ligand). Theoretical calculations suggested that the cage‐shaped borates had a large dihedral angle (Cipso‐O‐B‐O) compared with open‐shaped borates. The geometric effect due to the dihedral angle means that compared with open‐shaped, the cage‐shaped borates have a greater Lewis acidity. The introduction of electron‐withdrawing groups on the aryl moieties in the cage‐shaped framework increased the Lewis acidity. Substitution of a bridgehead Si for a bridgehead C decreased the Lewis acidity of the boron complexes because the large silicon atom reduces the dihedral angle of Cipso‐O‐B‐O. The ligand‐exchange rates of the para‐fluoro‐substituted compound B(OC6H3F)3CH and the ortho‐phenyl‐substituted compound B(OC6H3Ph)3CH were less than that of the unsubstituted borate B(OC6H4)3CH. The ligand‐exchange rate of B(OC6H4)3SiMe was much faster than that of B(OC6H4)3CH. A hetero Diels–Alder reaction and Mukaiyama‐type aldol reactions were more effectively catalyzed by cage‐shaped borates than by the open‐shaped borate B(OPh)3 or by the strong Lewis acid BF3?OEt2. The cage‐shaped borates with the bulky substituents at the ortho‐positions selectively catalyzed the reaction with less sterically hindered substrates, while the unsubstituted borate showed no selectivity. 相似文献
148.
The development of a new class of hydrazide type organocatalyst, (4R,5R)-1,3-bis(isopropylamino)-4,5-dihenylimidazolidin-2-one 2a, for enantioselective Diels-Alder reactions between cyclopentadiene and α,β-unsaturated aldehydes are presented. The new organocatalyst 2a promoted the reaction, affording Diels-Alder adducts in good yields with good levels of enantioselectivity. 相似文献
149.
tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for the cycloaddition of oximes and alkenes/alkynes, leading to the formation of a variety of isoxazolines or isoxazoles under mild conditions. 相似文献
150.
Terauchi T Kamikawai T Vinogradov MG Starodubtseva EV Takeda M Kainosho M 《Organic letters》2011,13(1):161-163
A stereoarray isotope labeled (SAIL) lysine, (2S,3R,4R,5S,6R)-[3,4,5,6-(2)H(4);1,2,3,4,5,6-(13)C(6);2,6-(15)N(2)]lysine, was synthesized by the "head-to-tail" conversion of SAIL-Glu, (2S,3S,4R)-[3,4-(2)H(2);1,2,3,4,5-(13)C(5);2-(15)N]glutamic acid, with high stereospecificities for all five chiral centers. With the SAIL-Lys in hand, the unambiguous simultaneous stereospecific assignments were able to be established for each of the prochiral protons within the four methylene groups of the Lys side chains in proteins. 相似文献